5-BROMO-2-FLUORO-6-PICOLINE

Product Name: 5-BROMO-2-FLUORO-6-PICOLINE
CAS No.: 375368-83-5
Chemical Name: 5-BROMO-2-FLUORO-6-PICOLINE
Synonyms: 3-Bromo-6-fluoro-2-methylpyridine;5-BROMO-2-FLUORO-6-PICOLINE;5-Bromo-2-flouro-6-picoline;5-Bromo-2-fluoro-6-methylpyridine;Pyridine,3-bromo-6-fluoro-2-methyl-;5-BROMO-2-FLUORO-6-PICOLINE ISO 9001：2015 REACH
CBNumber: CB4754716
Molecular Formula: C6H5BrFN
Formula Weight: 190.01
MOL File: 375368-83-5.mol

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5-BROMO-2-FLUORO-6-PICOLINE Property

Boiling point:: 189.5±35.0 °C(Predicted)
Density: 1.592±0.06 g/cm3(Predicted)
refractive index: 1.5270-1.5310
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: clear liquid
pka: -2.07±0.10(Predicted)
color: Colorless to Light yellow
InChI: InChI=1S/C6H5BrFN/c1-4-5(7)2-3-6(8)9-4/h2-3H,1H3
InChIKey: GUYGQQWIKZLHTP-UHFFFAOYSA-N
SMILES: C1(C)=NC(F)=CC=C1Br

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 22-37/38-41
Safety Statements: 26-39
HazardClass: IRRITANT
HS Code: 2933399990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: B5135
Product name: 3-Bromo-6-fluoro-2-methylpyridine
Purity: >98.0%(GC)
Packaging: 5g
Price: $40
Updated: 2025/07/31

TCI Chemical

Product number: B5135
Product name: 3-Bromo-6-fluoro-2-methylpyridine
Purity: >98.0%(GC)
Packaging: 25g
Price: $160
Updated: 2025/07/31

TRC

Product number: B692663
Product name: 3-Bromo-6-fluoro-2-methylpyridine
Packaging: 250mg
Price: $55
Updated: 2021/12/16

Apolloscientific

Product number: PC7144
Product name: 3-Bromo-6-fluoro-2-methylpyridine
Purity: 98%
Packaging: 5g
Price: $43
Updated: 2021/12/16

Matrix Scientific

Product number: 024607
Product name: 5-Bromo-2-fluoro-6-methylpyridine
Purity: 98%
Packaging: 5g
Price: $53
Updated: 2021/12/16

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5-BROMO-2-FLUORO-6-PICOLINE Chemical Properties,Usage,Production

Chemical Properties

Light yellow powder

Uses

5-Bromo-2-fluoro-6-methylpyridine is a Light yellow powder, it is used as an intermediate in organic synthesis and is widely used in the fields of pesticide, medicine and materials science.

Synthesis

42753-71-9

375368-83-5

The general procedure for the synthesis of 3-bromo-2-methyl-6-fluoropyridine from 2-amino-5-bromo-6-methylpyridine was as follows: 5-bromo-2-amino-6-methylpyridine (5 g) was dissolved in pyridine hydrogen fluoride (35 mL). The reaction system was cooled to -20°C, followed by the slow addition of potassium nitrite (KNO2, 2.7 g). The reaction was continued by keeping the temperature low. Once the reaction was complete, it was slowly warmed to room temperature and stirred continuously for 4 hours. The reaction mixture was slowly poured into ice water (200 mL) and extracted with a solvent mixture of dichloromethane (50 mL) and ethyl acetate (EtOAc). The organic phases were combined, washed with 1N hydrochloric acid solution and concentrated under reduced pressure to give 5-bromo-2-fluoro-6-methylpyridine (4 g, 78% yield).

References

[1] Patent: CN108341769, 2018, A. Location in patent: Paragraph 0021-0023; 0025-0027
[2] Bioorganic and Medicinal Chemistry Letters, 2003, vol. 13, # 22, p. 3979 - 3982

5-BROMO-2-FLUORO-6-PICOLINE Preparation Products And Raw materials

Raw materials

Preparation Products

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5-BROMO-2-FLUORO-6-PICOLINE Suppliers

Americas 1 China 177 Europe 1 France 1 India 5 Japan 2 United Kingdom 7 United States 32 Global 226

TCI Chemicals (India) Pvt. Ltd.

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Novasyn Organics Pvt. Ltd (India)

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Reax Chemicals

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A.J Chemicals

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View Lastest Price from 5-BROMO-2-FLUORO-6-PICOLINE manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 5-BROMO-2-FLUORO-6-PICOLINE 375368-83-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-05-29

Henan Fengda Chemical Co., Ltd

Product: 3-Bromo-6-fluoro-2-methylpyridine 375368-83-5
Price: US $200.00-1.00/KG
Min. Order: 1KG
Purity: 99%, 99.5% Sublimated
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-30

Dideu Industries Group Limited

Product: 5-BROMO-2-FLUORO-6-PICOLINE 375368-83-5
Price: US $1.10/g
Min. Order: 1g
Purity: 99.00%
Supply Ability: 100 Tons min
Release date: 2021-08-25

375368-83-5, 5-BROMO-2-FLUORO-6-PICOLINERelated Search:

2-Fluoro-6-methylpyridine 5-BROMO-2-FLUORO-3-PICOLINE,5-BROMO-2-FLUORO-3-PICOLINE (5-BROMO-2-FLUORO-3-METHYLPYRIDINE) 3-BROMO-2-FLUORO-5-PICOLINE,3-BROMO-2-FLUORO-5-PICOLINE (3-BROMO-2-FLUORO-5-METHYLPYRIDINE) 5-Bromo-2-fluoropyridine 5-Chloro-2-fluoropyridine 2-Fluoropyridine-6-carboxylic acid 2-Fluoro-3-nitropyridine 5-Bromo-2-fluoro-4-methyl-pyridine 5-Chloro-2-fluoro-3-methylpyridine 2-CHLORO-6-FLUOROPYRIDINE 4-Bromo-2-fluoropyridine 2-Fluoro-3-methylpyridine 3-Amino-2-fluoropyridine 3-Chloro-2-fluoro-pyridine 2-Fluoro-5-methylpyridine 2-Fluoro-4-methylpyridine 3-BROMO-5-CHLORO-2-FLUOROPYRIDINE 3-Chloro-2-iodopyridine

5-BROMO-2-FLUORO-6-PICOLINE

5-Bromo-2-fluoro-6-methylpyridine

3-Bromo-6-fluoro-2-methylpyridine

Pyridine,3-bromo-6-fluoro-2-methyl-

5-Bromo-2-flouro-6-picoline

5-BROMO-2-FLUORO-6-PICOLINE ISO 9001：2015 REACH

375368-83-5

Fluorine series

Pyridine Series

Organohalides

Pyridine

Variety of halogenated heterocyclic series

Heterocycles