Uses
ChemicalBook > CAS DataBase List > [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

Uses
Product Name
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
CAS No.
72287-26-4
Chemical Name
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Synonyms
PDCL2(DPPF);(dppf)2PdCl2;dichloropalladiuM;1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II);Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,complex with CH2Cl2;oropaL;[1,1′(DPPF)PdCl2;JACS-72287-26-4;CHEMWISH IC30255
CBNumber
CB3276259
Molecular Formula
C34H28Cl2FeP2Pd
Formula Weight
731.7
MOL File
72287-26-4.mol
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[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Property

Melting point:
275-280 °C(lit.)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Soluble in dichloromethane.
form 
powder
color 
red to very dark red
Stability:
Hygroscopic
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38-40
Safety Statements 
23-24/25-26-36/37
WGK Germany 
3
TSCA 
No
HazardClass 
IRRITANT
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
697230
Product name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Packaging
1g
Price
$74.3
Updated
2024/03/01
Sigma-Aldrich
Product number
697230
Product name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Packaging
5g
Price
$227
Updated
2024/03/01
Alfa Aesar
Product number
046503
Product name
Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), Pd 13.5-15.5%
Packaging
1g
Price
$72.5
Updated
2023/06/20
Sigma-Aldrich
Product number
697230
Product name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Packaging
250g
Price
$9580
Updated
2024/03/01
TRC
Product number
B430465
Product name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Packaging
1g
Price
$100
Updated
2021/12/16
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[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chemical Properties,Usage,Production

Uses

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds. Is used in preparation of Nucleosides as Ectonucleotidase inhibitors.

Chemical Properties

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is Red solid

Uses

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings.

Uses

suzuki reaction

Uses

Catalyst for C-C and C-N coupling reaction.

Application

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions:
Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

Mechanism of action

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds.

R = usually sp2 hybridised carbon
X = usually I, Br, Cl or OTf
The nature of R' and M are dependant upon
the specic coupling being performed

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[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Suppliers

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View Lastest Price from [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) manufacturers

Hebei Dangtong Import and export Co LTD
Product
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4
Price
US $80.00/kilograms
Min. Order
10kilograms
Purity
99
Supply Ability
10
Release date
2023-03-01
Hebei Weibang Biotechnology Co., Ltd
Product
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4
Price
US $10.00/KG
Min. Order
100KG
Purity
99%
Supply Ability
100 mt
Release date
2024-11-29
R&D Scientific Inc.
Product
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II) dichloride 72287-26-4
Price
US $1250.00/g
Min. Order
1g
Purity
99 %
Supply Ability
500 Kg
Release date
2024-11-12

72287-26-4, [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)Related Search:


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