ChemicalBook > CAS DataBase List > Methyl 2-aminothiazole-5-carboxylate

Methyl 2-aminothiazole-5-carboxylate

Product Name
Methyl 2-aminothiazole-5-carboxylate
CAS No.
6633-61-0
Chemical Name
Methyl 2-aminothiazole-5-carboxylate
Synonyms
NSC 42123;RARECHEM AL BF 1263;2-aminothiazole-5-carboxylate;2-aminothiazole-5-methyl formate;2-AMino-5-(Methoxycarbonyl)thiazole;Methyl 2-AMino-5-thiazolecarboxylate;METHYL 2-AMINOTHIAZOLE-5-CARBOXYLATE;Methyl 2-Aminothioazole-5-carboxylate;2-Amino-5-(methoxycarbonyl)-1,3-thiazole;Methyl 2-Aminothiazole-5-carboxylate >
CBNumber
CB3428872
Molecular Formula
C5H6N2O2S
Formula Weight
158.18
MOL File
6633-61-0.mol
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Methyl 2-aminothiazole-5-carboxylate Property

Melting point:
182-186°C
Boiling point:
298.7±13.0 °C(Predicted)
Density 
1.408±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
solubility 
DMSO (Slightly), Methanol (Slightly)
pka
3.02±0.10(Predicted)
form 
Solid
color 
Tan to Light Brown
InChI
InChI=1S/C5H6N2O2S/c1-9-4(8)3-2-7-5(6)10-3/h2H,1H3,(H2,6,7)
InChIKey
UJNNCGWBDJHCEM-UHFFFAOYSA-N
SMILES
S1C(C(OC)=O)=CN=C1N
CAS DataBase Reference
6633-61-0(CAS DataBase Reference)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
Hazard Note 
Harmful
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
M2598
Product name
Methyl 2-Aminothiazole-5-carboxylate
Purity
>98.0%(GC)
Packaging
1g
Price
$56
Updated
2025/07/31
TCI Chemical
Product number
M2598
Product name
Methyl 2-Aminothiazole-5-carboxylate
Purity
>98.0%(GC)
Packaging
5g
Price
$223
Updated
2025/07/31
TRC
Product number
M287280
Product name
Methyl 2-Aminothiazole-5-carboxylate
Packaging
5G
Price
$55
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK528814
Product name
Methyl 2-Aminothiazole-5-carboxylate
Purity
97%
Packaging
1g
Price
$250
Updated
2021/12/16
AK Scientific
Product number
B241
Product name
Methyl 2-Aminothiazole-5-carboxylate
Packaging
100g
Price
$307
Updated
2021/12/16
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Methyl 2-aminothiazole-5-carboxylate Chemical Properties,Usage,Production

Uses

Methyl 2-Aminothiazole-5-carboxylate (cas# 6633-61-0) is a compound useful in organic synthesis.

Synthesis

20656-61-5

17356-08-0

6633-61-0

General procedure for the synthesis of methyl 2-aminothiazole-5-carboxylate from methyl 2-chloro-3-oxopropionate and compound (CAS:17356-08-0): a mixture of 2.4 g of methyl 2-chloro-3-oxopropionate, 20 mL of water, and 1.75 g of thiourea was refluxed for 2 hours. Upon completion of the reaction, the mixture was cooled to room temperature, decolorized by adding 0.25 g of activated carbon (Norit) and filtered. The filtrate was adjusted to neutral pH by slowly adding 2.5 N sodium hydroxide solution to the filtrate.The precipitate was collected by filtration to give 1.23 g (44% yield) of methyl 2-aminothiazole-5-carboxylate.

References

[1] Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1991, # 3, p. 349 - 352
[2] Patent: WO2003/97616, 2003, A1. Location in patent: Page/Page column 26
[3] Journal of the American Chemical Society, 1952, vol. 74, p. 5799
[4] Ann. Rep. Res. Inst. Tuberc. Kanazawa Univ., 1953, vol. 11, # 2, p. 39,41
[5] Chem.Abstr., 1955, p. 8250

Methyl 2-aminothiazole-5-carboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl 2-aminothiazole-5-carboxylate manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
Methyl 2-aminothiazole-5-carboxylate 6633-61-0
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-09
Henan Aochuang Chemical Co.,Ltd.
Product
Methyl 2-aminothiazole-5-carboxylate 6633-61-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-10-10
Hebei Yanxi Chemical Co., Ltd.
Product
Methyl 2-aminothiazole-5-carboxylate 6633-61-0
Price
US $40.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-09-07

6633-61-0, Methyl 2-aminothiazole-5-carboxylateRelated Search:

Trimethoxymethane Methylparaben Bensulfuron methyl Methanol 2-(2-Aminothiazol-4-yl)glyoxylic acid Kresoxim-methyl Methyl anthranilate METSULFURON METHYL 2-Aminothiazole 2-AMINOTHIAZOLE-5-CARBOXYLIC ACID Methyl 2-bromobenzoate Methyl formate RESMETHRIN Methyl cellulose Methyl acrylate Methyl benzoate Ethyl 2-amino-1,3-thiazole-4-carboxylate Ethyl 2-aminothiazole-5-carboxylate

  • Methyl 2-AMino-5-thiazolecarboxylate
  • NSC 42123
  • 2-aminothiazole-5-carboxylate
  • 2-AMINO-THIAZOLE-5-CARBOXYLIC ACID METHYL ESTER
  • RARECHEM AL BF 1263
  • METHYL 2-AMINO-1,3-THIAZOLE-5-CARBOXYLATE
  • METHYL 2-AMINOTHIAZOLE-5-CARBOXYLATE
  • Methyl 2-Aminothioazole-5-carboxylate
  • Methyl 2-aminothiazole-5-carboxylate ,97%
  • 2-Amino-5-(methoxycarbonyl)-1,3-thiazole
  • 2-AMino-5-(Methoxycarbonyl)thiazole
  • 5-Thiazolecarboxylic acid, 2-amino-, methyl ester
  • Methyl 2-Aminothiazole-5-carboxylate &gt
  • Methyl 2-aminothiazole-5-carboxylate USP/EP/BP
  • 2-aminothiazole-5-methyl formate
  • 6633-61-0
  • Aromatics
  • Miscellaneous Reagents
  • Sulfur & Selenium Compounds
  • Amines
  • blocks
  • Carboxes
  • Thiazoles
  • Amino Acids and Derivatives
  • Heterocycles
  • 6633-61-0