ChemicalBook > CAS DataBase List > Potassium tetrachloroplatinate(II)

Potassium tetrachloroplatinate(II)

Product Name
Potassium tetrachloroplatinate(II)
CAS No.
10025-99-7
Chemical Name
Potassium tetrachloroplatinate(II)
Synonyms
POTASSIUM TETRACHLOROPLATINATE;POTASSIUM CHLOROPLATINITE;POTASSIUM TETRACHLOROPLATINATE(II);potassiumplatinochloride;PLATINOUS POTASSIUM CHLORIDE;POTASSIUM PLATINUM(II) CHLORIDE;PLATINUM(II) DIPOTASSIUM TETRACHLORIDE;oropL;1G;5G;100G;atinate(II)
CBNumber
CB4206811
Molecular Formula
Cl4KPt-
Formula Weight
375.98
MOL File
10025-99-7.mol
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Potassium tetrachloroplatinate(II) Property

Melting point:
250°C
Density 
3.38 g/mL at 25 °C(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in Water
form 
Crystals or Crystalline Powder
Specific Gravity
3.38
color 
Red-brown
Water Solubility 
10 g/L (20 ºC)
Sensitive 
Hygroscopic
Merck 
14,7682
Exposure limits
ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3
Stability:
Stable. Incompatible with acids, strong oxidizing agents.
InChIKey
RVRDLMCWUILSAH-UHFFFAOYSA-J
CAS DataBase Reference
10025-99-7(CAS DataBase Reference)
EPA Substance Registry System
Platinate(2-), tetrachloro-, dipotassium, (SP-4-1)- (10025-99-7)
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Safety

Hazard Codes 
T,Xi
Risk Statements 
25-38-41-42/43
Safety Statements 
22-26-36/37/39-45
RIDADR 
UN 3288 6.1/PG 3
WGK Germany 
1
RTECS 
TP1850000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
Ⅲ
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H317May cause an allergic skin reaction

H318Causes serious eye damage

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
925098
Product name
Potassium tetrachloroplatinate(II)
Purity
Technipur?, ≥99.9% trace metals basis
Packaging
50G
Price
$4100
Updated
2024/03/01
Sigma-Aldrich
Product number
925098
Product name
Potassium tetrachloroplatinate(II)
Purity
Technipur?, ≥99.9% trace metals basis
Packaging
100G
Price
$7370
Updated
2024/03/01
Sigma-Aldrich
Product number
925098
Product name
Potassium tetrachloroplatinate(II)
Purity
Technipur?, ≥99.9% trace metals basis
Packaging
250G
Price
$16230
Updated
2024/03/01
Sigma-Aldrich
Product number
925098
Product name
Potassium tetrachloroplatinate(II)
Purity
Technipur?, ≥99.9% trace metals basis
Packaging
500G
Price
$29210
Updated
2024/03/01
Sigma-Aldrich
Product number
206075
Product name
Potassium tetrachloroplatinate(II)
Purity
98%
Packaging
1g
Price
$135
Updated
2024/03/01
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Potassium tetrachloroplatinate(II) Chemical Properties,Usage,Production

Chemical Properties

Red/Brown, Tetragonal Crystals

Uses

Potassium tetrachloroplatinate solution is used in the preparation of platinum (Pt) nanoparticles. Ligands like ammonia or triphenyl phosphine can able to replace the chloride ligands to afford various derivatives. The replacement by ammonia results in the preparation of cisplatin, which is used in the cancer treatment. Further, it is used as catalyst in the hydroarylation reaction.

Uses

In photography, in acid toning baths.

General Description

Potassium tetrachloroplatinate(II) is a ruby red crystalline solid and can be prepared by reacting potassium hexachloroplatinate (IV) with cuprous chloride.

Flammability and Explosibility

Non flammable

Safety Profile

Human poison by ingestion. Poison experimentally by intraperitoneal route. Corrosive to human skin by intradermal route. Mutation data reported. Human systemic effects: eosinophha, gastritis, renal function tests depressed. When heated to decomposition it emits toxic fumes of Cland K2O. Used as a catalyst for hydroformulations, photocatalysts, and dissociation of water. See also PLATINUM COMPOUNDS.

Synthesis

To a suspension of 9.72g (0.02mol) of potassium hexachloroplatinate(IV) in 100cm3 of water, in a 250cm3 beaker, is added in small portions 1.0g (0.01mol) of hydrazine dihydrochloride. Excess hydrazine dihydrochloride must be avoided to prevent the formation of hydrazine complexes and the reduction of potassium hexachloroplatinate(IV) to platinum when the solution is made basic with ammonia during cisplatin synthesis. The mixture is stirred mechanically while the temperature is raised to 50-65°C over 5-10 minutes. This temperature is maintained for about 2 hours until only a small amount of yellow potassium hexachloroplatinate(IV) remains in the deep red solution. The temperature is then raised to 80-90°C to ensure completion of the reaction, and the mixture is cooled in an ice bath and filtered. The latter is washed with several 10cm3 portions of ice water until the washings are colourless. The washings and deep red filtrate contain pure potassium tetrachloroplatinate(II) and HCl(aq). Half of this solution is used to make the cisplatin.

Purification Methods

It forms crystals from aqueous 0.75M HCl (20mL/g) between 100o and 0o. Wash them with ice-cold water and dry.

Potassium tetrachloroplatinate(II) Preparation Products And Raw materials

Raw materials

Preparation Products

ZENIPLATIN acrylate ternary copolymer bound disulfide platinum complex catalyst ENLOPLATIN Dichloro(1,5-cyclooctadiene)platinum(II)
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View Lastest Price from Potassium tetrachloroplatinate(II) manufacturers

HebeiShuoshengImportandExportco.,Ltd
Product
dipotassium tetrachloroplatinate 10025-99-7
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-09
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Dipotassium Tetrachloroplatinate 10025-99-7
Price
US $200.00-95.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-24
WUHAN FORTUNA CHEMICAL CO., LTD
Product
dipotassium tetrachloroplatinate 10025-99-7
Price
US $0.00/MG
Min. Order
100MG
Purity
98.0%
Supply Ability
1kg/month
Release date
2022-12-29

10025-99-7, Potassium tetrachloroplatinate(II)Related Search:

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