XPhos Pd G2

ChemicalBook > CAS DataBase List > XPhos Pd G2

Appearance Reaction

Product Name: XPhos Pd G2
CAS No.: 1310584-14-5
Chemical Name: XPhos Pd G2
Synonyms: 2nd Generation XPhos Precatalyst;chloro(2-dicyclohexylphosphino-2',4',6'-triisoporpyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)] palladium (II);Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2'-aMino-1,1'-biphenyl)]palladiuM(II);XPhos Pd G2;oro(2-dicycL;Palladium-Xphos;Xphos Palladacycle Gen.2;)[2-(2'-amino-1,1'-biphenyL;Chloro(2-dicyclohexylphosphin;XPhos Pd G2 ISO 9001：2015 REACH
CBNumber: CB62654276
Molecular Formula: C45H58ClNPPd+2
Formula Weight: 785.795481
MOL File: 1310584-14-5.mol

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XPhos Pd G2 Property

Melting point:: 202-210°C
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
color: white
InChI: InChI=1S/C33H48ClP.C12H10N.Pd/c1-22(2)25-20-29(23(3)4)32(30(21-25)24(5)6)28-18-13-19-31(34)33(28)35(26-14-9-7-10-15-26)27-16-11-8-12-17-27;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;/h13,18-24,26-27H,7-12,14-17H2,1-6H3;1-6,8-9H,13H2;/q;;+2
InChIKey: USWOVTRTHZODCW-UHFFFAOYSA-N
SMILES: C1(C2=CC=CC=C2N)=CC=CC=C1[Pd+2].C1(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)=CC=CC(Cl)=C1P(C1CCCCC1)C1CCCCC1

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 741825
Product name: XPhos Pd G2
Packaging: 1g
Price: $143
Updated: 2024/03/01

Sigma-Aldrich

Product number: 741825
Product name: XPhos Pd G2
Packaging: 5g
Price: $507
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0281
Product name: Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II), min. 98% [XPhos Palladacycle Gen. 2]
Packaging: 250mg
Price: $40
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0281
Product name: Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II), min. 98% [XPhos Palladacycle Gen. 2]
Packaging: 1g
Price: $121
Updated: 2024/03/01

Sigma-Aldrich

Product number: 741825
Product name: XPhos Pd G2
Packaging: 250mg
Price: $44.2
Updated: 2024/03/01

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XPhos Pd G2 Chemical Properties,Usage,Production

Appearance

Turquoise or grey or dark green powder

Reaction

Palladium precatalyst for Suzuki-Miyaura coupling reactions.

Uses

XPhos Pd G2 is a used as a catalyst in chemical reactions.

Uses

XPhos Pd G2 was employed as catalyst in the following reactions:

Palladium-catalyzed Suzuki-Miyaura coupling reactions of potassium organotrifluoroborates and sulfamates.
Suzuki-Miyaura cross-coupling reactions of sensitive aryl and heteroarylboronic acids.
Synthesis of potassium Boc-protected secondary aminomethyltrifluoroborates, via Suzuki-Miyaura cross-coupling reaction.

Application

XPhos Pd G2 is a second-generation Buchwald catalyst typically used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions.

General Description

XPhos Pd G2 is a bulky monodentate biaryl ligand. It is a Buchwald′s 2^nd generation preformed catalyst. It undergoes rapid reductive elimination to form a reactive, monoligated Pd(0) species.

XPhos Pd G2 Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from XPhos Pd G2 manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: XPhos Pd G2 1310584-14-5
Price: US $0.00/G
Min. Order: 10G
Purity: 98%min
Supply Ability: 30kg/month
Release date: 2023-02-03

Hebei Guanlang Biotechnology Co., Ltd.

Product: XPhos Pd G2 1310584-14-5
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2021-04-01

Wuhan LPBchem Technology Co.,Ltd

Product: Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / XPhos Pd G2 1310584-14-5
Price: US $10.00-10.00/g
Min. Order: 1g
Purity: 0.98
Supply Ability: 50kg
Release date: 2020-11-27

1310584-14-5, XPhos Pd G2Related Search:

XPhos Pd G3 XPhos Pd G4 Chloro(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [BrettPhos Palladacycle] BrettPhos Pd G3 RuPhos Pd G1 Methyl t--Butyl Ether Adduct BrettPhosPalladacycle Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2 tBuXPhos Pd G1 XPhos Pd G1 RuPhos Pd G3 Bis(diphenylphosphinophenyl)ether palladium (II) dichloride Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)

Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl) palladiuM(II), Min. 98% [XPhos Palladacycle]

Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2'-aMino-1,1'-biphenyl)]palladiuM(II)

Chloro(2-dicyclohexylphosphin

(SP-4-4)-[2'-Amino[1,1'-biphenyl]-2-yl]chloro[dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine]palladium

2nd Generation XPhos Precatalyst

X-Phos aminobiphenyl palladium chloride precatalyst

Palladium-Xphos

-biphenyl-2-yl) palladium(II), min. 98%

XPhos Pd G2

CHLORO(2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL) PALLADIUM(II), MIN

Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II)

chloro(2-dicyclohexylphosphino-2',4',6'-triisoporpyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)] palladium (II)

Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II), min. 98% [XPhos Palladacycle Gen. 2]

Xphos Palladacycle Gen.2

Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl) palladiuM(II) [XPhos Palladacycle]

Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / XPhos Pd G2

)[2-(2'-amino-1,1'-biphenyL

oro(2-dicycL

Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro[dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine]-, (SP-4-4)-

2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro[dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine]palladium

Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl)(2'-aminobiphenyl-2-yl)palladium(II)

XPhos Pd G2 ISO 9001：2015 REACH

Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-bi...

dicyclohexyl-[3-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane

XPhos Pd G2 / Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II) (XPhos Pd G2)

2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro[dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine]palladium

2-(2′-amino-1,1′-biphenyl)]palladium(II), X-Phos aminobiphenyl palladium chloride precatalyst, XPhos-Pd-G2

Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)

1310584-14-5

310584-14-5

C45H59ClNPPd

C33H49PC12H10ClNPd

Buchwald Ligands&Precatalysts

Buchwald Precatalysts Series