1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE
- Product Name
- 1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE
- CAS No.
- 154471-65-5
- Chemical Name
- 1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE
- Synonyms
- 1-methyl-3-trifluoromethylpyrazol;1-Methyl-3-(trifluoroMethyl)pyrazole;1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE;1H-Pyrazole, 1-methyl-3-(trifluoromethyl)-;1-Methyl-3-trifluoromethyl-1H-pyrazole ,97%
- CBNumber
- CB3759512
- Molecular Formula
- C5H5F3N2
- Formula Weight
- 150.1
- MOL File
- 154471-65-5.mol
1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE Property
- Boiling point:
- 137.7±35.0 °C(Predicted)
- Density
- 1.32g/ml
- storage temp.
- 2-8°C
- pka
- -0.71±0.10(Predicted)
- Appearance
- Colorless to light yellow Liquid
- InChI
- InChI=1S/C5H5F3N2/c1-10-3-2-4(9-10)5(6,7)8/h2-3H,1H3
- InChIKey
- MQSLINQSJFALSP-UHFFFAOYSA-N
- SMILES
- N1(C)C=CC(C(F)(F)F)=N1
Safety
- Safety Statements
- 22-24/25
- HS Code
- 29331990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- M332173
- Product name
- 1-Methyl-3-(trifluoromethyl)-1H-pyrazole
- Packaging
- 500mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- HCH0016506
- Product name
- 1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE
- Purity
- 95.00%
- Packaging
- 250MG
- Price
- $146.06
- Updated
- 2021/12/16
- Product number
- JK135649
- Product name
- 1-Methyl-3-trifluoromethyl-1H-pyrazole
- Purity
- 97%
- Packaging
- 1g
- Price
- $149
- Updated
- 2021/12/16
- Product number
- PC31708
- Product name
- 1-Methyl-3-(trifluoromethyl)-1H-pyrazole
- Packaging
- 1g
- Price
- $151
- Updated
- 2021/12/16
- Product number
- 3H32-3-U9
- Product name
- 1-Methyl-3-(trifluoromethyl)-1H-pyrazole
- Packaging
- 1g
- Price
- $167
- Updated
- 2021/12/16
1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE Chemical Properties,Usage,Production
Chemical Properties
Colorless liquid
Synthesis
59938-06-6
60-34-4
153085-15-5
154471-65-5
(E)-1-ethoxy-3-trifluoromethyl-1,3-butadiene (ETFBO, 270 g, 1.61 mol, 1.00 eq.) was dissolved in methanol (750 mL). The resulting solution was cooled in an ice-water bath, followed by the slow dropwise addition of methylhydrazine (88.3 mL, 77.7 g, 1.69 mol, 1.05 eq.) over 20 min. The reaction mixture was heated to 55 °C and stirred in dry air (via a drying tube) at this temperature for 20 hours. Upon completion of the reaction, the solvent was removed by rotary evaporation and the residue was subjected to decompression distillation: the first fraction was collected at 150 mbar, bath temperature of 130 °C, and collection temperature of 73-85 °C to give 129 g of the mixture of isomers, and the second fraction was collected at 70 mbar, bath temperature of 150 °C, and collection temperature of 75-85 °C to give 24 g of 1 -methyl-3-trifluoromethyl-1H-pyrazole. the total yield was 153 g (1.02 mol), 63% yield.
References
[1] Patent: EP2662359, 2013, A1. Location in patent: Page/Page column 6; 10
1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE Preparation Products And Raw materials
Raw materials
Preparation Products
1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE Suppliers
- Tel
- --
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- Country
- Belgium
- ProdList
- 6293
- Advantage
- 73
View Lastest Price from 1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE manufacturers
- Product
- 1-METHYL-3-(TRIFLUOROMETHYL)-1H-PYRAZOLE 154471-65-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2020-01-02