SILVER TRIFLUOROMETHANESULFONATE

Reactions

Product Name: SILVER TRIFLUOROMETHANESULFONATE
CAS No.: 2923-28-6
Chemical Name: SILVER TRIFLUOROMETHANESULFONATE
Synonyms: AGOTF;SILVER TRIFLATE;SILVER TRIFLUOROMETHANESULPHONATE;Silver (trifluoromethyl)sulfonate;TRIFLUOROMETHANESULFONIC ACID SILVER SALT;fonate;ver trifL;uoromethanesuL;Silver(I)triflate;Indiumtrifluorometha
CBNumber: CB3157655
Molecular Formula: CAgF3O3S
Formula Weight: 256.94
MOL File: 2923-28-6.mol

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SILVER TRIFLUOROMETHANESULFONATE Property

Melting point:: 286 °C (lit.)
storage temp.: Store below +30°C.
solubility: Methanol (Slightly), Water (Slightly)
form: Powder
color: White to light beige
Water Solubility: Soluble in water and also in most organic solvents.
Sensitive: Light Sensitive
Hydrolytic Sensitivity: 6: forms irreversible hydrate
BRN: 3598402
Stability:: Stable, but may be light sensitive. Incompatible with strong acids, strong oxidizing agents.
InChI: InChI=1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
InChIKey: QRUBYZBWAOOHSV-UHFFFAOYSA-M
SMILES: C(F)(F)(F)S([O-])(=O)=O.[Ag+]
CAS DataBase Reference: 2923-28-6(CAS DataBase Reference)
EPA Substance Registry System: Methanesulfonic acid, trifluoro-, silver(1+) salt (2923-28-6)

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Safety

Hazard Codes: Xi,C
Risk Statements: 36/37/38-50-34
Safety Statements: 26-36-61-45-36/37/39
RIDADR: 3260
WGK Germany: 3
F: 8
Hazard Note: Corrosive
TSCA: Yes
HazardClass: 8
HS Code: 28432900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.14325
Product name: Silver trifluoromethanesulfonate
Purity: for synthesis
Packaging: 5G
Price: $103
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.14325
Product name: Silver trifluoromethanesulfonate
Purity: for synthesis
Packaging: 25g
Price: $342
Updated: 2024/03/01

Sigma-Aldrich

Product number: 176435
Product name: Silver trifluoromethanesulfonate
Purity: ≥99%
Packaging: 1g
Price: $40.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 176435
Product name: Silver trifluoromethanesulfonate
Purity: ≥99%
Packaging: 10g
Price: $122
Updated: 2024/03/01

TCI Chemical

Product number: T1331
Product name: Silver Trifluoromethanesulfonate
Purity: >98.0%(T)
Packaging: 1g
Price: $28
Updated: 2024/03/01

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SILVER TRIFLUOROMETHANESULFONATE Chemical Properties,Usage,Production

Reactions

Silver precatalyst for the asymmetric allylation of aldehydes
Silver catalyst for intramolecular additions of alcohols and carboxylic acids to inert olefins
Silver catalyst for the fluorination of boronic acids
Silver catalyst for the fluorination of functionalized aryl stannanes
Silver catalyst for cyclopropenation of internal alkynes with donor/acceptor substituted diazo compounds
Silver catalyst for the reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate

Chemical Properties

light beige crystalline powder

Uses

Silver Trifluoromethanesulfonate is used to generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes. It is also employed as a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes.

General Description

Silver trifluoromethanesulfonate p-complexes of monoenes, dienes, trienes, monoynes and diynes have been prepared. It reacts with 2-fluoro- and 3-fluoro-4-alkoxystilbazoles to afford the mesomorphic complexes. Iodine monochloride/AgOTf constitutes an efficient promoter system for the O-glycoside synthesis.

Purification Methods

Recrystallise it twice from hot CCl4 [Alo et al. J Chem Soc, Perkin Trans 1 805 1986]. Store it in the dark. [Beilstein 3 IV 34.]

SILVER TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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SILVER TRIFLUOROMETHANESULFONATE Suppliers

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View Lastest Price from SILVER TRIFLUOROMETHANESULFONATE manufacturers

LY Global chemicals co.,ltd .

Product: SILVER TRIFLUOROMETHANESULFONATE 2923-28-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000KG
Release date: 2023-03-09

Henan Aochuang Chemical Co.,Ltd.

Product: SILVER TRIFLUOROMETHANESULFONATE 2923-28-6
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-09

henan kanbei chemical co.,ltd

Product: SILVER TRIFLUOROMETHANESULFONATE 2923-28-6
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-22

2923-28-6, SILVER TRIFLUOROMETHANESULFONATERelated Search:

Trifluoromethanesulfonic acid Scandium trifluoromethanesulfonate Ethyl trifluoromethanesulfonate TIN(II) TRIFLUOROMETHANESULFONATE Fluoranthene-3-boronic acid 2,3-DIHYDRO-1H-INDOLE-6-CARBOXYLIC ACID Lanthanum trifluoromethanesulfonate Aluminum trifluoromethanesulfonate YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE Sodium trifluoromethanesulfonate Trifluoromethanesulfonic anhydride Trifluoromethanesulfonyl chloride Trifluoromethanesulfonimide Lithium trifluoromethanesulfonate Zinc trifluoromethanesulfonate Lithium bis(trifluoromethanesulphonyl)imide N-Phenyl-bis(trifluoromethanesulfonimide) Potassium trifluoromethanesulfonate

SILVER (I) TRIFLUOROMETHANE SULFONATE

SILVER(I) TRIFLUOROMETHANESULPHONATE

SILVER TRIFLATE

SILVER TRIFLUOROMETANESULFONATE

SILVER TRIFLUOROMETHANESULFONATE

SILVER TRIFLUOROMETHANESULPHONATE

TRIFLUOROMETHANESULFONATE SILVER SALT

TRIFLUOROMETHANESULFONIC ACID SILVER SALT

Silver triflate, Trifluoromethanesulfonic acid silver salt

(Trifluoromethylsulfonyloxy) silver(I)

Trifluoromethanesulfonic acid silver

Trifluoromethanesulfonic acid silver(I)

Trifluoromethylsulfonyloxysilver(I)

Silver trifluoromethanesulfonate,Silver triflate, Trifluoromethanesulfonic acid silver salt

Silver trifluoromethanesulfonate/ 97+%

LVER TRIFLUOROMETHANESULFONATE

Silver trifluoroMethanesulfonate,98% (Silver triflate) Ag(CF3SO3)

SILVER TRIFLUOROMETHANESULFONATE FOR SYN

(trifluoroMethylsulfonyloxy)silver, TfOAg

SILVER (I) TRILUOROMETHANE SULFONATE

silver(I) 4-(trifluoroMethyl)benzenesulfonate

Silver trifluoroMethanesulfonate >=99.95% trace Metals basis

Silver (trifluoromethyl)sulfonate

Silver trifluoromethanesulfonate purum, >=98.0% (Ag)

AGOTF

trifluoro-methanesulfonicacisilver(1++)salt

Silvertrifluoromethanesulfonate,99%(Silvertriflate)

Methanesulfonic acid, trifluoro-, silver(1+) salt

Silver trifluoromethanesulphonate 99%

Silver trifluormethanesulfonate

Silver(I) triflate~Trifluoromethanesulphonic acid silver(I) salt

SILVER TRIFLUOROMETHANESULFONATE, 99.95+ %

SILVER TRIFLUOROMETHANESULFONATE, 99+%

Silver(I)triflate

Trifluoromethanesulfonicacidsilver(I)salt

Silvertrifluoromethanesulphonate99%

SILVER TRIFLUOROMETHANESULFONATE (SILVER TRIFLATE)

SILVER TRIFLUOROMETHANESULFOTE

Silver trifluoromethanesulfonate (99.95%-Ag) (Silver triflate)

TRIFLUOROMETHYLSULFONYLOXYSILVER

Indiumtrifluorometha

Silver Trifluoromethanesulfonate （AgOTf）

SILVER TRIFLUOROMETHANESULFONATE, 99%SILVER TRIFLUOROMETHANESULFONATE, 99%SILVER TRIFLUOROMETHANESULFONATE, 99%SILVER TRIFLUOROMETHANESULFONATE, 99%

silver trifluoromethanesulphonate CHF3O3S.Ag

fonate

uoromethanesuL

ver trifL

Silver trifluoromethanesulfonate, 98%, for synthesis

Powdered silver trifluoromethanesulfonate

Methanesulfonic acid, 1,1,1-trifluoro-, silver(1+) salt (1:1)

SILVER TRIFLUOROMETHANESULFONATE ISO 9001：2015 REACH

Silver Trifluoromethanesulfonate extrapure, 98%

Silver(Ⅰ) trifluorometanesulfonate

SILVER TRIFLATE Silver trifluoromethanesulfonate

2923-28-6

AgSO3CF3

AgOSO2CF3

CHF3O3SAg