ChemicalBook > CAS DataBase List > Ethyl 1-benzyl-3-oxopiperidine-4-carboxylate

Ethyl 1-benzyl-3-oxopiperidine-4-carboxylate

Product Name
Ethyl 1-benzyl-3-oxopiperidine-4-carboxylate
CAS No.
39514-19-7
Chemical Name
Ethyl 1-benzyl-3-oxopiperidine-4-carboxylate
Synonyms
ethyl 1-benzyl-3-oxopiperidine-4-carboxylate;1-benzyl-3-oxopiperidine-4-carboxylate;N-BENZYL-4-CARBETHOXY-3-PIPERIDONE;N-Benzyl-3-oxo-4-piperidinecarboxylate;Ethyl 1-benzyl-3-oxo-4-piperidinecarboxylate;ETHYL N-BENZYL-3-KETOPIPERIDINE-4-CARBOXYLATE;1-BENZYL-3-OXO-PIPERIDINE-4-CARBOXYLIC ACID ETH;Ethyl 1-benzyl-3-oxopiperidine-4-carboxylate,0.95;Ethyl 3-oxo-1-(phenylmethyl)-4-piperidinecarboxylate;1-BENZYL-3-OXO-PIPERIDINE-4-CARBOXYLIC ACID ETHYL ESTER
CBNumber
CB4160661
Molecular Formula
C15H19NO3
Formula Weight
261.32
MOL File
39514-19-7.mol
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Ethyl 1-benzyl-3-oxopiperidine-4-carboxylate Property

Boiling point:
368.6±42.0 °C(Predicted)
Density 
1.154
refractive index 
1.544
storage temp. 
2-8°C
pka
10.85±0.20(Predicted)
Appearance
Yellow to reddish brown Liquid
InChI
InChI=1S/C15H19NO3/c1-2-19-15(18)13-8-9-16(11-14(13)17)10-12-6-4-3-5-7-12/h3-7,13H,2,8-11H2,1H3
InChIKey
JYFGIESQUYQLGM-UHFFFAOYSA-N
SMILES
N1(CC2=CC=CC=C2)CCC(C(OCC)=O)C(=O)C1
LogP
1.680 (est)
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Safety

HazardClass 
IRRITANT
HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
E936928
Product name
1-Benzyl-3-oxopiperidine-4-carboxylate
Packaging
50mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
040335
Product name
Ethyl 1-benzyl-3-oxopiperidine-4-carboxylate
Purity
95%
Packaging
1g
Price
$17
Updated
2021/12/16
Matrix Scientific
Product number
040335
Product name
Ethyl 1-benzyl-3-oxopiperidine-4-carboxylate
Purity
95%
Packaging
5g
Price
$69
Updated
2021/12/16
SynQuest Laboratories
Product number
4H29-1-05
Product name
Ethyl 1-benzyl-3-oxo-piperidine-4-carboxylate
Purity
95%
Packaging
5G
Price
$83
Updated
2021/12/16
AK Scientific
Product number
W5985
Product name
Ethyl1-benzyl-3-oxo-piperidine-4-carboxylate
Packaging
5g
Price
$124
Updated
2021/12/16
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Ethyl 1-benzyl-3-oxopiperidine-4-carboxylate Chemical Properties,Usage,Production

Uses

The microbial reduction of ethyl 1-benzyl-3-oxopiperidine-4-carboxylate could be used to make the ethyl cis-(3R,4R)-1-benzyl-3R-hydroxypiperidine-4R-carboxylate in high diastereomeric and enantiomeric excess[1].

References

[1] Zhiwei Guo. “Stereospecific microbial reduction of ethyl 1-benzyl-3-oxo-piperidine-4-carboxylate.” Tetrahedron, asymmetry 17 13 (2006): Pages 2015-2020.

Ethyl 1-benzyl-3-oxopiperidine-4-carboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Ethyl 1-benzyl-3-oxopiperidine-4-carboxylate Suppliers

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View Lastest Price from Ethyl 1-benzyl-3-oxopiperidine-4-carboxylate manufacturers

Career Henan Chemical Co
Product
4-Piperidinecarboxylicacid, 3-oxo-1-(phenylmethyl)-, ethyl ester 39514-19-7
Price
US $9.80/KG
Min. Order
1KG
Purity
≥98%
Supply Ability
20 tons
Release date
2020-01-09

39514-19-7, Ethyl 1-benzyl-3-oxopiperidine-4-carboxylateRelated Search:

Methyl N-methyl piperidine-4-carboxylate Ethyl 1-methyl-4-piperidinecarboxylate 3-Piperidinone Ethyl N-benzyl-3-oxo-4-piperidine-carboxylate hydrochloride 4-Pyridylcarbinol 1-METHYLPIPERIDINE-4-CARBALDEHYDE 4-(ETHOXYMETHYL)PIPERIDINE 4-(METHOXYMETHYL)PIPERIDINE (1-Benzyl-4-piperidyl)methanol Piperidine-4-carbaldehyde Isonipecotic acid 1-Benzyl-3-piperidone 1-BENZYL-3-OXO-PIPERIDINE-4-CARBOXYLIC ACID ETHYL ESTER 1-METHYL-PIPERIDINE-4-CARBOXYLIC ACID Ethyl 1-benzylpiperidine-4-carboxylate N-Benzylpiperidine-4-carboxaldehyde 1-Methyl-4-piperidinemethanol METHYL 1-BENZYLPIPERIDINE-4-CARBOXYLATE

  • N-BENZYL-4-CARBETHOXY-3-PIPERIDONE
  • N-Benzyl-3-oxo-4-piperidinecarboxylate
  • 1-BENZYL-3-OXO-PIPERIDINE-4-CARBOXYLIC ACID ETHYL ESTER
  • ETHYL N-BENZYL-3-KETOPIPERIDINE-4-CARBOXYLATE
  • ethyl 1-benzyl-3-oxopiperidine-4-carboxylate
  • 3-Oxo-1-(phenylmethyl)-4-piperidinecarboxylic acid ethyl ester
  • 3-Oxo-1-phenylmethyl-4-piperidinecarboxylic acid ethyl ester
  • 4-piperidinecarboxylic acid, 3-oxo-1-(phenylmethyl)-, ethyl ester
  • 1-benzyl-3-oxopiperidine-4-carboxylate
  • Ethyl 1-benzyl-3-oxo-4-piperidinecarboxylate
  • Ethyl 1-benzyl-3-oxopiperidine-4-carboxylate,0.95
  • -BENZYL-3-CARBETHOXYPIPERIDIN-4-ONE (DROPERIDOL INTERMEDIATE)
  • 1-BENZYL-3-OXO-PIPERIDINE-4-CARBOXYLIC ACID ETH
  • Ethyl 3-oxo-1-(phenylmethyl)-4-piperidinecarboxylate
  • 39514-19-7