ChemicalBook > CAS DataBase List > Ethyl (triphenylphosphoranylidene)acetate
Ethyl (triphenylphosphoranylidene)acetate
Description- Product Name
- Ethyl (triphenylphosphoranylidene)acetate
- CAS No.
- 1099-45-2
- Chemical Name
- Ethyl (triphenylphosphoranylidene)acetate
- Synonyms
- (CARBETHOXYMETHYLENE)TRIPHENYLPHOSPHORANE;CEMTPP;(triphenylphosphoranylidene)acetate;(ETHOXYCARBONYLMETHYLENE)TRIPHENYLPHOSPHORANE;Ethoxyformylmethylene triphenylphosphine;(CARBOETHOXYMETHYLENE)TRIPHENYLPHOSPHORANE;EMY;NSC 72406;ene)triphenyL;AURORA KA-1176
- CBNumber
- CB5290828
- Molecular Formula
- C22H21O2P
- Formula Weight
- 348.37
- MOL File
- 1099-45-2.mol
More
Less
Ethyl (triphenylphosphoranylidene)acetate Property
- Melting point:
- 128-130 °C (lit.)
- Boiling point:
- 490.4±28.0 °C(Predicted)
- Density
- 1.086 g/cm3
- storage temp.
- 2-8°C
- solubility
- Chloroform, THF
- form
- Powder
- color
- White to light yellow
- Water Solubility
- Insoluble
- Sensitive
- Air Sensitive
- BRN
- 754639
- InChIKey
- IIHPVYJPDKJYOU-UHFFFAOYSA-N
- CAS DataBase Reference
- 1099-45-2(CAS DataBase Reference)
- EPA Substance Registry System
- Acetic acid, (triphenylphosphoranylidene)-, ethyl ester (1099-45-2)
More
Less
Safety
- Hazard Codes
- T,Xi,Xn
- Risk Statements
- 36/37/38-25-20/21/22
- Safety Statements
- 22-24/25-45-37/39-26-36
- RIDADR
- UN2811
- WGK Germany
- 3
- Hazard Note
- Irritant
- TSCA
- Yes
- HS Code
- 29310095
More
Less
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H300Fatal if swallowed
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H373May cause damage to organs through prolonged or repeated exposure
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P272Contaminated work clothing should not be allowed out of the workplace.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P314Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.
P363Wash contaminated clothing before reuse.
P405Store locked up.
P501Dispose of contents/container to..…
More
Less
N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- C5106
- Product name
- (Carbethoxymethylene)triphenylphosphorane
- Purity
- 95%
- Packaging
- 5g
- Price
- $32.6
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- C5106
- Product name
- (Carbethoxymethylene)triphenylphosphorane
- Purity
- 95%
- Packaging
- 25g
- Price
- $138
- Updated
- 2024/03/01
TCI Chemical
- Product number
- T1944
- Product name
- Ethyl (Triphenylphosphoranylidene)acetate
- Purity
- >98.0%(HPLC)
- Packaging
- 25g
- Price
- $75
- Updated
- 2024/03/01
TCI Chemical
- Product number
- T1944
- Product name
- Ethyl (Triphenylphosphoranylidene)acetate
- Purity
- >98.0%(HPLC)
- Packaging
- 250g
- Price
- $482
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- A12896
- Product name
- (Ethoxycarbonylmethylene)triphenylphosphorane, 98+%
- Packaging
- 10g
- Price
- $29.65
- Updated
- 2024/03/01
More
Less
Ethyl (triphenylphosphoranylidene)acetate Chemical Properties,Usage,Production
Description
Ethyl (triphenylphosphoranylidene)acetate is a common Wittig reagent in organic synthesis as well as a cholinesterase inhibitor that inhibits both AChE and BChE. It is used in the preparation of indole from o-nitrobenzaldehydes, coumarins from o-hydroxy acetophenone.
Chemical Properties
Off-White Solid
Uses
A common Wittig reagent. A cholinesterase inhibitor.
Uses
(Ethoxycarbonylmethylene)triphenylphosphoran is used as a Wittig reagent in organic synthesis. It is used in the preparation of indole from o-nitrobenzaldehydes, coumarins from o-hydroxy acetophenone. It acts as an inhibitor and inhibits the activity of cholinesterase.
Purification Methods
Crystallise it by dissolving it in AcOH and adding pet ether (b 40-50o) to give colourless plates. UV (A 1% ): 222nm (865) and 268nm (116) [Isler et max 1mm al. Helv Chim Acta 40 1242 1957]. [Beilstein 16 IV 977.]
Ethyl (triphenylphosphoranylidene)acetate Preparation Products And Raw materials
Raw materials
Preparation Products
More
Less
Ethyl (triphenylphosphoranylidene)acetate Suppliers
- Tel
- 13383293380 18032131480
- 649498984@qq.com
- Country
- China
- ProdList
- 75
- Advantage
- 58
- Tel
- 18655878467
- Fax
- -
- fayinzheng@163.com
- Country
- China
- ProdList
- 37
- Advantage
- 55
- Tel
- 022-83945173 18622315263
- Fax
- QQ1559208715
- export@creasyn.com
- Country
- China
- ProdList
- 459
- Advantage
- 55
- Tel
- 0311-67799589
- Fax
- 0311-67799589
- Country
- China
- ProdList
- 6
- Advantage
- 55
- Tel
- 022-83946278 13820503911
- Fax
- 022-83945176
- sales@creasyn.com
- Country
- China
- ProdList
- 978
- Advantage
- 68
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 94657
- Advantage
- 76
- Tel
- 021-61259108 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40228
- Advantage
- 62
- Tel
- 010-88425576
- Fax
- (+86)-10-88425546
- sales@dhltchem.com
- Country
- China
- ProdList
- 793
- Advantage
- 59
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30123
- Advantage
- 84
- Tel
- +86 351 7031519
- Fax
- +86 351 7031519
- sales@RHFChem.com
- Country
- China
- ProdList
- 2338
- Advantage
- 56
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 400-021-7337 2355568890
- Fax
- 0086-21-50182339
- sales@demochem.com
- Country
- China
- ProdList
- 2572
- Advantage
- 57
- Tel
- 010-89508211 18501085097
- Fax
- 010-89508210
- sales.bj@hwrkchemical.com
- Country
- China
- ProdList
- 8418
- Advantage
- 55
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44689
- Advantage
- 61
- Tel
- 010-82967028 13552068683
- Fax
- +86-10-82967029
- 2355560935@qq.com
- Country
- China
- ProdList
- 12390
- Advantage
- 60
- Tel
- 13817811078
- Fax
- 86-021-50426522,50426273
- sales@jingyan-chemical.com
- Country
- China
- ProdList
- 9976
- Advantage
- 60
- Tel
- 0573-85285100 18627885956
- Fax
- 0573-85285100
- isenchem@163.com
- Country
- China
- ProdList
- 9413
- Advantage
- 66
- Tel
- 021-50795510 4000665055
- Fax
- 021-50795055
- sales@accelachem.com
- Country
- China
- ProdList
- 11655
- Advantage
- 64
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
- Country
- China
- ProdList
- 42958
- Advantage
- 64
- Tel
- 021-50135380
- shchemsky@sina.com
- Country
- China
- ProdList
- 32321
- Advantage
- 50
- Tel
- 15527768850
- 1791901229@qq.com
- Country
- China
- ProdList
- 8843
- Advantage
- 52
- Tel
- 4009903999 13355009207
- Fax
- 0539-6365991
- 3007715519@qq.com
- Country
- China
- ProdList
- 18738
- Advantage
- 57
- Tel
- Fax
- E-Mail Inquiry
- info@syntechem.com
- Country
- China
- ProdList
- 12984
- Advantage
- 57
- Tel
- 0315-8309571 15633399667
- Fax
- +86-315-7726572
- sales@moneidechem.com
- Country
- China
- ProdList
- 704
- Advantage
- 57
- Tel
- 400-188-0725 +86 21 34310725 13611771617
- Fax
- +86 21 34311076
- Country
- China
- ProdList
- 2002
- Advantage
- 57
- Tel
- 400 638 7771
- sales@heowns.com
- Country
- China
- ProdList
- 14435
- Advantage
- 57
- Tel
- 86-21-63210123
- Fax
- 86-21-63290778 86-21-63218885
- sj_scrc@sinopharm.com
- Country
- China
- ProdList
- 9815
- Advantage
- 79
- Tel
- +86 (25) 5860-8846
- Fax
- +86 (25) 5860-8846
- kt_chem@126.com
- Country
- China
- ProdList
- 218
- Advantage
- 62
- Tel
- 021-50273253 13641951838
- Fax
- +86-21-61294436
- chemmilestone@163.com
- Country
- China
- ProdList
- 151
- Advantage
- 62
- Tel
- 021-51613915-820 13611835272
- Fax
- 021 51613951
- mmwang@sunwaypharm.cn
- Country
- China
- ProdList
- 9734
- Advantage
- 57
- Tel
- 0731-85526065 13308475853
- ivy@hnhbsj.com
- Country
- China
- ProdList
- 4552
- Advantage
- 62
- Tel
- 0370-2785118 17550508557
- Fax
- QQ：3470079902
- 675141927@qq.com
- Country
- China
- ProdList
- 3203
- Advantage
- 55
- Tel
- 021-33690831-8001 13552411790
- Fax
- 021-33690831
- postmaster@tyjchem.cn
- Country
- China
- ProdList
- 1541
- Advantage
- 55
- Tel
- 21-58388037 13472507714
- Fax
- 0086-21-56829747 Company QQ: 1589045147
- 1589045147@qq.com
- Country
- China
- ProdList
- 729
- Advantage
- 55
- Tel
- 136-16210669 13914021065
- Fax
- 0512-66627360
- sales@guide-chemicals.com
- Country
- China
- ProdList
- 271
- Advantage
- 60
- Tel
- 4008-755-333 18080918076
- Fax
- 028-86757656
- 800078821@qq.com
- Country
- China
- ProdList
- 9718
- Advantage
- 55
- Tel
- 86-21-34053660
- Fax
- 86-21-34053661
- sale@labgogo.com
- Country
- China
- ProdList
- 9865
- Advantage
- 52
- Tel
- 800-810-5118
- Fax
- +86-10-84193589
- cnchemical@thermofisher.com
- Country
- China
- ProdList
- 17770
- Advantage
- 75
- Tel
- 400-810-7969 010-59572699
- Fax
- 010-59572688
- ningzi.li@inno-chem.com.cn
- Country
- China
- ProdList
- 6134
- Advantage
- 55
- Tel
- 021-58170097
- info@topbiochem.com
- Country
- China
- ProdList
- 9459
- Advantage
- 58
- Tel
- 025-66099280 17798518460
- Fax
- (1)02557626880
- cfzhang@aikonchem.com
- Country
- China
- ProdList
- 19915
- Advantage
- 55
- Tel
- 18017383231 18017383231
- Fax
- qq：2817624287
- lyh_antaeus@163.com
- Country
- China
- ProdList
- 9347
- Advantage
- 55
- Tel
- 4009209199
- Fax
- 86-021-52271987
- sales@9dingchem.com
- Country
- China
- ProdList
- 18209
- Advantage
- 56
- Tel
- 400-400-6206333 18521732826
- Fax
- 021-50323701
- market@aladdin-e.com
- Country
- China
- ProdList
- 25003
- Advantage
- 65
- Tel
- 028-87578473
- Fax
- +86 (28) 8757-8473
- ellnn@163.com
- Country
- China
- ProdList
- 50
- Advantage
- 60
- Tel
- 021-61552785
- Fax
- 021-55660885
- sales@shshiji.com
- Country
- China
- ProdList
- 9545
- Advantage
- 55
- Tel
- 021-62960152
- Fax
- 021-52212593
- 934678158@qq.com
- Country
- China
- ProdList
- 9899
- Advantage
- 55
- Tel
- +86-28-85122536 85324413
- Fax
- +86-28-85326443
- market@astatech.cn
- Country
- China
- ProdList
- 8026
- Advantage
- 55
- Tel
- 021-021-33632979 15002134094
- Fax
- 021-33632979
- marketing@targetmol.com
- Country
- China
- ProdList
- 7783
- Advantage
- 58
- Tel
- 021-61995394 18916691159
- chemicalsea@163.com
- Country
- China
- ProdList
- 1972
- Advantage
- 58
More
Less
View Lastest Price from Ethyl (triphenylphosphoranylidene)acetate manufacturers
WUHAN FORTUNA CHEMICAL CO., LTD
- Product
- Ethyl (triphenylphosphoranylidene)acetate 1099-45-2
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-02-23
.GZ HONESTCHEM CO.,LTD
- Product
- (Carbethoxymethylene)triphenylphosphorane 1099-45-2
- Price
- US $1.00/g
- Min. Order
- 300g
- Purity
- 99.8%
- Supply Ability
- 20 TONS
- Release date
- 2021-07-05
Shaanxi Dideu Medichem Co. Ltd
- Product
- Ethyl (triphenylphosphoranylidene)acetate 1099-45-2
- Price
- US $1.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 Tons
- Release date
- 2020-01-14
1099-45-2, Ethyl (triphenylphosphoranylidene)acetateRelated Search:
Ethyltriphenylphosphonium acetate
Tocopheryl acetate
Sodium acetate
Benzyl acetate
Ethyl acetate
Triacetin
Butyl acetate
N,N-Dimethylacetamide
Vinyl acetate
Ethylene dimethacrylate
Methyl acetate
N,N,N',N'-Tetramethylethylenediamine
Triphenylphosphine
2,3-Butanedione
Ethyltriphenylphosphonium iodide
Potassium Acetate
Amyl acetate
Glatiramer acetate