Palladacycle Gen. 3

ChemicalBook > CAS DataBase List > Palladacycle Gen. 3

Product Name: Palladacycle Gen. 3
CAS No.: 1447963-73-6
Chemical Name: Palladacycle Gen. 3
Synonyms: Palladacycle Gen. 3;CPHOS PALLADACYCLE GEN. 3;{2-amino-[1,1-biphenyl]-2-yl}palladio;Palladacycle Gen. 3 ISO 9001：2015 REACH;Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), 98%;CPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / CPhos Pd G3;Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),CPhos Palladacycle Gen. 3;METHANESULFONATO(2-DICYCLOHEXYLPHOSPHINO-2',6'-BIS(DIMETHYLAMINO)-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),98%[CPHOSPALLADACYCLEGEN.3]
CBNumber: CB43175619
Molecular Formula: C41H54N3O3PPdS
Formula Weight: 806.35
MOL File: 1447963-73-6.mol

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Palladacycle Gen. 3 Property

Melting point:: 176-178 °C (decomposition)
form: Powder
color: white to off-white
InChI: InChI=1S/C28H41N2P.C12H9N.CH4O3S.Pd/c1-29(2)25-19-13-20-26(30(3)4)28(25)24-18-11-12-21-27(24)31(22-14-7-5-8-15-22)23-16-9-6-10-17-23;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h11-13,18-23H,5-10,14-17H2,1-4H3;1-6,8-9,13H;1H3,(H,2,3,4);/q;-2;;+2
InChIKey: BYZMMBLECCTRMT-UHFFFAOYSA-N
SMILES: P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1N(C)C)N(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 763004
Product name: CPhos Pd G3
Purity: 95%
Packaging: 500mg
Price: $313
Updated: 2024/03/01

Sigma-Aldrich

Product number: 763004
Product name: CPhos Pd G3
Purity: 95%
Packaging: 5g
Price: $2260
Updated: 2023/06/20

Strem Chemicals

Product number: 46-0487
Product name: Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), 98% [CPhos Palladacycle Gen. 3]
Packaging: 100mg
Price: $57
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0487
Product name: Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), 98% [CPhos Palladacycle Gen. 3]
Packaging: 500mg
Price: $245
Updated: 2024/03/01

Sigma-Aldrich

Product number: 763004
Product name: CPhos Pd G3
Purity: 95%
Packaging: 100mg
Price: $72.6
Updated: 2024/03/01

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Palladacycle Gen. 3 Chemical Properties,Usage,Production

Reactions

Catalyst for the highly selective cross-coupling of secondary alkylzinc reagents with heteroaryl halides
Catalyst for the completely linear-selective Negishi cross-coupling of allylzinc halides with aryl and vinyl electrophiles

General Description

CPhos Pd G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.

Palladacycle Gen. 3 Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Palladacycle Gen. 3 manufacturers

Wuhan LPBchem Technology Co.,Ltd

Product: Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / CPhos Pd G3 1447963-73-6
Price: US $10.00-10.00/g
Min. Order: 1g
Purity: 0.98
Supply Ability: 50KG
Release date: 2020-11-26

1447963-73-6, Palladacycle Gen. 3Related Search:

RockPhos Pd G3 XPhos Pd G3 SPhos Palladacycle Gen. 4 XPhos Pd G4 Xantphos Pd G3 BrettPhos Pd G3 XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct SPhos Pd G2 BrettPhosPalladacycle t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2 tBuXPhos Pd G1 XPhos Pd G1

CPHOS PALLADACYCLE GEN. 3

Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), 98%

METHANESULFONATO(2-DICYCLOHEXYLPHOSPHINO-2',6'-BIS(DIMETHYLAMINO)-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),98%[CPHOSPALLADACYCLEGEN.3]

Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),CPhos Palladacycle Gen. 3

Palladacycle Gen. 3

Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / CPhos Pd G3

Palladacycle Gen. 3 ISO 9001：2015 REACH

CPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

{2-amino-[1,1-biphenyl]-2-yl}palladio

Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

1447963-73-6

C41H54N3O3PPdS

Buchwald Ligands&Precatalysts

Buchwald Precatalysts Series