ChemicalBook > CAS DataBase List > Borane-methyl sulfide complex

Borane-methyl sulfide complex

Product Name
Borane-methyl sulfide complex
CAS No.
13292-87-0
Chemical Name
Borane-methyl sulfide complex
Synonyms
BMS;Dimethylsulfide borane complex;(Dimethyl sulfide)trihydroboron;DMSB;borane-methyl sulfide;DIMETHYL SULFIDE BORANE;BORANE-DIMETHYLSULFIDE;BORANE-DIMETHYLSULFIDE COMPLEX;borane dimethyl sulfide complex solution;Borane dimethyL
CBNumber
CB3700534
Molecular Formula
C2H10BS
Formula Weight
76.97
MOL File
13292-87-0.mol
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Borane-methyl sulfide complex Property

Melting point:
-40--37°C
Boiling point:
~34 °C
Density 
1.287 g/mL at 25 °C
refractive index 
1.4570
Flash point:
65 °F
storage temp. 
2-8°C
solubility 
Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents.
form 
Solution
Specific Gravity
0.801
color 
Colorless to pale yellow
Water Solubility 
reacts
Sensitive 
Air & Moisture Sensitive
BRN 
3663489
InChIKey
RMHDLBZYPISZOI-UHFFFAOYSA-N
CAS DataBase Reference
13292-87-0(CAS DataBase Reference)
NIST Chemistry Reference
Borane-methyl sulfide complex(13292-87-0)
EPA Substance Registry System
Boron, trihydro[thiobis[methane]]-, (T-4)- (13292-87-0)
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Safety

Hazard Codes 
F+,Xn,F,Xi
Risk Statements 
12-14/15-19-20/22-37/38-41-67-65-63-48/20-38-11-22-14-40-36-21-36/37/38-37
Safety Statements 
36/37-62-36/39-33-26-23-16-36-24/25-7/8-43-39-36/37/39
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
3
RTECS 
PV5080000
F 
10-13-23
TSCA 
Yes
HazardClass 
4.3
PackingGroup 
II
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H260In contact with water releases flammable gases which may ignite spontaneously

H318Causes serious eye damage

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
192120
Product name
Borane dimethyl sulfide complex solution
Purity
2.0?M in THF
Packaging
4X25ML
Price
$80.3
Updated
2024/03/01
Sigma-Aldrich
Product number
179825
Product name
Borane dimethyl sulfide complex
Packaging
25ml
Price
$80.6
Updated
2024/03/01
Sigma-Aldrich
Product number
179825
Product name
Borane dimethyl sulfide complex
Packaging
4x25ml
Price
$153
Updated
2024/03/01
TCI Chemical
Product number
D1843
Product name
Dimethyl Sulfide Borane
Purity
>90.0%(T)
Packaging
25mL
Price
$40
Updated
2024/03/01
TCI Chemical
Product number
D1843
Product name
Dimethyl Sulfide Borane
Purity
>90.0%(T)
Packaging
100mL
Price
$116
Updated
2024/03/01
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Borane-methyl sulfide complex Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow solution

Uses

Borane-dimethyl sulfide complex is used for hydroborations and reductions. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.

Uses

Borane-dimethyl sulfide (BH3 Me2S) can be used as a reagent:

  • For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate.
  • For the conversion of ozonides to alcohols.
  • In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols.
  • For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C3-symmetric tripodal hydroxyamide as a ligand.
  • For the hydroboration reduction and other applications.
  • With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.

General Description

Borane dimethyl sulfide complex (BMS) acts as a highly efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α-hydroxy esters. Asymmetric borane reduction of a variety of prochiral ketones with BMS using spiroborate esters as catalyst has been reported.

Borane-methyl sulfide complex Preparation Products And Raw materials

Raw materials

Preparation Products

4H-AMINO-6-BROMO-2,3-DIHYDROTHIOCHROMEN-1,1-DIOXIDE Ethylferrocene 5'-BROMO-2'-CHLOROACETOPHENONE 1,1'-DI-N-BUTYLFERROCENE 4-Hydroxy-6-bromo-2,3-dihydrothiochromen-1,1-dioxide Butylferrocene 3-Nitrobenzylammonium hydrochloride (S)-5-Hydroxymethyldihydrofuran-2-one 1,1'-DIMETHYLFERROCENE Pinacolborane 3-(4-NITRO-PHENYL)-PROPAN-1-OL
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View Lastest Price from Borane-methyl sulfide complex manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
Borane-Methyl Sulfide Complex 13292-87-0
Price
US $10.00/kg
Min. Order
1kg
Purity
99.6%
Supply Ability
100000
Release date
2024-04-25
Hebei Guanlang Biotechnology Co,.LTD
Product
Borane-Methyl Sulfide Complex 13292-87-0
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2023-07-19
Henan Aochuang Chemical Co.,Ltd.
Product
Borane-methyl sulfide complex 13292-87-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-26

13292-87-0, Borane-methyl sulfide complexRelated Search:

Hydrogen Sulfide Sodium sulfide Dimethyl fumarate Methoxydiethylborane tert-Butyl methyl ether (2-Methoxyethyl)benzene N,N-Dimethylformamide CHLOROMETHYL METHYL SULFIDE (+)-Diisopinocampheyl chloroborane ETHANE Borane-pyridine complex Tribenuron methyl Dimethyl sulfate Dimethyl phthalate Thioanisole CARBONYL SULFIDE Poly(tetrahydrofuran) Dimethylaminoborane

  • Borane diMethyl sulfide coMplex technical, >90% in diMethyl sulfide
  • Borane diMethyl sulfide coMplex, 1.0 M solution in Methylene chloride, SpcSeal
  • Borane diMethyl sulfide coMplex, 10.0 M solution in DMS, SpcSeal
  • Borane diMethyl sulfide coMplex, 2.0 M solution in THF, SpcSeal
  • Borane diMethyl sulfide coMplex, 2.0 M solution in toluene, SpcSeal
  • Borane dimethyl sulfide complex solution 1.0 M in methylene chloride
  • Borane diMethyl sulfide coMplex, 5.0 M solution in diethyl ether, SpcSeal
  • Trihydro[thiobis[methane]]boron
  • Borane dimethyl sulfide complex solution 2.0 M in diethyl ether
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  • dimethylsulfideborane,dmsb,in
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  • Methyl sulfide, compd. with borane (1:1)
  • methylsulfide,compd.withborane(1:1)
  • (Dimethyl sulfide)trihydroboron
  • BMS~Borane-methyl sulphide~Dimethyl sulphide borane
  • dimethyl sulphide--borane
  • BORANE DIMETHYL SULFIDE COMPLEX SOL., ~5 M IN DIETHYL ETH.
  • BORANE DIMETHYL SULFIDE COMPLEX SOL., ~2 M IN THF
  • BORANE-METHYL SULFIDE COMPLEX, 2.0M SOLU TION IN TOLUENE
  • BORANE-METHYL SULFIDE COMPLEX, 5.0M SOLU TION IN DIETHYL ETHER
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  • BORANE-METHYL SULFIDE COMPLEX, 2.0M SOLU
  • BORANE-METHYL SULFIDE COMPLEX, 1.0M SOLU TION IN DICHLOROMETHANE
  • BORANE DIMETHYL SULFIDE COMPLEX, ~95% IN DIMETHYL SULFIDE
  • Borane-methyl sulfide complex, 1M solution in methylene chloride
  • Borane-dimethyl sulfide complex, 2M in tetrahydrofuran, packaged under Argon in resealable ChemSeal^t bottles
  • Borane-dimethyl sulfide complex, packaged under Argon in resealable ChemSeal^t bottles
  • Borane-dimethyl sulfide complex, nominally 5M in ether, packaged under Argon in resealable ChemSeal^t bottles
  • Borane-dimethyl sulfide complex, 2M in toluene, packaged under Argon in resealable ChemSeal^t bottle
  • Borane-methyl sulphide
  • Borane-methyl sulfide complex,94%
  • Borane-methyl sulfide complex, 2M solution in tetrahydrofuran, AcroSeal?
  • Borane-dimethyl sulfide complex, 2M in THF, packaged under Argon in resealable ChemSealTM bottles
  • Borane-dimethyl sulfide complex, 2M in THF, packaged under Argon in resealable ChemSeal^t bottles
  • Borane-dimethylsulfide complex, 2.0 M solution in THF
  • Borane Dimethyl Sulfide Complex (BMS), 2M in THF
  • Borane dimethyl sulfide complex [2M solution in THF]
  • Borane-dimethyl sulfide complex [10M]
  • Borane dimethyl sulfide complex [10M in DMS]
  • Borane-methyl sulfide complex, 1M solution in methylene chloride, AcroSeal
  • Borane-methyl sulfide complex, 2M solution in THF, AcroSeal
  • METHYL SULFIDE BORANE
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  • DMSB
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  • BORANE DIMETHYL SULPHIDE COMPLEX
  • BMS
  • Borane, compd. with dimethylsulfide
  • borane,compd.withdimethylsulfide
  • Boron, trihydro[thiobis[methane]]-, (T-4)-
  • Boron,trihydro[thiobis[methane]]-,(T-4)-
  • dimethylsulfide-borane(3)(1:1)
  • dimethylsulfideborane,dmsb
  • Borane Methylsulfide Complex-D3
  • Borane,dimethylsulfidecomplex(contains5-6%excessdimethylsulfide)