ChemicalBook > CAS DataBase List > (R)-(+)-Glycidol

(R)-(+)-Glycidol

Product Name
(R)-(+)-Glycidol
CAS No.
57044-25-4
Chemical Name
(R)-(+)-Glycidol
Synonyms
(R)-Oxiran-2-ylMethanol;(R)-GLYCIDOL;(R)-Oxiranemethanol;EOS-60676;R-Glycidoe;(R)-(+)-GL;(+)-Glycidol;(R)-GLYCIDOL,99%;(R)-(+)-GLYCIDOL;(r)-oxiranemethano
CBNumber
CB5205831
Molecular Formula
C3H6O2
Formula Weight
74.08
MOL File
57044-25-4.mol
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(R)-(+)-Glycidol Property

Boiling point:
56-57 °C11 mm Hg(lit.)
Density 
1.116 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.43(lit.)
Flash point:
178 °F
storage temp. 
-20°C
Water Solubility 
Completely miscible in water
solubility 
Chloroform (Slightly), DMSO (Slightly)
pka
14.62±0.10(Predicted)
color 
Colorless to Light yellow
optical activity
[α]23/D +15°, neat
BRN 
79782
Stability:
Moisture Sensitive
InChIKey
CTKINSOISVBQLD-GSVOUGTGSA-N
CAS DataBase Reference
57044-25-4(CAS DataBase Reference)
NIST Chemistry Reference
Oxiranemethanol, (R)-(57044-25-4)
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Safety

Hazard Codes 
T,E
Risk Statements 
45-60-2-21/22-23-34-68-41-37/38
Safety Statements 
53-45-36/37/39-26
RIDADR 
UN 2922 8/PG 2
WGK Germany 
3
RTECS 
RR0508000
F 
10-21
HazardClass 
6.1
PackingGroup 
Ⅲ
HS Code 
29109000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H227Combustible liquid

H242Heating may cause a fire

H302Harmful if swallowed

H312Harmful in contact with skin

H314Causes severe skin burns and eye damage

H315Causes skin irritation

H319Causes serious eye irritation

H330Fatal if inhaled

H331Toxic if inhaled

H335May cause respiratory irritation

H341Suspected of causing genetic defects

H350May cause cancer

H361Suspected of damaging fertility or the unborn child

H370Causes damage to organs

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P307+P311IF exposed: call a POISON CENTER or doctor/physician.

P310Immediately call a POISON CENTER or doctor/physician.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
480819
Product name
(R)-(+)-Glycidol
Purity
97%, optical purity ee: 98% (GLC)
Packaging
1g
Price
$50.1
Updated
2023/06/20
TCI Chemical
Product number
G0363
Product name
(R)-(+)-Glycidol
Purity
>98.0%(GC)
Packaging
5g
Price
$86
Updated
2024/03/01
TCI Chemical
Product number
G0363
Product name
(R)-(+)-Glycidol
Purity
>98.0%(GC)
Packaging
25g
Price
$291
Updated
2024/03/01
TRC
Product number
G615695
Product name
(R)-(+)-Glycidol
Packaging
5g
Price
$135
Updated
2021/12/16
TRC
Product number
G615695
Product name
(R)-(+)-Glycidol
Packaging
10g
Price
$215
Updated
2021/12/16
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(R)-(+)-Glycidol Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

(R)-(+)-Glycidol may be used in the following synthesis:

  • heteroarylpropane-2,3-diols, useful for combinatorial oligomer synthesis
  • enantiomerically pure (2S,3S)- and (2S,3R)-threoninol and -hydroxyphenylalaninol
  • 2-amino-1,4-anhydro-pentitol and 3-amino-1,5-anhydro-4-deoxy-hexitol with the arabino configuration
  • (S)-4-tosyloxymethyl-2-oxazolidinone, required for the synthesis of protected amino alcohol derivatives
  • 1-(S)-[3-hydroxy-2-(phosphonomethoxy)propyl]cytosine [(S)-HPMPC]
  • chiral building block used to construct an epoxyvinyl iodide intermediate in a synthesis of a furanocembrane, a marine natural product

Uses

(R)-(+)-Glycidol can be used to construct chiral building blocks of epoxyvinyl iodide intermediates in the synthesis of furanocembrane, a marine natural product.

Definition

ChEBI: (R)-glycidol is a glycidol. It is functionally related to a (R)-1,2-epoxypropane. It is an enantiomer of a (S)-glycidol.

General Description

Enantioselective esterification of (R)-(+)-glycidol with n-butyric acid in organic media using hybrid gel-entrapped lipase on Celite has been reported.

Purification Methods

[S(-)-isomer, § also available on polymer support, has b 49-50o/7mm, 66-67o/19mm, [ ] D -1 5o(neat)], [R(+)-isomer has b 56 -5 6 . 5o/11mm, d 4 1.117, n D 1.429, [ ] D +15o (neat)]. Purify glycidol by fractional distillation.

(R)-(+)-Glycidol Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-(+)-Methyl glycidyl ether
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(R)-(+)-Glycidol Suppliers

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View Lastest Price from (R)-(+)-Glycidol manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(R)-(+)-Glycidol 57044-25-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
(R)-(+)-Glycidol 57044-25-4
Price
US $1.00/KG
Min. Order
1KG
Purity
95%-99%
Supply Ability
2000kg
Release date
2019-08-05

57044-25-4, (R)-(+)-GlycidolRelated Search:

Allyl glycidyl ether Ethylene glycol diglycidyl ether DIGLYCIDYL ETHER Propylene oxide 1,2,3-PROPANETRIOL GLYCIDYL ETHER CHLOROPHOSPHONAZO III ETHYLENE OXIDE Methanol Glycidol methyl ether (S)-Glycidol 3-Nitrobenzenesulfonate (S)-(+)-Benzyl glycidyl ether (2S)-(+)-Glycidyl tosylate (+/-)-GLYCIDOL,(RS)-Glycido BISPHENOL A DIGLYCIDYL ETHER RESIN Cinobufagin Cinobufotalin Methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate Glycidol phenyl ether

  • EOS-60676
  • (r)-oxiranemethano
  • (R)-(+)-2,3-EPOXY-1-PROPANOL
  • (R)-(+)-GLYCIDOL
  • (R)-GLYCIDOL
  • R(+)-OXIRANE-2-METHANOL
  • (R)-Oxiranemethanol
  • OXIRANEMETHANOL, (2R)-
  • (R)-GLYCIDOL,99%
  • (R)-3-Hydroxy-1,2-epoxypropane
  • (R)-(+)-GLYCIDOL, 97% (98% EE/GLC)
  • R-Glycidoe
  • (R)-(+)-GLYCIDOL ((R)-(+)-2,3-EPOXY-1-PROPANOL)
  • (2R)-Oxirane-2-methanol
  • (R)-2-Hydroxymethyloxirane
  • (R)-(+)-Glycidol,(R)-(+)-Oxirane-2-methanol
  • (R)-Oxiran-2-ylMethanol
  • (R)-(+)-1-Hydroxy-2,3-epoxypropane (R)-(+)-2-(Hydroxymethyl)oxirane
  • (R)-(+)-Glycidol 97%, optical purity ee: 98% (GLC)
  • 2-Oxiranemethanol, (2R)-
  • (R)-(+)-1-Hydroxy-2,3-epoxypropane
  • (R)-(+)-Glycidol≥ 99% (GC)
  • (R)-(+)-Oxirane-2-methanol (R)-(+)-1-Hydroxy-2,3-epoxypropane (R)-(+)-2-(Hydroxymethyl)oxirane
  • (R)-(+)-Glycidol&gt
  • (R)-(+)-GL
  • 97%, optical purity ee: 98% (GLC)
  • (+)-Glycidol
  • Levodropropazine impurity 11
  • 57044-25-4
  • C3H6O2
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • Organic Building Blocks
  • Epoxides
  • Chiral Compound
  • CHIRAL COMPOUNDS
  • chiral
  • API intermediates