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2'-Hydroxy-4'-methylacetophenone

Product Name
2'-Hydroxy-4'-methylacetophenone
CAS No.
6921-64-8
Chemical Name
2'-Hydroxy-4'-methylacetophenone
Synonyms
ASISCHEM D38758;2'-Hydroxyacetopenone;4-Methyl-2-Hydroxyacetophenone;2-Hydroxy-4-Methylacetophenone;Mercaptobenzimidazole zinc salt;2'-Hydroxy-4'-methylacetophenone;2''-Hydroxy-4''-methylacetophenone;1-(2-hydroxy-4-methylphenyl)-ethanon;1-(2-HYDROXY-4-METHYLPHENYL)ETHANONE;2'-Hydroxy-4'-Methylacetophenone 97%
CBNumber
CB3253409
Molecular Formula
C9H10O2
Formula Weight
150.17
MOL File
6921-64-8.mol
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2'-Hydroxy-4'-methylacetophenone Property

Melting point:
21°C
Boiling point:
245 °C(lit.)
Density 
1.08 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.565(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
form 
clear liquid
pka
10.27±0.10(Predicted)
color 
Colorless to Light orange to Yellow
λmax
325nm(MeOH)(lit.)
InChI
InChI=1S/C9H10O2/c1-6-3-4-8(7(2)10)9(11)5-6/h3-5,11H,1-2H3
InChIKey
LYKDOWJROLHYOT-UHFFFAOYSA-N
SMILES
C(=O)(C1=CC=C(C)C=C1O)C
CAS DataBase Reference
6921-64-8(CAS DataBase Reference)
EPA Substance Registry System
Ethanone, 1-(2-hydroxy-4-methylphenyl)- (6921-64-8)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
TSCA 
TSCA listed
HS Code 
2914500090
Storage Class
10 - Combustible liquids
Hazard Classifications
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
531669
Product name
2′-Hydroxy-4′-methylacetophenone
Purity
97%
Packaging
10g
Price
$132
Updated
2022/05/15
TCI Chemical
Product number
H1530
Product name
2'-Hydroxy-4'-methylacetophenone
Purity
>95.0%(GC)
Packaging
5g
Price
$76
Updated
2025/07/31
TCI Chemical
Product number
H1530
Product name
2'-Hydroxy-4'-methylacetophenone
Purity
>95.0%(GC)
Packaging
25g
Price
$264
Updated
2025/07/31
TRC
Product number
H939865
Product name
2′-Hydroxy-4′-methylacetophenone
Packaging
5g
Price
$110
Updated
2021/12/16
TRC
Product number
H939865
Product name
2′-Hydroxy-4′-methylacetophenone
Packaging
10g
Price
$175
Updated
2021/12/16
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2'-Hydroxy-4'-methylacetophenone Chemical Properties,Usage,Production

Uses

2′-Hydroxy-4′-methylacetophenone is found in Angelica koreana roots and a study was done in which it could be useful for natural acaricides against three mite species.

Preparation

Preparation by treatment of methyl 4-hydroxy-7- methyl-coumarin-3-carboxylate with potassium hydroxide at 200° (87%).

Synthesis Reference(s)

Tetrahedron Letters, 37, p. 4183, 1996 DOI: 10.1016/0040-4039(96)00790-3

General Description

2′-Hydroxy-4′-methylacetophenone, also known as 1-(2-hydroxy-4-methylphenyl)ethanone can be synthesized by the Fries rearrangement of m-tolyl acetate in the presence of zirconium tetrachloride. The results from the toxicity studies on mite species suggest that 2′-hydroxy-4′-methylacetophenone possesses acaricidal property.

2'-Hydroxy-4'-methylacetophenone Preparation Products And Raw materials

Raw materials

Preparation Products

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2'-Hydroxy-4'-methylacetophenone Suppliers

J & K SCIENTIFIC LTD.
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18210857532; 18210857532
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86-10-82849933
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jkinfo@jkchemical.com
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China
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96815
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
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China
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Beijing HwrkChemical Technology Co., Ltd
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010-89508211 18501085097
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010-89508210
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sales.bj@hwrkchemical.com
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Energy Chemical
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+86 (0) 571 85 58 67 18
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0086-571-85864795
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China
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Accela ChemBio Co.,Ltd.
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021-50795055
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sales@accelachem.com
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China
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Nanjing Chemlin Chemical Co., Ltd
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025-83697070 13913916777;
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+86-25-83453306
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info@chemlin.com.cn
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China
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Shanghai Hanhong Scientific Co.,Ltd.
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021-54306202 13764082696
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ChangZhou SIDU chemical Co., Ltd.
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0519-81291281 18015082300
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0519-81291281
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siduchem@hotmail.com
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China
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Shanghai yirong biology science and technology co., ltd
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18049974220 18049974220
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+86 (21) 51062076
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2982487773@qq.com
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China
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View Lastest Price from 2'-Hydroxy-4'-methylacetophenone manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
2'-Hydroxy-4'-methylacetophenone 6921-64-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2024-11-19
Zhuozhou Wenxi import and Export Co., Ltd
Product
2"-Hydroxy-4"-methylacetophenone 6921-64-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
2'-Hydroxy-4'-methylacetophenone 6921-64-8
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10tons
Release date
2020-02-18

6921-64-8, 2'-Hydroxy-4'-methylacetophenoneRelated Search:


  • 1-(2-HYDROXY-4-METHYLPHENYL)ETHAN-1-ONE
  • 1-(2-HYDROXY-4-METHYLPHENYL)ETHANONE
  • ASISCHEM D38758
  • 1-(2-hydroxy-4-methylphenyl)-ethanon
  • 4-Methyl-2-Hydroxyacetophenone
  • 1-(2-HYDROXY-4-METHYLPHENYL)ETHAN-1-ON
  • Ethanone,1-(2-hydroxy-4-Methylphenyl)-
  • 2'-Hydroxy-4'-Methylacetophenone 97%
  • 2'-Hydroxyacetopenone
  • Mercaptobenzimidazole zinc salt
  • 2'-Hydroxy-4'-methylacetophenone
  • 2''-Hydroxy-4''-methylacetophenone
  • 2''-Hydroxy-4''-methylacetophenone, 10 mM in DMSO
  • 2′-Hydroxy-4′-methylacetophenone, CAS 6921-64-8
  • 2-Hydroxy-4-Methylacetophenone
  • 2'-Hydroxy-4'-methylacetophenone - [H71503]
  • 6921-64-8
  • Building Blocks
  • Carbonyl Compounds
  • C9
  • Organic Building Blocks
  • Ketones
  • Aromatic Acetophenones & Derivatives (substituted)
  • Phenyls & Phenyl-Het
  • Phenyls & Phenyl-Het
  • C9
  • Carbonyl Compounds
  • Ketones