Methyl 6-broMo-3-Methoxypicolinate
- Product Name
- Methyl 6-broMo-3-Methoxypicolinate
- CAS No.
- 945954-94-9
- Chemical Name
- Methyl 6-broMo-3-Methoxypicolinate
- Synonyms
- Methyl 6-broMo-3-Methoxypicolinate;methyl 6-bromo-3-methoxypyridine-2-carboxylate;methyl 6-bromo-3-methoxypyridine-2-carboxylate - [AC80521];2-Pyridinecarboxylic acid, 6-bromo-3-methoxy-, methyl ester
- CBNumber
- CB62549552
- Molecular Formula
- C8H8BrNO3
- Formula Weight
- 246.06
- MOL File
- 945954-94-9.mol
Methyl 6-broMo-3-Methoxypicolinate Property
- Boiling point:
- 338.2±37.0 °C(Predicted)
- Density
- 1.530±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C
- pka
- -1.56±0.10(Predicted)
- Appearance
- White to off-white Solid
N-Bromosuccinimide Price
- Product number
- HCH0369577
- Product name
- METHYL-6-BROMO-3-METHOXYPICOLINATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $499.8
- Updated
- 2021/12/16
- Product number
- 143724
- Product name
- Methyl 6-bromo-3-methoxypicolinate
- Purity
- 95%
- Packaging
- 1g
- Price
- $1388
- Updated
- 2021/12/16
- Product number
- 143724
- Product name
- Methyl 6-bromo-3-methoxypicolinate
- Purity
- 95%
- Packaging
- 5g
- Price
- $4163
- Updated
- 2021/12/16
- Product number
- A167550
- Product name
- Methyl6-bromo-3-methoxypicolinate
- Purity
- 98%
- Packaging
- 5g
- Price
- $754
- Updated
- 2021/12/16
- Product number
- CM126470
- Product name
- methyl6-bromo-3-methoxypicolinate
- Purity
- 98%
- Packaging
- 5g
- Price
- $857
- Updated
- 2021/12/16
Methyl 6-broMo-3-Methoxypicolinate Chemical Properties,Usage,Production
Synthesis
321601-48-3
74-88-4
945954-94-9
General procedure for the synthesis of methyl 6-bromo-3-methoxypyridine carboxylate from methyl 6-bromo-3-hydroxypyridine-2-carboxylate and iodomethane: Methyl 6-bromo-3-hydroxypyridine-2-carboxylate (4 g, 17.2 mmol), iodomethane (7.15 g, 34.5 mmol) and potassium carbonate (4.76 g, 34.5 mmol) were dissolved in N,N- dimethylformamide (50 mL) and the reaction was stirred at room temperature for 3 hours. After completion of the reaction, the reaction mixture was concentrated under reduced pressure, diluted with water and extracted with ethyl acetate (50 mL x 3). The organic layers were combined, dried with anhydrous sodium sulfate and concentrated under reduced pressure to give the crude product methyl 6-bromo-3-methoxypyridinecarboxylate (4 g, yield: 90%). The product was identified by NMR hydrogen spectroscopy (CDCl3, 400 MHz): δ 7.56 (d, J = 8.0 Hz, 1H), 7.25 (d, J = 8.0 Hz, 1H), 3.94 (s, 3H), 3.90 (s, 3H). Mass spectrum (M + H)+: 256/258.
References
[1] Patent: WO2014/121418, 2014, A1. Location in patent: Page/Page column 45
[2] Patent: EP3255042, 2017, A2. Location in patent: Paragraph 0180; 0183
[3] Patent: WO2007/89031, 2007, A1. Location in patent: Page/Page column 84-85
[4] Patent: WO2014/209727, 2014, A1. Location in patent: Page/Page column 39
[5] Patent: WO2014/205593, 2014, A1. Location in patent: Page/Page column 41; 42
Methyl 6-broMo-3-Methoxypicolinate Preparation Products And Raw materials
Raw materials
Preparation Products
Methyl 6-broMo-3-Methoxypicolinate Suppliers
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- Country
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