ChemicalBook > CAS DataBase List > 3-Nitrobenzyl bromide

3-Nitrobenzyl bromide

Product Name
3-Nitrobenzyl bromide
CAS No.
3958-57-4
Chemical Name
3-Nitrobenzyl bromide
Synonyms
1-(Bromomethyl)-3-nitrobenzene;NSC 66499;3-Nitrobromobenzyl;3-Nitrobenzyl bromid;M-NITROBENZYL BROMIDE;3-NITROBENZYL BROMIDE;α-Bromo-3-nitrotoluene;A-BROMO-M-NITROTOLUENE;a-Bromo-3-nitrotoluene;à-bromo-3-nitrotoluene
CBNumber
CB3402571
Molecular Formula
C7H6BrNO2
Formula Weight
216.03
MOL File
3958-57-4.mol
More
Less

3-Nitrobenzyl bromide Property

Melting point:
58-59 °C(lit.)
Boiling point:
153-154 °C (7 mmHg)
Density 
1.6841 (rough estimate)
refractive index 
1.6120 (estimate)
Flash point:
153-154°C/7mm
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Dichloromethane, Hot Ethanol
form 
Crystalline Powder or Crystals
color 
Yellow to light brown
Water Solubility 
insoluble
BRN 
742795
InChIKey
LNWXALCHPJANMJ-UHFFFAOYSA-N
CAS DataBase Reference
3958-57-4(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-(bromomethyl)-3-nitro-(3958-57-4)
EPA Substance Registry System
Benzene, 1-(bromomethyl)-3-nitro- (3958-57-4)
More
Less

Safety

Hazard Codes 
C
Risk Statements 
34-36/37
Safety Statements 
26-27-28-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29049090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
222518
Product name
3-Nitrobenzyl bromide
Purity
98%
Packaging
5g
Price
$43.1
Updated
2025/07/31
TCI Chemical
Product number
N0625
Product name
3-Nitrobenzyl Bromide
Purity
>98.0%(GC)
Packaging
10g
Price
$16
Updated
2025/07/31
TCI Chemical
Product number
N0625
Product name
3-Nitrobenzyl Bromide
Purity
>98.0%(GC)
Packaging
25g
Price
$27
Updated
2025/07/31
Usbiological
Product number
232095
Product name
3-Nitrobenzyl bromide 98+%
Packaging
5g
Price
$156
Updated
2021/12/16
TRC
Product number
N493635
Product name
3-Nitrobenzyl Bromide
Packaging
25g
Price
$710
Updated
2021/12/16
More
Less

3-Nitrobenzyl bromide Chemical Properties,Usage,Production

Chemical Properties

Pale Yellow Crystalline Solid

Uses

3-Nitrobenzyl bromide was used in the synthesis of 1,4-disubstituted imidazoles.

Synthesis

619-25-0

3958-57-4

General procedure for the synthesis of 3-nitrobenzyl bromide from 3-nitrobenzyl alcohol: Powdered 3-nitrobenzyl alcohol (0.5 mmol) was mixed with halosilanes (0.55 mmol) in a 4 mL screw-capped vial and stirred or heated at room temperature. The reaction mixture was kept at 70-75 °C for 0.5-24 h, during which the reaction progress was monitored by TLC. Upon completion of the reaction, the crude product was cooled to room temperature and the volatile by-product (TMS) was removed by evaporation under reduced pressure (30-35 °C).2O. The residue was confirmed by 1H NMR analysis. If necessary, the pure 3-nitrobenzyl bromide was purified by column chromatography on dry silica to obtain pure 3-nitrobenzyl bromide. Detailed experimental data, including isolated yields, spectral and other characterization data, are given in the Final Product Characterization section of the Supporting Information.

References

[1] Tetrahedron Letters, 2016, vol. 57, # 22, p. 2430 - 2433
[2] Organic Process Research and Development, 2002, vol. 6, # 2, p. 190 - 191
[3] Beilstein Journal of Organic Chemistry, 2014, vol. 10, p. 1397 - 1405
[4] Patent: WO2014/151871, 2014, A2. Location in patent: Page/Page column 59; 60
[5] Journal of the American Chemical Society, 1949, vol. 71, p. 2137,2138,2140

3-Nitrobenzyl bromide Preparation Products And Raw materials

Raw materials

Benzoyl peroxide N-Bromosuccinimide Carbon tetrachloride 3-Nitrotoluene

Preparation Products

3-NITROPHENYLACETIC ACID 3-NITROBENZYLAMINE
More
Less

3-Nitrobenzyl bromide Suppliers

Americas 1 Belgium 1 Canada 1 China 193 Europe 2 Germany 3 India 24 Japan 3 Slovakia 1 South Korea 1 Switzerland 4 Ukraine 1 United Kingdom 15 United States 39 Global 289
Xi'an Yutebang New Material Technology Co., Ltd.
Tel
029-84536388 18717328141
Fax
029-84536389
Email
ella@yutbon.com
Country
China
ProdList
174
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15838
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2338
Advantage
56
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-010-82967028 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12000
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9309
Advantage
66
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11035
Advantage
64
Shijiazhuang Outejia Chemical Co. LTD
Tel
0311-87795622
Fax
0311-87709298
Email
sales@adonghui.com
Country
China
ProdList
54
Advantage
64
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9883
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Chemsky（shanghai）International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
China DongFan Chemical Co.,LTD
Tel
86-0571-85151182
Fax
86-0571-85151182
Country
China
ProdList
5691
Advantage
66
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Sinopharm Chemical Reagent Co,Ltd.
Tel
86-21-63210123
Fax
86-21-63290778 86-21-63218885
Email
sj_scrc@sinopharm.com
Country
China
ProdList
9815
Advantage
79
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
18270980682
Fax
021 51613951
Email
mlcheng@sunwaypharm.cn
Country
China
ProdList
8669
Advantage
57
Nanjing Vital Chemical Co., Ltd.
Tel
Please Send Email 18652950785
Fax
025-87193546
Email
chemweiao@163.com
Country
China
ProdList
4378
Advantage
65
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Wuhan Haizheng Industry & Trade Development Co. Ltd
Tel
027-8866 0053/88660577/88660578
Fax
027-8899 1911
Country
China
ProdList
1073
Advantage
55
Shanghai civi chemical technology co.,Ltd
Tel
86-21-34053660
Fax
86-21-34053661
Email
sale@labgogo.com
Country
China
ProdList
9865
Advantage
52
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Shanghai Topbiochem Technology Co., Ltd
Tel
+86-21-60341587
Fax
+86-21-61294319
Email
sales@topbiochem.com
Country
China
ProdList
6175
Advantage
58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19913
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
18209
Advantage
56
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-6206333 13167063860
Fax
021-50323701
Email
anhua.mao@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
The future of Shanghai Industrial Co., Ltd.
Tel
021-61552785
Fax
021-55660885
Email
sales@shshiji.com
Country
China
ProdList
9546
Advantage
55
Shanghai Yolne Chemical Co., Ltd.
Tel
021-62960152
Fax
021-52212593
Email
934678158@qq.com
Country
China
ProdList
9899
Advantage
55
Hunan Furui Biopharma Technology Co., Ltd.
Tel
1822-2954721 15901640172
Fax
0731-57805668
Email
sales03@hn-furui.com
Country
China
ProdList
421
Advantage
55
Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.
Tel
+86-28-85122536 85324413
Fax
+86-28-85326443
Email
market@astatech.cn
Country
China
ProdList
8026
Advantage
55
Wuxi Zhangkun Biochemical Technology Co., Ltd.
Tel
+86 0510-85629785
Fax
+86 0510-85625359
Country
China
ProdList
2327
Advantage
58
Quzhou HuntBio Co., Ltd.
Tel
0571-64067827 13372408495
Fax
0571-64067827
Email
sales@huntchem.com
Country
China
ProdList
150
Advantage
60
Quzhou Juhua Friendship Co., Ltd
Tel
0570-3066667
Fax
0570-3063388
Country
China
ProdList
3930
Advantage
58
Shanghai JONLN Reagent Co., Ltd.
Tel
400-0066400 13621662912
Fax
021-55660885
Email
422131432@qq.com
Country
China
ProdList
9979
Advantage
55
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Chemwill Asia Co.,Ltd.
Tel
86-21-51086038
Fax
86-21-51861608
Country
China
ProdList
2930
Advantage
58
Zhengzhou HongSheng Pharmaceutical Co., Ltd.
Tel
0371-0371-13526885213 15637198702
Fax
0371-63709726
Email
hsyykjchem@163.com
Country
China
ProdList
3852
Advantage
58
ChemStrong Scientific Co.,Ltd
Tel
0755-0755-66853366 13670046396
Fax
0755-28363542
Email
sales@chem-strong.com
Country
China
ProdList
18333
Advantage
56
Wuxi Zhongkun Biochemical Technology Co., Ltd.
Tel
0510-85629785 18013409632
Fax
051085625359
Email
sales@reading-chemicals.com
Country
China
ProdList
15178
Advantage
58
Hunan HuaTeng Pharmaceutical Co., Ltd.,
Tel
400-8592883
Fax
0731-82251112
Email
sales@huatengsci.com
Country
China
ProdList
5872
Advantage
58
Credit-Chem Co., Ltd.
Tel
400-821-5857 021-64326257
Fax
021-64393586 QQ;2798200800
Email
credit-chem@foxmail.com
Country
China
ProdList
5219
Advantage
58
Shanghai YuLue Chemical Co., Ltd.
Tel
021-60345187 13671753212
Fax
021-34702061
Email
lzz841106@aliyun.com
Country
China
ProdList
10263
Advantage
55
Hangzhou J&H Chemical Co., Ltd.
Tel
0571-87396432
Fax
0571-87396431
Email
sales@jhechem.com
Country
China
ProdList
14912
Advantage
59
Shanghai Na Qian Chemical Technology Co. Ltd.
Tel
13598610367
Fax
QQ:2468833170
Email
2841375912@qq.com
Country
China
ProdList
2790
Advantage
52
Shanghai Song Yuan Chemical Technology Co., Ltd.
Tel
010-1234567 18521000990
Fax
86-021-33275113
Email
sonyuanchemical@163.com
Country
China
ProdList
6479
Advantage
50
More
Less

View Lastest Price from 3-Nitrobenzyl bromide manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
3-Nitrobenzyl bromide 3958-57-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-29
Xi'an Yutbon Pharmaceutical Technology Co., Ltd
Product
3-Nitrobenzyl bromide 3958-57-4
Price
US $0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200kgs
Release date
2020-09-28
Career Henan Chemical Co
Product
3-Nitrobenzyl bromide 3958-57-4
Price
US $1.00/KG
Min. Order
1KG
Purity
≥98%
Supply Ability
200kg
Release date
2019-08-30

3958-57-4, 3-Nitrobenzyl bromideRelated Search:

3-Bromobenzyl alcohol (3-NITROPHENYL)ACETIC ACID METHYL ESTER 3-Bromoanisole 3-Nitroacetophenone 3-Bromobenzyl bromide 3-Nitrobenzaldehyde 1-Bromo-3-iodobenzene 3-Bromobenzonitrile 3-Bromobenzaldehyde 4-Methoxy-2-nitrobenzyl bromide 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE,4,5-Dimethoxy-2-nitrobenzyl bromide 95%,4,5-dimenoxy-2-nitrobenzyl bromide 4-BROMO-2-NITROBENZYL BROMIDE 2-Fluoro-6-nitrobenzyl bromide 98%,2-FLUORO-6-NITROBENZYL BROMIDE 4-NITROBENZYL BROMOACETATE 2-Nitrobenzyl bromide, 98+%,O-NITROBENZYL BROMIDE,2-NITROBENZYL BROMIDE 3-FLUORO-4-NITROBENZYL BROMIDE 4-Nitrobenzyl bromide 3-Nitrotoluene

  • 3-(BroMoMethyl)-1-nitrobenzene
  • NSC 66499
  • 3-Nitrobenzyl bromid
  • α-Bromo-3-nitrotoluene
  • 3-Nitrobenzyl bromide,99%
  • A-BROMO-M-NITROTOLUENE
  • ALPHA-BROMO-3-NITROTOLUENE
  • ALPHA-BROMO-M-NITROTOLUENE
  • 3-NITROBENZYL BROMIDE
  • M-NITROBENZYL BROMIDE
  • 1-(bromomethyl)-3-nitro-benzen
  • 1-(Bromomethyl)-3-nitrobenzene
  • m-(Bromomethyl)nitrobenzene
  • m-Nitro-alpha-bromotoluene
  • Toluene, alpha-bromo-m-nitro-
  • a-Bromo-3-nitrotoluene
  • 3-Nitrobenzyl bromide, 98+%
  • à-bromo-3-nitrotoluene
  • α-bromo-m-nitrotoluene
  • 3-(Bromomethyl)nitrobenzene
  • m-Nitro-a-bromotoluene
  • 3-Nitro-1-(bromomethyl)benzene
  • 3-NitrobenzylBromide&gt
  • 3-Nitrobenzyl bromide, 98%, for synthesis
  • Benzene, 1-(bromomethyl)-3-nitro-
  • Rizatriptan Impurity 14
  • 3-Nitrobromobenzyl
  • Rizatriptan EP Impurity4
  • 3958-57-4
  • Organic Building Blocks
  • Nitrogen Compounds
  • Nitro Compounds
  • Building Blocks
  • Aromatics Compounds
  • Aromatics
  • Halides
  • Aromatic Halides (substituted)