Methyl 2-(bromomethyl)-4-methoxybenzoate

Product Name: Methyl 2-(bromomethyl)-4-methoxybenzoate
CAS No.: 15365-25-0
Chemical Name: Methyl 2-(bromomethyl)-4-methoxybenzoate
Synonyms: NISTC15365250;METHYL 2-BROMOMETHYL-4-METHOXY-BENZOATE;p-Anisic acid, 2-bromomethyl-, methyl ester;2-BROMOMETHYL-4-METHOXYBENZOICACID,METHYLESTER;Benzoic acid, 2-(broMoMethyl)-4-Methoxy-, Methyl ester
CBNumber: CB3104220
Molecular Formula: C10H11BrO3
Formula Weight: 259.1
MOL File: 15365-25-0.mol

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Methyl 2-(bromomethyl)-4-methoxybenzoate Property

Melting point:: 51 °C
Boiling point:: 350.4±32.0 °C(Predicted)
Density: 1.432±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: White to off-white Solid

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC

Product number: M296168
Product name: Methyl2-(bromomethyl)-4-methoxybenzoate
Packaging: 25mg
Price: $45
Updated: 2021/12/16

Matrix Scientific

Product number: 072736
Product name: Methyl 2-bromomethyl-4-methoxybenzoate
Purity: 95+%
Packaging: 1g
Price: $155
Updated: 2021/12/16

AK Scientific

Product number: W3346
Product name: Methyl2-bromomethyl-4-methoxybenzoate
Packaging: 5g
Price: $291
Updated: 2021/12/16

Matrix Scientific

Product number: 072736
Product name: Methyl 2-bromomethyl-4-methoxybenzoate
Purity: 95+%
Packaging: 5g
Price: $306
Updated: 2021/12/16

AK Scientific

Product number: W3346
Product name: Methyl2-bromomethyl-4-methoxybenzoate
Packaging: 10g
Price: $451
Updated: 2021/12/16

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Methyl 2-(bromomethyl)-4-methoxybenzoate Chemical Properties,Usage,Production

Uses

Methyl 2-(bromomethyl)-4-methoxybenzoate

Synthesis

35598-05-1

15365-25-0

The general procedure for the synthesis of methyl 2-bromomethyl-4-methoxybenzoate from methyl 4-methoxy-2-methylbenzoate was as follows: N-bromosuccinimide (1.1 g, 6.2 mmol) and a catalytic amount of methyl 4-methoxy-2-methylbenzoate (1 g, 5.6 mmol) were pre-dissolved in carbon tetrachloride (5 mL), which was subsequently added dropwise to a solution containing 25 mL of carbon tetrachloride. After addition of benzoyl peroxide, the reaction mixture was refluxed for 2 hours. After completion of the reaction, it was cooled to room temperature and the mixture was poured into ice water. The aqueous phase was extracted with dichloromethane (3×), and the combined organic phases were dried over magnesium sulfate, filtered, and concentrated under vacuum to afford 2.1 g of the target product, methyl 2-bromomethyl-4-methoxybenzoate, as a light yellow solid in about 100% yield. Mass spectrometry analysis showed [M + H+] m/z 260.

References

[1] Patent: WO2011/85261, 2011, A1. Location in patent: Page/Page column 36
[2] Patent: WO2011/85128, 2011, A1. Location in patent: Page/Page column 56
[3] Journal of Medicinal Chemistry, 1987, vol. 30, # 10, p. 1798 - 1806
[4] Patent: US2008/249101, 2008, A1. Location in patent: Page/Page column 40
[5] Patent: WO2008/20306, 2008, A2. Location in patent: Page/Page column 35

Methyl 2-(bromomethyl)-4-methoxybenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-(bromomethyl)-4-methoxybenzoate Suppliers

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View Lastest Price from Methyl 2-(bromomethyl)-4-methoxybenzoate manufacturers

Career Henan Chemical Co

Product: Methyl 2-(bromomethyl)-4-methoxybenzoate 15365-25-0
Price: US $6.68/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 1kg-1000kg
Release date: 2020-01-10

15365-25-0, Methyl 2-(bromomethyl)-4-methoxybenzoateRelated Search:

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METHYL 2-BROMOMETHYL-4-METHOXY-BENZOATE

NISTC15365250

2-BROMOMETHYL-4-METHOXYBENZOICACID,METHYLESTER

p-Anisic acid, 2-bromomethyl-, methyl ester

Benzoic acid, 2-(broMoMethyl)-4-Methoxy-, Methyl ester

15365-25-0