2,4,6-Trimethyliodobenzene

Product Name: 2,4,6-Trimethyliodobenzene
CAS No.: 4028-63-1
Chemical Name: 2,4,6-Trimethyliodobenzene
Synonyms: DF77;SKL669;Mesityliodine;MESITYL IODIDE;IODOMESITYLENE;2-Iodmesitylen;2-IODOMESITYLENE;MesitylIodide>2-Iodo-3-isopropyltoluene;2,4,6-TRIMETHYLIODOBENZENE
CBNumber: CB3674064
Molecular Formula: C9H11I
Formula Weight: 246.09
MOL File: 4028-63-1.mol

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2,4,6-Trimethyliodobenzene Property

Melting point:: 28-32 °C
Boiling point:: 250 °C
Density: 1.5100 (rough estimate)
refractive index: 1.5905 (estimate)
storage temp.: 2-8°C(protect from light)
form: powder to lump to clear liquid
color: White or Colorless to Light yellow
Sensitive: Light Sensitive
BRN: 1860064
InChIKey: GTPNXFKONRIHRW-UHFFFAOYSA-N
CAS DataBase Reference: 4028-63-1(CAS DataBase Reference)
NIST Chemistry Reference: 2,4,6-Trimethyliodobenzene(4028-63-1)

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Safety

Risk Statements: 36/37/38
Safety Statements: 24/25-36/37/39-24/28
HazardClass: LIGHT SENSITIVE
HS Code: 29039990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H319Causes serious eye irritation
Precautionary statements: P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: R258377
Product name: 2-IODO-1,3,5-TRIMETHYL-BENZENE
Purity: Aldrich
Packaging: 50mg
Price: $29.8
Updated: 2024/03/01

TCI Chemical

Product number: I0478
Product name: Mesityl Iodide
Packaging: 5G
Price: $18
Updated: 2024/03/01

TCI Chemical

Product number: I0478
Product name: Mesityl Iodide
Packaging: 25G
Price: $62
Updated: 2024/03/01

Alfa Aesar

Product number: A15360
Product name: 2-Iodo-1,3,5-trimethylbenzene, 98%
Packaging: 5g
Price: $51.65
Updated: 2024/03/01

Alfa Aesar

Product number: A15360
Product name: 2-Iodo-1,3,5-trimethylbenzene, 98%
Packaging: 25g
Price: $196.65
Updated: 2024/03/01

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2,4,6-Trimethyliodobenzene Chemical Properties,Usage,Production

Chemical Properties

yellow crystalline low melting solid

Uses

suzuki reaction

Uses

Iodomesitylene can be used as a good catalyst for living radical polymerization due to its good molecular weight distribution.

Synthesis Reference(s)

Tetrahedron Letters, 10, p. 2427, 1969 DOI: 10.1017/S0009838800024678

Hazard

May cause eye, skin, and respiratory tract irritation. Light sensitive.

Health effects

Eye: May cause eye irritation.
Skin: May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.

Synthesis

The synthesis of 2,4,6-Trimethyliodobenzene is as follows:
A 10 mL glass flask equipped with a magnetic stir bar wascharged with a methyl ketone (1 mmol) and dissolved in MeCN (2 mL). To thermostat solution NH4NO3 (10-25 mol%), I2 (50 mol%) and H2SO4 (aqueous 96% solution, 10-20 mol%) were added and the flask was furtherequipped with a balloon filled with air (1 L) and magnetically stirred at 60 C.The consumption of starting material was monitored by TLC. After completion of the reaction, the mixture was cooled to room temperature, diluted withEtOAc (10 mL), and insoluble material identified as ammonium sulfate filtered off. The filtrate neutralized with NaHCO3 (aqueous 10% solution, 2 mL)and Na2S2O3 (aqueous 10% solution, 2 mL) and phase was separated. The waterphase was washed with EtOAc additionally two times (2 5 mL). The combined organic phase was dried over anhydrous Na2SO4 and the solvent distilled under reduced pressure. The crude product obtained was analyzed by 1H NMR. Finally, the crude product was purified using column chromatography (SiO2, n-hexane/CH2Cl2 elution) and preparative thin layer chromatography to afford purematerial.

storage

Store in a cool, dry place. Store in a tightly closed container. Store protected from light.

2,4,6-Trimethyliodobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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2,4,6-Trimethyliodobenzene Suppliers

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View Lastest Price from 2,4,6-Trimethyliodobenzene manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: 2,4,6-Trimethyliodobenzene 4028-63-1
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-11-11

Shaanxi Dideu Medichem Co. Ltd

Product: 2,4,6-Trimethyliodobenzene 4028-63-1
Price: US $1.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100000KG
Release date: 2024-07-26

Henan Fengda Chemical Co., Ltd

Product: 2,4,6-Trimethyliodobenzene 4028-63-1
Price: US $101.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-28

4028-63-1, 2,4,6-TrimethyliodobenzeneRelated Search:

(Diacetoxyiodo)benzene Iodotrimethylsilane 4'-(Trifluoromethyl)acetophenone Mesitylene Trimethylsulfoxonium iodide Tris(hydroxymethyl)aminomethane 1,2-Diiodobenzene 2-(Trifluoromethyl)benzaldehyde 5-Methyl-1H-benzotriazole Trimethylsilylacetylene 2-(Trifluoromethyl)benzoic acid 3-(Trifluoromethyl)benzaldehyde Trimethylhydroquinone 1,4-Diiodobenzene Trimethylolpropane TRIMETHYL PHLOROGLUCINOL 5-(TERT-BUTYL)-2-IODO-1,3-DIMETHYLBENZENE PENTAMETHYLIODOBENZENE

Iodomesitylene~2,4,6-Trimethyliodobenzene

2,4,6-TRIMETHYLIODOBENZENE (2-IODOMESITYLENE)

2,4,6-Trimethylphenyl iodide

Mesityliodine

2,4,6-Trimethyliodobenzene,98%

2-Iodo-3-isopropyltoluene

2,4,6-Trimethyliodobenzene 98%

2-Iodo-1,3,5-trimethylbenzene, 2-Iodomesitylene, Mesityl iodide

2-Iodomesitylene 2-Iodo-1,3,5-trimethylbenzene

2-IODO-1,3,5-TRIMETHYLBENZENE

2-IODOMESITYLENE

2,4,6-TRIMETHYLIODOBENZENE

1-IODO-2,4,6-TRIMETHYLBENZENE

MESITYL IODIDE

IODOMESITYLENE

Benzene, 2-iodo-1,3,5-trimethyl-

Iodo-2,4,6-trimethylbenzene

2-Iodmesitylen

2,4,6-Trimethyliodobenzene, 97%, for synthesis

MesitylIodide&gt

SKL669

DF77

4028-63-1

C9H11I

Aromatic Halides (substituted)