Appearance Reaction
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XPhos Pd G2

Appearance Reaction
Product Name
XPhos Pd G2
CAS No.
1310584-14-5
Chemical Name
XPhos Pd G2
Synonyms
2nd Generation XPhos Precatalyst;chloro(2-dicyclohexylphosphino-2',4',6'-triisoporpyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)] palladium (II);Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2'-aMino-1,1'-biphenyl)]palladiuM(II);XPhos Pd G2;oro(2-dicycL;Palladium-Xphos;Xphos Palladacycle Gen.2;)[2-(2'-amino-1,1'-biphenyL;Chloro(2-dicyclohexylphosphin;XPhos Pd G2 ISO 9001：2015 REACH
CBNumber
CB62654276
Molecular Formula
C45H58ClNPPd+2
Formula Weight
785.795481
MOL File
1310584-14-5.mol
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XPhos Pd G2 Property

Melting point:
202-210°C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
white
InChI
InChI=1S/C33H48ClP.C12H10N.Pd/c1-22(2)25-20-29(23(3)4)32(30(21-25)24(5)6)28-18-13-19-31(34)33(28)35(26-14-9-7-10-15-26)27-16-11-8-12-17-27;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;/h13,18-24,26-27H,7-12,14-17H2,1-6H3;1-6,8-9H,13H2;/q;;+2
InChIKey
USWOVTRTHZODCW-UHFFFAOYSA-N
SMILES
C1(C2=CC=CC=C2N)=CC=CC=C1[Pd+2].C1(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)=CC=CC(Cl)=C1P(C1CCCCC1)C1CCCCC1
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
741825
Product name
XPhos Pd G2
Packaging
1g
Price
$143
Updated
2024/03/01
Sigma-Aldrich
Product number
741825
Product name
XPhos Pd G2
Packaging
5g
Price
$507
Updated
2024/03/01
Strem Chemicals
Product number
46-0281
Product name
Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II), min. 98% [XPhos Palladacycle Gen. 2]
Packaging
250mg
Price
$40
Updated
2024/03/01
Strem Chemicals
Product number
46-0281
Product name
Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II), min. 98% [XPhos Palladacycle Gen. 2]
Packaging
1g
Price
$121
Updated
2024/03/01
Sigma-Aldrich
Product number
741825
Product name
XPhos Pd G2
Packaging
250mg
Price
$44.2
Updated
2024/03/01
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XPhos Pd G2 Chemical Properties,Usage,Production

Appearance

Turquoise or grey or dark green powder

Reaction

Palladium precatalyst for Suzuki-Miyaura coupling reactions.

Uses

XPhos Pd G2 is a used as a catalyst in chemical reactions.

Uses

XPhos Pd G2 was employed as catalyst in the following reactions:

  • Palladium-catalyzed Suzuki-Miyaura coupling reactions of potassium organotrifluoroborates and sulfamates.
  • Suzuki-Miyaura cross-coupling reactions of sensitive aryl and heteroarylboronic acids.
  • Synthesis of potassium Boc-protected secondary aminomethyltrifluoroborates, via Suzuki-Miyaura cross-coupling reaction.

Application

XPhos Pd G2 is a second-generation Buchwald catalyst typically used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions. 

General Description

XPhos Pd G2 is a bulky monodentate biaryl ligand. It is a Buchwald′s 2nd generation preformed catalyst. It undergoes rapid reductive elimination to form a reactive, monoligated Pd(0) species.

XPhos Pd G2 Preparation Products And Raw materials

Raw materials

Preparation Products

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XPhos Pd G2 Suppliers

Australia 1 China 177 India 3 Switzerland 1 United States 10 Global 192
Biosynth AG
Tel
--
Fax
--
Email
welcome@biosynth.ch
Country
Switzerland
ProdList
3324
Advantage
72
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View Lastest Price from XPhos Pd G2 manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
XPhos Pd G2 1310584-14-5
Price
US $0.00/G
Min. Order
10G
Purity
98%min
Supply Ability
30kg/month
Release date
2023-02-03
Hebei Weibang Biotechnology Co., Ltd
Product
XPhos Pd G2 1310584-14-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-04-01
Wuhan LPBchem Technology Co.,Ltd
Product
Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / XPhos Pd G2 1310584-14-5
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2020-11-27

1310584-14-5, XPhos Pd G2Related Search:

XPhos Pd G3 XPhos Pd G4 Chloro(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [BrettPhos Palladacycle] BrettPhos Pd G3 RuPhos Pd G1 Methyl t--Butyl Ether Adduct BrettPhosPalladacycle Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2 tBuXPhos Pd G1 XPhos Pd G1 RuPhos Pd G3 Bis(diphenylphosphinophenyl)ether palladium (II) dichloride Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)

  • Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl) palladiuM(II), Min. 98% [XPhos Palladacycle]
  • Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2'-aMino-1,1'-biphenyl)]palladiuM(II)
  • Chloro(2-dicyclohexylphosphin
  • (SP-4-4)-[2'-Amino[1,1'-biphenyl]-2-yl]chloro[dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine]palladium
  • 2nd Generation XPhos Precatalyst
  • X-Phos aminobiphenyl palladium chloride precatalyst
  • Palladium-Xphos
  • -biphenyl-2-yl) palladium(II), min. 98%
  • XPhos Pd G2
  • CHLORO(2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL) PALLADIUM(II), MIN
  • Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II)
  • chloro(2-dicyclohexylphosphino-2',4',6'-triisoporpyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)] palladium (II)
  • Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II), min. 98% [XPhos Palladacycle Gen. 2]
  • Xphos Palladacycle Gen.2
  • Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl) palladiuM(II) [XPhos Palladacycle]
  • Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / XPhos Pd G2
  • )[2-(2'-amino-1,1'-biphenyL
  • oro(2-dicycL
  • Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro[dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine]-, (SP-4-4)-
  • 2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro[dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine]palladium
  • Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl)(2'-aminobiphenyl-2-yl)palladium(II)
  • XPhos Pd G2 ISO 9001：2015 REACH
  • Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-bi...
  • dicyclohexyl-[3-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane
  • XPhos Pd G2 / Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II) (XPhos Pd G2)
  • 2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro[dicyclohexyl[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine]palladium
  • 2-(2′-amino-1,1′-biphenyl)]palladium(II), X-Phos aminobiphenyl palladium chloride precatalyst, XPhos-Pd-G2
  • Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
  • chloro(2-dicyclohexylphosphino-2',4',6'-triisoporpyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)] palladium (II)
  • Chloro(2-dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II)
  • (SP-4-4)-[2′-(Amino-κN)[1,1′-biphenyl]-2-yl-κC]chloro[dicyclohexyl[2′,4′,6′-tris(1-methylethyl)[1,1′-biphenyl]-2-yl]phosphine]palladium (ACI)
  • Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • Chloro(2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II) (XPhos Pd G2)
  • 1310584-14-5
  • 310584-14-5
  • C45H59ClNPPd
  • C33H49PC12H10ClNPd
  • Pd
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series