ChemicalBook > CAS DataBase List > 2-Methyl-3-nitroaniline

2-Methyl-3-nitroaniline

Product Name
2-Methyl-3-nitroaniline
CAS No.
603-83-8
Chemical Name
2-Methyl-3-nitroaniline
Synonyms
-3-nitroaniL;3-nitro-o-toluidin;Methyl-3-nitroanil;3-NITRO-O-TOLUIDINE;o-Toluidine, 3-nitro-;LABOTEST-BB LTBB000622;2-Methy-3-nitroaniline;2-AMINO-6-NITROTOLUENE;2-NITRO-6-AMINOTOLUENE;6-Amino-2-nitrotoluene
CBNumber
CB4492469
Molecular Formula
C7H8N2O2
Formula Weight
152.15
MOL File
603-83-8.mol
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2-Methyl-3-nitroaniline Property

Melting point:
88-90 °C (lit.)
Boiling point:
305 °C (lit.)
Density 
1.378
refractive index 
1.6394 (estimate)
Flash point:
305°C
storage temp. 
Store below +30°C.
solubility 
<1mg/l
form 
Crystalline Powder
pka
2.31±0.10(Predicted)
color 
Yellow to greenish-yellow
Water Solubility 
<0.1 g/100 mL at 23 ºC
BRN 
388393
InChIKey
HFCFJYRLBAANKN-UHFFFAOYSA-N
CAS DataBase Reference
603-83-8(CAS DataBase Reference)
NIST Chemistry Reference
2-Methyl-3-nitroaniline(603-83-8)
EPA Substance Registry System
2-Methyl-3-nitroaniline (603-83-8)
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Safety

Hazard Codes 
T,N
Risk Statements 
23/24/25-33-51/53
Safety Statements 
28-36/37-45-61-28A
RIDADR 
UN 2660 6.1/PG 3
WGK Germany 
3
RTECS 
XU8200000
Hazard Note 
Toxic
HazardClass 
6.1
PackingGroup 
III
HS Code 
29214300
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
115843
Product name
2-Methyl-3-nitroaniline
Purity
97%
Packaging
100g
Price
$62.8
Updated
2024/03/01
Sigma-Aldrich
Product number
115843
Product name
2-Methyl-3-nitroaniline
Purity
97%
Packaging
25g
Price
$72.8
Updated
2024/03/01
TCI Chemical
Product number
N0455
Product name
2-Methyl-3-nitroaniline
Purity
>98.0%(GC)
Packaging
25g
Price
$104
Updated
2024/03/01
TCI Chemical
Product number
N0455
Product name
2-Methyl-3-nitroaniline
Purity
>98.0%(GC)
Packaging
250g
Price
$746
Updated
2024/03/01
Alfa Aesar
Product number
A10347
Product name
2-Methyl-3-nitroaniline, 98%
Packaging
100g
Price
$97.8
Updated
2021/12/16
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2-Methyl-3-nitroaniline Chemical Properties,Usage,Production

Chemical Properties

YELLOW TO GREENISH-YELLOW CRYSTALLINE POWDER

Uses

2-Amino-6-nitrotoluene (2-Methyl-3-nitroaniline) has been used as a standard while evaluating the potential for degradation of nitroaromatic compounds by indigenous microorganisms.

Production Methods

6-Nitro-o-toluidine is produced by sulfide reduction of 2,6-dinitrotoluene in a process similar to that for 3-nitroaniline or by controlled hydrogenation of 2,6-dinitrotoluene with palladium on a carbon catalyst.

General Description

Yellow rhombic needles (from water) or bright yellow powder.

Air & Water Reactions

2-Methyl-3-nitroaniline may be sensitive to prolonged exposure to air. Insoluble in water.

Reactivity Profile

2-Methyl-3-nitroaniline is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizers.

Fire Hazard

Flash point data for 2-Methyl-3-nitroaniline are not available; however, 2-Methyl-3-nitroaniline is probably combustible.

Purification Methods

Crystallise the nitrotoluidine from EtOH or *C6H6. It is steam volatile. The acetyl derivative crystallises from aqueous EtOH and has m 164o. [Beilstein 12 I 395, 12 II 460, 12 III 1944, 2 IV 1811.]

2-Methyl-3-nitroaniline Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-Methyl-3-nitroaniline manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
2-Methyl-3-nitroaniline 603-83-8
Price
US $40.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-09-08
Henan Fengda Chemical Co., Ltd
Product
2-Methyl-3-nitroaniline 603-83-8
Price
US $122.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-11
Career Henan Chemical Co
Product
2-Methyl-3-nitroaniline 603-83-8
Price
US $8.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10MT
Release date
2018-12-17

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