Cyclopropanecarboxaldehyde

Product Name: Cyclopropanecarboxaldehyde
CAS No.: 1489-69-6
Chemical Name: Cyclopropanecarboxaldehyde
Synonyms: Cyclopropanecarbaldehyde;Formylcyclopropane;Cyclopropylmethanal;Cyclopropylcarboxaldehyde;1-Cyclopropanecarbaldehyde;Cyclopropane-1-carbaldehyde;Cyclopropanecarboxyaldehyde;opropanecarbaL;RARECHEM AK ML 0578;Cyclopropanecarboxal
CBNumber: CB4132338
Molecular Formula: C4H6O
Formula Weight: 70.09
MOL File: 1489-69-6.mol

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Cyclopropanecarboxaldehyde Property

Boiling point:: 98-101 °C (lit.)
Density: 0.938 g/mL at 25 °C (lit.)
refractive index: n20/D 1.4298(lit.)
Flash point:: 45 °F
storage temp.: 2-8°C
solubility: soluble in Chloroform
form: clear liquid
color: Colorless to Light orange to Yellow
Water Solubility: Soluble in water.
Sensitive: Air Sensitive
BRN: 906781
Stability:: Volatile
InChIKey: JMYVMOUINOAAPA-UHFFFAOYSA-N
CAS DataBase Reference: 1489-69-6(CAS DataBase Reference)
NIST Chemistry Reference: Cyclopropanecarboxaldehyde(1489-69-6)
EPA Substance Registry System: Cyclopropanecarboxaldehyde (1489-69-6)

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Safety

Hazard Codes: F,C
Risk Statements: 11-34
Safety Statements: 16-26-36/37/39-45
RIDADR: UN 2924 3/PG 2
WGK Germany: 3
RTECS: GZ1005000
TSCA: Yes
HazardClass: 3
PackingGroup: II
HS Code: 29122990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 272213
Product name: Cyclopropanecarboxaldehyde
Purity: 98%
Packaging: 1g
Price: $47.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: 272213
Product name: Cyclopropanecarboxaldehyde
Purity: 98%
Packaging: 5g
Price: $126
Updated: 2024/03/01

TCI Chemical

Product number: C1707
Product name: Cyclopropanecarboxaldehyde
Purity: >97.0%(GC)
Packaging: 1g
Price: $38
Updated: 2024/03/01

TCI Chemical

Product number: C1707
Product name: Cyclopropanecarboxaldehyde
Purity: >97.0%(GC)
Packaging: 5g
Price: $109
Updated: 2024/03/01

Alfa Aesar

Product number: L14931
Product name: Cyclopropanecarboxaldehyde, 98%
Packaging: 1g
Price: $36.65
Updated: 2024/03/01

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Cyclopropanecarboxaldehyde Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

Cyclopropanecarboxaldehyde reacts with Grignard or organolithium reagents to give the expected secondary alcohols. These are susceptible to ring opening in the presence of HBr, providing stereoselective access to homoallylic bromides. It is also used in the synthesis of eta(2)-enonenickel complexes by reacting with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) and to prepare a cyclopropylidene tetralone which underwent an enantioselective palladium-catalyzed [3+2] TMM cycloaddition providing a chiral spiro-fused cyclopentene.

Application

Cyclopropanecarboxaldehyde is a reagent in the preparation of N-alkylphenylalaninamides of pyridinylphenyland oxobipyridinylamines as human GPR 142 agonists for potential use as anti-diabetic agents and the cytochrome P 450 inhibition.

Preparation

Cyclopropanecarboxaldehyde is prepared by reaction of cyclopropylmethanol. The reaction needs reagent pyridinium chlorochromate and solvent CH2Cl2 with other condition of ambient temperature for 3 hours. The yield is about 60%.

Definition

ChEBI: Cyclopropanecarbaldehyde is an organooxygen compound.

Cyclopropanecarboxaldehyde Preparation Products And Raw materials

Raw materials

Cyclopropyl carbinol Sodium hypochlorite Potassium bromide Pyridinium chlorochromate Triethylamine Potassium Phosphate Monobasic TEMPO Dichloromethane Oxalyl chloride Cyclopropyl bromide Magnesium sulfate

Preparation Products

1-(CYCLOPROPYLMETHYL)PIPERAZINE N-Boc-4-(Cyclopropylmethyl)piperazine

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Cyclopropanecarboxaldehyde Suppliers

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View Lastest Price from Cyclopropanecarboxaldehyde manufacturers

Hebei Mujin Biotechnology Co.,Ltd

Product: Cyclopropanecarboxaldehyde 1489-69-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-07-03

Hebei Mujin Biotechnology Co.,Ltd

Product: Cyclopropanecarboxaldehyde 1489-69-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-07-24

Hebei Chuanghai Biotechnology Co., Ltd

Product: Cyclopropanecarboxaldehyde 1489-69-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2023-04-28

1489-69-6, CyclopropanecarboxaldehydeRelated Search:

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CYCLOPROPANECARBOXALDEHYDE

RARECHEM AK ML 0578

Cyclopropanecarbaldehyde

Cyclopropylcarboxaldehyde

Cyclopropylmethanal

Cyclopropanecarboxyaldehyde

Cyclopropanecarboxyldehyde

Cyclopropanecarboxaldehyde ,98%

1-Cyclopropanecarbaldehyde

Cyclopropane-1-carbaldehyde

Cyclopropanecarboxaldehyde, 98% 5GR

Cyclopropanecarboxal

Formylcyclopropane

Cyclopropanecarboxaldehyde 98%

Cyclopropanecarboxaldehyde &gt

opropanecarbaL

Cyclopropyl formaldehyde

1489-69-6

1849-69-6

C3H5CHO

ALDEHYDE

Aldehydes

Organic Building Blocks

Building Blocks

C1 to C6

Carbonyl Compounds

Pharmaceutical intermdiate

Pharmaceutical Intermediates

Cyclopropanes

Simple 3-Membered Ring Compounds

Aldehydes

C1 to C6

Carbonyl Compounds

bc0001