2-FLUORO-5-METHOXYBENZALDEHYDE

Product Name: 2-FLUORO-5-METHOXYBENZALDEHYDE
CAS No.: 105728-90-3
Chemical Name: 2-FLUORO-5-METHOXYBENZALDEHYDE
Synonyms: uoro-5-methoxybenzaL;6-FLUORO-M-ANISALDEHYDE;Fluoro-5-Methoxybenzaldeh;6-Fluoro-m-anisaldehyde>2-FLUORO-5ETHOXYBENZALDEHYDE;2-FLUORO-5-METHOXYBENZALDEHYDE;1-tert-butoxycarb-3-pyrrolidone;Benzaldehyde,2-fluoro-5-methoxy-;2-Fluoro-5-methoxybenzaldehyde98%;2-Fluoro-5-methoxybenzaldehyde 98%
CBNumber: CB3482580
Molecular Formula: C8H7FO2
Formula Weight: 154.14
MOL File: 105728-90-3.mol

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2-FLUORO-5-METHOXYBENZALDEHYDE Property

Melting point:: 48-50 °C
Boiling point:: 229-230 °C (lit.)
Density: 1.237 g/mL at 25 °C (lit.)
refractive index: n20/D 1.532(lit.)
Flash point:: 226 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: powder to lump to clear liquid
color: White or Colorless to Yellow
Water Solubility: Slightly soluble in water.
Sensitive: Air Sensitive
BRN: 4379088
InChI: InChI=1S/C8H7FO2/c1-11-7-2-3-8(9)6(4-7)5-10/h2-5H,1H3
InChIKey: DKIQXHIAEMGZGO-UHFFFAOYSA-N
SMILES: C(=O)C1=CC(OC)=CC=C1F
CAS DataBase Reference: 105728-90-3(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-22
Safety Statements: 26-36-37/39
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29130000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 542644
Product name: 2-Fluoro-5-methoxybenzaldehyde
Purity: 97%
Packaging: 1g
Price: $27
Updated: 2023/06/20

Sigma-Aldrich

Product number: 542644
Product name: 2-Fluoro-5-methoxybenzaldehyde
Purity: 97%
Packaging: 5G
Price: $63
Updated: 2023/06/20

TCI Chemical

Product number: F0383
Product name: 6-Fluoro-m-anisaldehyde
Purity: >95.0%(GC)
Packaging: 5g
Price: $166
Updated: 2025/07/31

TCI Chemical

Product number: F0383
Product name: 6-Fluoro-m-anisaldehyde
Purity: >95.0%(GC)
Packaging: 25g
Price: $661
Updated: 2025/07/31

TRC

Product number: F599323
Product name: 2-Fluoro-5-methoxybenzaldehyde
Packaging: 50mg
Price: $60
Updated: 2021/12/16

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2-FLUORO-5-METHOXYBENZALDEHYDE Chemical Properties,Usage,Production

Chemical Properties

clear yellow liquid

Uses

2-Fluoro-5-methoxybenzaldehyde may be used in the synthesis of:

5,10,15,20-tetrakis(2-fluoro-5-methoxyphenyl)porphyrin
aryl(2-fluoro-5-methoxyphenyl)methanones
5′-methoxy-4-nitro-2,2′,5-trifluorobenzophenone
2-(2-fluoro-5-methoxybenzylidene)-1-(5-bromo-2-morpholinopyrimidin-4-yl) hydrazine

General Description

2-Fluoro-5-methoxybenzaldehyde can be prepared starting from 2-amino-5-methoxytoluene.

Synthesis

459-60-9

68-12-2

105728-90-3

1. In a dry reaction flask, 20 g of 4-fluoroanisole was dissolved in 230 ml of anhydrous tetrahydrofuran. 2. The reaction system was cooled to -78 °C. 3. 130 ml of 2.5 M n-butyllithium tetrahydrofuran solution was added dropwise, the temperature was maintained at -78 °C, and the reaction was stirred for 2 h. 4. N,N-dimethylformamide was added to the reaction system, which was then allowed to warm naturally to room temperature. 5. Stirring continued overnight at room temperature. 6. The reaction was allowed to warm naturally to room temperature. 5. Stirring was continued at room temperature overnight. 6. After completion of the reaction, the reaction was quenched by the addition of 1 N hydrochloric acid. 7. The reaction mixture was extracted with ethyl acetate, and the organic phases were combined. 8. The organic phases were dried with anhydrous sodium sulfate, filtered, and then concentrated to afford 17 g of 2-fluoro-5-methoxybenzaldehyde. 9. The reaction was continued at room temperature for 2 hours. 10.

References

[1] Tetrahedron Letters, 1992, vol. 33, # 49, p. 7499 - 7502
[2] Patent: CN107778264, 2018, A. Location in patent: Paragraph 0025; 0026
[3] Patent: CN107698535, 2018, A. Location in patent: Paragraph 0024; 0025; 0026
[4] Patent: CN108129415, 2018, A. Location in patent: Paragraph 0024-0026

2-FLUORO-5-METHOXYBENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-FLUORO-5-METHOXYBENZALDEHYDE Suppliers

Americas 1 Belgium 1 China 148 Europe 3 France 1 Germany 3 India 6 Italy 1 Japan 1 Switzerland 1 United Kingdom 16 United States 21 Global 203

Shanghai Harvest Chemical Industrial Co., Ltd.

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Zhuhai Aobokai Biomedical Technology Co., Ltd.

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Energy Chemical

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Capot Chemical Co., Ltd

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View Lastest Price from 2-FLUORO-5-METHOXYBENZALDEHYDE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 2-FLUORO-5-METHOXYBENZALDEHYDE 105728-90-3
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-11-12

Shaanxi Dideu Medichem Co. Ltd

Product: 2-Fluoro-5-methoxybenzaldehyde 105728-90-3
Price: US $0.00-0.00/KG
Min. Order: 10mg
Purity: 99%HPLC
Supply Ability: 2000tons
Release date: 2020-01-15

Career Henan Chemical Co

Product: 2-FLUORO-5-METHOXYBENZALDEHYDE 105728-90-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2019-07-11

105728-90-3, 2-FLUORO-5-METHOXYBENZALDEHYDERelated Search:

2,6-Difluoro-3-methoxyBenzaldehyde 2-FLUORO-5-(TRIFLUOROMETHOXY)BENZOIC ACID 2-FLUORO-5-(TRIFLUOROMETHOXY)BENZALDEHYDE 2-CHLORO-6-FLUORO-3-METHOXYBENZALDEHYDE 2,6-DIFLUORO-3-METHOXYBENZOIC ACID 6-FLUOROVERATRALDEHYDE 2-CHLORO-6-FLUORO-3-METHOXYBENZOIC ACID 2-FLUORO-4-METHOXYBENZALDEHYDE,2-Fluoro-4-methoxybenzaldehyde97%,2-Fluoro-4-methoxybenzaldehyde 97% 3-CHLORO-5-FLUORO-4-METHOXYBENZALDEHYDE 6-CHLORO-2-FLUORO-3-METHOXYBENZALDEHYDE 4-FLUORO-3-METHOXYBENZALDEHYDE,4-Fluoro-3-methoxybenzaldehyde97%,4-Fluoro-3-methoxybenzaldehyde 97% 3-Fluoro-5-methoxybenzaldehyde 97%,3-Fluoro-5-methoxybenzaldehyde97% 3-FLUORO-4-METHOXYBENZALDEHYDE,3-Fluoro-4-Methoxybenzaldehyde/3-Fluoro-P-Anisaldehyde/M-Fluoro-P-Anisaldehyde/ 4-FLUORO-2-METHOXYBENZALDEHYDE 3-FLUORO-2-METHOXYBENZALDEHYDE 2-Fluoro-3-methoxybenzaldehyde 96%,2-Fluoro-3-methoxybenzaldehyde96%,2-FLUORO-3-METHOXYBENZALDEHYDE 2-FLUORO-6-METHOXYBENZALDEHYDE,2-Fluoro-6-methoxybenzaldehyde99%,2-Fluoro-6-methoxybenzaldehyde 99% 5-FLUORO-2-METHOXYBENZALDEHYDE

Benzaldehyde,2-fluoro-5-methoxy-

2-FLUORO-5ETHOXYBENZALDEHYDE

4-Fluoro-3-formylanisole, 6-Fluoro-m-anisaldehyde

2-Fluoro-5-methoxybenzaldehyde 98%

2-Fluoro-5-methoxybenzaldehyde98%

Fluoro-5-Methoxybenzaldeh

6-FLUORO-M-ANISALDEHYDE

2-FLUORO-5-METHOXYBENZALDEHYDE

1-tert-butoxycarb-3-pyrrolidone

6-Fluoro-m-anisaldehyde&gt

uoro-5-methoxybenzaL

105728-90-3

Aldehydes

Organic Building Blocks

Building Blocks

C8

Carbonyl Compounds

Aromatic Aldehydes & Derivatives (substituted)

Benzaldehyde

Adehydes, Acetals & Ketones

Anisoles, Alkyloxy Compounds & Phenylacetates

Fluorine Compounds

Benzenes