ChemicalBook > CAS DataBase List > 3'-Methylacetanilide

3'-Methylacetanilide

Product Name
3'-Methylacetanilide
CAS No.
537-92-8
Chemical Name
3'-Methylacetanilide
Synonyms
M-ACETOTOLUIDINE;Acetamide, N-(3-methylphenyl)-;NSC 3103;N-(m-Tolyl);Acetotoluide;m-Acetotoluide;N-Acetotoluidine;M-ACETOTOLUIDIDE;N-Acetyltoluidine;M-TOLYL-ACETAMIDE
CBNumber
CB4271347
Molecular Formula
C9H11NO
Formula Weight
149.19
MOL File
537-92-8.mol
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3'-Methylacetanilide Property

Melting point:
65-67 °C (lit.)
Boiling point:
303 °C (lit.)
Density 
1.1410
vapor pressure 
16 mm Hg ( 163 °C)
refractive index 
1.5279 (estimate)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
alcohol: freely soluble(lit.)
form 
powder to crystal
pka
15.12±0.70(Predicted)
color 
White to Light gray to Light yellow
Merck 
14,74
Stability:
Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference
537-92-8(CAS DataBase Reference)
NIST Chemistry Reference
N-(3-Tolyl)acetic acid amide(537-92-8)
EPA Substance Registry System
m-Acetotoluidide (537-92-8)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
AN2875000
HS Code 
29242998
Toxicity
LD50 orl-mus: 1450 mg/kg TXAPA9 19,20,71
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
A0062
Product name
m-Acetotoluidine
Purity
>98.0%(GC)
Packaging
25g
Price
$60
Updated
2024/03/01
TCI Chemical
Product number
A0062
Product name
m-Acetotoluidine
Purity
>98.0%(GC)
Packaging
250g
Price
$410
Updated
2024/03/01
TRC
Product number
A168335
Product name
3-Acetylaminotoluene
Packaging
10g
Price
$100
Updated
2021/12/16
TRC
Product number
A168335
Product name
3-Acetylaminotoluene
Packaging
50g
Price
$120
Updated
2021/12/16
AK Scientific
Product number
L546
Product name
3'-Methylacetanilide
Packaging
100g
Price
$142
Updated
2021/12/16
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3'-Methylacetanilide Chemical Properties,Usage,Production

Chemical Properties

white crystalline solid

General Description

White solid.

Air & Water Reactions

Water insoluble.

Reactivity Profile

3'-Methylacetanilide is an amide. Flammable gases are formed by the reaction of organic amides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).

Health Hazard

ACUTE/CHRONIC HAZARDS: When heated to decomposition 3'-Methylacetanilide emits toxic fumes of nitrogen oxides.

Fire Hazard

Flash point data for 3'-Methylacetanilide are not available; however, 3'-Methylacetanilide is probably combustible.

Safety Profile

Moderately toxic by ingestion. Seealso p-ACETOTOLUIDIDE. When heated todecomposition it emits toxic fumes of NOx.

Purification Methods

Crystallise the toluidide from H2O, EtOH, aqueous EtOH or Et2O/pet ether (m 66o). UV: max 245nm (EtOH). [Beilstein 12 H 860, 12 I 400, 12 II 468, 12 III 1962, 12 IV 1823.]

3'-Methylacetanilide Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3'-Methylacetanilide manufacturers

Career Henan Chemical Co
Product
3'-Methylacetanilide 537-92-8
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10t
Release date
2019-12-20

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