Cyclobutanecarboxylic acid, 3-methylene-, methyl ester (6CI,8CI,9CI)
- Product Name
- Cyclobutanecarboxylic acid, 3-methylene-, methyl ester (6CI,8CI,9CI)
- CAS No.
- 15963-40-3
- Chemical Name
- Cyclobutanecarboxylic acid, 3-methylene-, methyl ester (6CI,8CI,9CI)
- Synonyms
- methyl 3-methylenecyclobutane-1-carboxylate;Methyl 3-Methylenecyclobutanecarboxylate;methyl 3-methylidenecyclobutane-1-carboxylate;3-Methylenecyclobutanecarboxylic acid methyl ester;Methyl 3-methylenecyclobutanecarboxylate - [M12361];Cyclobutanecarboxylic acid, 3-methylene-, methyl ester;Cyclobutanecarboxylic acid, 3-methylene-, methyl ester (6CI,8CI,9CI)
- CBNumber
- CB41059728
- Molecular Formula
- C7H10O2
- Formula Weight
- 126.15
- MOL File
- 15963-40-3.mol
Cyclobutanecarboxylic acid, 3-methylene-, methyl ester (6CI,8CI,9CI) Property
- Boiling point:
- 56-59 °C(Press: 20 Torr)
- Density
- 1.01±0.1 g/cm3(Predicted)
- storage temp.
- 2-8°C
- form
- liquid
- color
- Clear, colourless
- InChI
- InChI=1S/C7H10O2/c1-5-3-6(4-5)7(8)9-2/h6H,1,3-4H2,2H3
- InChIKey
- OSWTXCSCDKIANQ-UHFFFAOYSA-N
- SMILES
- C1(C(OC)=O)CC(=C)C1
Safety
- HS Code
- 2916200090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
N-Bromosuccinimide Price
- Product number
- M338533
- Product name
- Methyl3-Methylenecyclobutanecarboxylate
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- M338533
- Product name
- Methyl3-Methylenecyclobutanecarboxylate
- Packaging
- 500mg
- Price
- $200
- Updated
- 2021/12/16
- Product number
- 2323-1-39
- Product name
- Methyl 3-methylidenecyclobutane-1-carboxylate
- Purity
- 97.0%
- Packaging
- 1g
- Price
- $340
- Updated
- 2021/12/16
- Product number
- 114723
- Product name
- Methyl 3-methylenecyclobutanecarboxylate
- Purity
- 97%
- Packaging
- 5g
- Price
- $535
- Updated
- 2021/12/16
- Product number
- 2323-1-39
- Product name
- Methyl 3-methylidenecyclobutane-1-carboxylate
- Purity
- 97.0%
- Packaging
- 5G
- Price
- $595
- Updated
- 2021/12/16
Cyclobutanecarboxylic acid, 3-methylene-, methyl ester (6CI,8CI,9CI) Chemical Properties,Usage,Production
Synthesis
15760-36-8
77-78-1
15963-40-3
3-Methylenecyclobutanecarboxylic acid (11.0 g, 98.1 mmol) and potassium carbonate (27.1 g, 196 mmol) were dissolved in acetone (100 mL), and dimethyl sulfate (14.8 g, 117 mmol) was slowly added at 25 °C. The reaction mixture was heated to 70 °C and maintained for 12 hours. Upon completion of the reaction, water (20 mL) was added to quench the reaction, followed by extraction with dichloromethane (30 mL x 3). The organic phases were combined, dried over anhydrous sodium sulfate, filtered, and the filtrate was concentrated under reduced pressure to afford methyl 3-methylenecyclobutanecarboxylate (12.0 g, yellow oil) in 97% yield.
References
[1] Patent: CN105566324, 2016, A. Location in patent: Paragraph 0197; 0201; 0202; 0203
[2] Patent: WO2015/66413, 2015, A1. Location in patent: Page/Page column 131
[3] Patent: WO2012/154204, 2012, A1. Location in patent: Page/Page column 67; 68
[4] Patent: WO2015/180612, 2015, A1. Location in patent: Page/Page column 60
[5] Patent: WO2015/196071, A1. Location in patent: Paragraph 0174
Cyclobutanecarboxylic acid, 3-methylene-, methyl ester (6CI,8CI,9CI) Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Cyclobutanecarboxylic acid, 3-methylene-, methyl ester (6CI,8CI,9CI) manufacturers
- Product
- Cyclobutanecarboxylic acid, 3-methylene-, methyl ester (6CI,8CI,9CI) 15963-40-3
- Price
- US $1.00/KG
- Min. Order
- 1g
- Purity
- 98%min
- Supply Ability
- ask
- Release date
- 2019-12-20