4-Chlorothiophenol

Product Name: 4-Chlorothiophenol
CAS No.: 106-54-7
Chemical Name: 4-Chlorothiophenol
Synonyms: 4-CHLOROBENZENETHIOL;4-Chloro;PARA-CHLOROTHIOPHENOL;NSC 229564;orothiophenoL;p-Chlorthiofenol;4-CHLOROTHIOPENOL;4-chlorthiophenol;AKOS BBS-00004252;CHLOROTHIOPHENOL-4
CBNumber: CB6130893
Molecular Formula: C6H5ClS
Formula Weight: 144.62
MOL File: 106-54-7.mol

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4-Chlorothiophenol Property

Melting point:: 49-51 °C(lit.)
Boiling point:: 205-207 °C(lit.)
Density: 1.1911
refractive index: 1.5480
Flash point:: >230 °F
storage temp.: 2-8°C
solubility: methanol: soluble
pka: pK1:5.9 (25°C)
form: Crystalline Solid
color: White to almost white
Water Solubility: insoluble
Sensitive: Stench/Lachrymatory
BRN: 605971
InChIKey: VZXOZSQDJJNBRC-UHFFFAOYSA-N
CAS DataBase Reference: 106-54-7(CAS DataBase Reference)
NIST Chemistry Reference: Benzenethiol, 4-chloro-(106-54-7)
EPA Substance Registry System: Benzenethiol, 4-chloro- (106-54-7)

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Safety

Hazard Codes: C
Risk Statements: 22-34-36/37-20/21/22
Safety Statements: 26-36/37/39-45-27
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
RTECS: DC1050000
F: 9-13-23
Hazard Note: Corrosive/Lachrymatory/Stench
TSCA: Yes
HazardClass: 8
PackingGroup: III
HS Code: 29309090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 125237
Product name: 4-Chlorothiophenol
Purity: 97%
Packaging: 5g
Price: $45.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 125237
Product name: 4-Chlorothiophenol
Purity: 97%
Packaging: 100g
Price: $110
Updated: 2024/03/01

TCI Chemical

Product number: C0129
Product name: 4-Chlorobenzenethiol
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $41
Updated: 2024/03/01

TCI Chemical

Product number: C0129
Product name: 4-Chlorobenzenethiol
Purity: >98.0%(GC)(T)
Packaging: 500g
Price: $140
Updated: 2024/03/01

Alfa Aesar

Product number: B23838
Product name: 4-Chlorothiophenol, 97%
Packaging: 25g
Price: $24.65
Updated: 2024/03/01

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4-Chlorothiophenol Chemical Properties,Usage,Production

Chemical Properties

white to almost white crystalline solid

Uses

Oil additives, agricultural chemicals, plasticizers, rubber chemical, dyes, wetting agents, and stabilizers.

Uses

4-Chlorothiophenol was used to modify poly(vinyl chloride) and to synthesize poly(vinyl chloride) with halogen groups.

Synthesis Reference(s)

The Journal of Organic Chemistry, 27, p. 4455, 1962 DOI: 10.1021/jo01059a081
Synthetic Communications, 18, p. 575, 1988 DOI: 10.1080/00397918808064014

General Description

4-Chlorothiophenol undergoes oxidative coupling catalyzed by iron(III)-tetra phenyl prophyrin to form disulfides.

Hazard

Toxic by ingestion.

Purification Methods

Recrystallise the thiophenol from aqueous EtOH. The SMe ether has m 129o and the SEt ether has m 64o. [D'Sousa et al. J Org Chem 52 1720 1987, Beilstein 6 H 326, 6 I 149, 6 III 1034.]

4-Chlorothiophenol Preparation Products And Raw materials

Raw materials

Chlorosulfonic acid Chlorobenzene Sulfuric acid

Preparation Products

2-CHLORO-9-(3-(DIMETHYLAMINO)PROPYL)-TH& 5-CHLORO-3-METHYLBENZO[B]THIOPHENE-2-SULFONAMIDE 5-CHLORO-3-METHYLBENZO[B]THIOPHENE 5-CHLORO-BENZO[B]THIOPHENE-3-CARBOXYLIC ACID 1-(5-CHLOROBENZO[B]THIOPHEN-3-YL)ETHANONE CHLOROMETHYL 4-CHLOROPHENYL SULFIDE CARBOPHENOTHION 2-Chlorothioxanthone 5-CHLOROBENZOTHIOPHENE (5-CHLORO-1-BENZOTHIOPHEN-3-YL)METHANOL 5-CHLORO-3-METHYLBENZO[B]THIOPHENE-2-SULFONYL CHLORIDE 2-(4-chlorophenylthio)benzoic acid 4-(4-CHLOROPHENYLTHIO)-3-NITROBENZALDEHYDE (5-CHLORO-1-BENZOTHIOPHEN-3-YL)METHYLAMINE 3-(Bromomethyl)-5-chlorobenzo[b]thiophene

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4-Chlorothiophenol Suppliers

Americas 1 Belgium 1 China 177 Europe 4 France 1 Germany 3 India 38 Japan 10 Slovakia 1 South Korea 1 Switzerland 4 The Netherlands 1 Ukraine 1 United Kingdom 17 United States 33 Global 293

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View Lastest Price from 4-Chlorothiophenol manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: 4-Chlorothiophenol 106-54-7
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100 mt
Release date: 2024-11-18

Hebei Chuanghai Biotechnology Co,.LTD

Product: 4-Chlorothiophenol 106-54-7
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-09-20

Hebei Mojin Biotechnology Co., Ltd

Product: 4-Chlorothiophenol 106-54-7
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-06-21

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