Chloroacetamide

Product Name: Chloroacetamide
CAS No.: 79-07-2
Chemical Name: Chloroacetamide
Synonyms: 2-CHLOROACETAMIDE;Chloracetamide;Microcide;KM 101;0/2/79;NSC 8408;mergalaf;Mergal AF;NSC 54286;usafdo-29
CBNumber: CB5691957
Molecular Formula: C2H4ClNO
Formula Weight: 93.51
MOL File: 79-07-2.mol

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Chloroacetamide Property

Melting point:: 116-118 °C(lit.)
Boiling point:: 224.5 °C
Density: 0.84
vapor pressure: 0.05 mm Hg ( 20 °C)
refractive index: 1.4480 (estimate)
Flash point:: 170 °C
storage temp.: Store below +30°C.
solubility: methanol: soluble1g/10 mL
pka: 14.69±0.40(Predicted)
form: Crystalline Powder
color: White
PH: 3.8-4.1 (40g/l, H2O, 20℃)
Water Solubility: Soluble in water(90g/L).
Merck: 14,2110
BRN: 878191
InChIKey: VXIVSQZSERGHQP-UHFFFAOYSA-N
LogP: -0.530
CAS DataBase Reference: 79-07-2(CAS DataBase Reference)
NIST Chemistry Reference: Acetamide, 2-chloro-(79-07-2)
EPA Substance Registry System: Acetamide, 2-chloro- (79-07-2)

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Safety

Hazard Codes: T
Risk Statements: 25-43-62
Safety Statements: 22-36/37-45
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 2
RTECS: AB5075000
TSCA: Yes
HazardClass: 6.1
PackingGroup: III
HS Code: 29241900
Hazardous Substances Data: 79-07-2(Hazardous Substances Data)
Toxicity: LD50 orally in Rabbit: 138 mg/kg LD50 dermal Rat > 2000 mg/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H317May cause an allergic skin reaction

Precautionary statements

P201Obtain special instructions before use.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: C0267
Product name: 2-Chloroacetamide
Purity: ≥98%
Packaging: 1kg
Price: $92.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.02412
Product name: 2-Chloroacetamide
Purity: for synthesis
Packaging: 100g
Price: $27.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.02412
Product name: 2-Chloroacetamide
Purity: for synthesis
Packaging: 1kg
Price: $104
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.02412
Product name: 2-Chloroacetamide
Purity: for synthesis
Packaging: 25kg
Price: $976
Updated: 2024/03/01

Sigma-Aldrich

Product number: 22790
Product name: 2-Chloroacetamide
Purity: ≥98.0% (HPLC)
Packaging: 250g
Price: $35
Updated: 2024/03/01

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Chloroacetamide Chemical Properties,Usage,Production

Description

Chloroacetamide is a preservative used in several applications such as in cutting metalwork fluids, in paints or in glues. It can induce contact dermatitis in hairdressers, or in shoemakers when used as a leather preservative.

Chemical Properties

white crystalline powder

Uses

2-Chloroacetamide is used as surface-active agent in home laundry, cleaning products & household formulated cleaners, other industrial uses, petroleum production, polymer processing.

Uses

A component of herbicidal mixtures of cellulose biosynthesis inhibitors with VLCFA inhibitors.

Uses

preservative in cosmetic and pharmaceutical creams, shampoos, bath lotions, etc.; preservative in glues, cooling fluids.

Flammability and Explosibility

Non flammable

Contact allergens

Chloroacetamide as a preservative is used in several applications as in cutting metalworking fluids, in paints or in glues. It can induce contact dermatitis in hairdressers or in shoemakers, being used as a leather preservative.

Safety Profile

Poison by ingestion, intravenous, and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits very toxic Cland NOx. See also N-CHLOROACETAMIDE.

Synthesis

Chloroacetamide can be prepared from chloroacetyl chloride and dry ammonia gas and by treating ethyl chloroacetate or methyl chloroacetate with cold aqueous ammonia solutions in a 2-l. A round-bottomed flask fitted with a mechanical stirrer and surrounded by an ice-salt bath is placed 215 g. (1.75 moles) of ethyl chloroacetate. Vigorous stirring is started, and 200 cc. of chilled aqueous ammonia (sp. gr. 0.9) is added to the cold ester. The solution is stirred in the cold for about fifteen minutes, then another 200. A portion of aqueous ammonia is added, and the stirring is continued for about fifteen minutes. The mixture is then allowed to stand for thirty minutes, filtered with suction, and washed with two 25-cc. portions of cold water to remove ammonium chloride. The yield of air-dried material melting at 118–119℃ is 128–138 g. This product contains traces of ammonium chloride, which may be removed by crystallization from water. When 100 g. of crude product is recrystallized from 400 cc. of water, about 80 g. of product Chloroacetamide is obtained. The recrystallized product melts at 119–120°.

Purification Methods

Recrystallise the amide from acetone and dry it under vacuum over P2O5. [Beilstein 2 IV 490.]

Chloroacetamide Preparation Products And Raw materials

Raw materials

Ammonium chloride Ethyl chloroacetate

Preparation Products

Machette L-Aspartic acid 2-Iodoacetamide Chloroacetonitrile 3-aminopropanamide 2-Chloro-5-methoxyphenylboronic acid CHLOROACETYL ISOCYANATE FLUOROACETAMIDE Nitrazepam

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Chloroacetamide Suppliers

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View Lastest Price from Chloroacetamide manufacturers

Hebei Longbang Technology Co., Ltd

Product: 2-Chloroacetamide 79-07-2
Price: US $6.00/kg
Min. Order: 1kg
Purity: More than 99%
Supply Ability: 2000KG/Month
Release date: 2024-04-29

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Chloroacetamide 79-07-2
Price: US $75.00-20.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-06-07

HebeiShuoshengImportandExportco.,Ltd

Product: Chloroacetamide 79-07-2
Price: US $6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 2000KG/Month
Release date: 2024-08-08

79-07-2, ChloroacetamideRelated Search:

2-Iodoacetamide DIACETAMIDE 2-Phenylacetamide N,N-Dimethylacetamide 2-Cyanoacetamide Thioacetamide Acetamide Acetaminophen Chloroacetyl chloride Difluorochloromethane 3,5-DICHLORO-2-PYRIDONE FLUOROACETAMIDE Dichloroacetamide 2,2,2-Trichloroacetamide CHLOROACETYL ISOCYANATE 5-Chlorouracil CHLOROACETYL-L-TYROSINE N-Methylolchloroacetamide

KM 101

NSC 54286

NSC 8408

2-ChloroacetaMide >=98.0% (HPLC)

Piracetam Imp. B

chloroacetylamine

Mergal AF

mergalaf

Microcide

USAF do-29

usafdo-29

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2-ChloroacetaMideClCH2CONH2

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2-ChloroacetaMide, 98% 500GR

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2-ChloroacetamideClCH2CONH2,Chloroacetamide, 2-Chloroethanamide

79-07-2 Chloroacetamide

2-Chloroacetamide [CAD

0/2/79

79-07-2

1979-07-2

1979-7-2

197-97-2

1979-07-02

1979/7/2

ClCH2CONH2

C2H4ClNO

CH2ClCONH2

AMINE

Organic Building Blocks

Carbonyl Compounds

Building Blocks

Amides

Amines

Inhibitors

API Intermediate