4-AMINO-5-BROMO-3-METHYLPYRIDINE

Product Name: 4-AMINO-5-BROMO-3-METHYLPYRIDINE
CAS No.: 97944-43-9
Chemical Name: 4-AMINO-5-BROMO-3-METHYLPYRIDINE
Synonyms: 4-AMINO-5-BROMO-3-PICOLINE;3-Bromo-5-methyl-4-pyridinamine;3-Bromo-5-methylpyridin-4-amine;4-AMINO-5-BROMO-3-METHYLPYRIDINE;4-Pyridinamine, 3-bromo-5-methyl-;3-Bromo-5-methyl-pyridin-4-ylamine;4-Amino-5-bromo-3-methylpyridine 95+%;4-AMINO-5-BROMO-3-METHYLPYRIDINE ISO 9001：2015 REACH
CBNumber: CB6367420
Molecular Formula: C6H7BrN2
Formula Weight: 187.04
MOL File: 97944-43-9.mol

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4-AMINO-5-BROMO-3-METHYLPYRIDINE Property

Melting point:: 115.0 °C
Boiling point:: 290.0±35.0 °C(Predicted)
Density: 1.593±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
pka: 7.34±0.24(Predicted)
Appearance: White to off-white Solid
InChI: InChI=1S/C6H7BrN2/c1-4-2-9-3-5(7)6(4)8/h2-3H,1H3,(H2,8,9)
InChIKey: GUAFGBUKLIFASX-UHFFFAOYSA-N
SMILES: C1=NC=C(C)C(N)=C1Br

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Safety

HS Code: 2933399990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H320Causes eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B623740
Product name: 3-Bromo-5-methylpyridin-4-amine
Packaging: 100mg
Price: $65
Updated: 2021/12/16

Activate Scientific

Product number: AS12121
Product name: 3-Bromo-5-methyl-pyridin-4-ylamine
Purity: 97%
Packaging: 1g
Price: $53
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB140920
Product name: 3-Bromo-5-methylpyridin-4-amine
Packaging: 250mg
Price: $72.5
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB140920
Product name: 3-Bromo-5-methylpyridin-4-amine
Packaging: 500mg
Price: $125
Updated: 2021/12/16

SynQuest Laboratories

Product number: 3H30-9-95
Product name: 4-Amino-5-bromo-3-methylpyridine
Packaging: 5G
Price: $183
Updated: 2021/12/16

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4-AMINO-5-BROMO-3-METHYLPYRIDINE Chemical Properties,Usage,Production

Synthesis

1990-90-5

97944-43-9

The general procedure for the synthesis of 3-methyl-4-amino-5-bromopyridine from 3-methyl-4-aminopyridine is as follows: Step 1: To a solution of 4-amino-3-methylpyridine (97, 10 g, 0.092 mol) and hydrobromic acid (HBr, 50 mL) heated to 70 °C was slowly added 15% hydrogen peroxide (H2O2, 16 mL) over a period of 1 hour. The reaction mixture was continued to be stirred at 70 °C for 1 h. The reaction was subsequently quenched by pouring into ice (100 g). The pH of the reaction mixture was adjusted to about 5 with 50% sodium hydroxide (NaOH) solution and the resulting red precipitate was collected by filtration. Subsequently, the pH of the filtrate was adjusted to about 9 and the resulting white precipitate was collected by filtration to afford 3-methyl-4-amino-5-bromopyridine (98, 13.5 g, 78% yield).

References

[1] Patent: WO2005/16892, 2005, A1. Location in patent: Page/Page column 104
[2] Journal fuer Praktische Chemie (Leipzig), 1989, vol. 331, # 3, p. 369 - 374
[3] Journal fuer Praktische Chemie (Leipzig), 1989, vol. 331, # 3, p. 369 - 374
[4] Patent: US2013/5705, 2013, A1

4-AMINO-5-BROMO-3-METHYLPYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-AMINO-5-BROMO-3-METHYLPYRIDINE Suppliers

China 74 Germany 1 India 3 United Kingdom 2 United States 7 Global 87

Changzhou Jienuo Pharmaceutical Technology Co., Ltd

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Capot Chemical Co., Ltd

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Chiba Pharmaceutical Science and technology Co, Ltd.

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Hebei Summedchem Co.,Ltd

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Synchem OHG

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ShangHai KenEn Chemical Technology Co., Ltd.

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Shanghai Balmxy Pharmaceutical Co., Ltd

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Shanghai Yongye Biotechnology Co., Ltd.

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View Lastest Price from 4-AMINO-5-BROMO-3-METHYLPYRIDINE manufacturers

Dideu Industries Group Limited

Product: 4-AMINO-5-BROMO-3-METHYLPYRIDINE 97944-43-9
Price: US $1.10/g
Min. Order: 1g
Purity: 99.00%
Supply Ability: 100 Tons min
Release date: 2021-08-31

97944-43-9, 4-AMINO-5-BROMO-3-METHYLPYRIDINERelated Search:

ETHYL 3-(4-AMINO-5-BROMOPYRIDIN-3-YL)ACRYLATE 3-Amino-2-bromo-4-methylpyridine 2-AMINO-3-BROMO-4-METHYLPYRIDINE 5-Amino-2-bromo-4-methylpyridine 4-AMINO-5-BROMO-2-METHYLPYRIDINE 3-Amino-5-bromo-2-methylpyridine 5-AMINO-3-BROMO-2-METHYLPYRIDINE 3-Amino-2-bromo-5-methylpyridine 2-Amino-5-bromo-4-methylpyridine 6-BROMO-5-AMINO-2-PICOLINE (3-AMINO-2-BROMO-6-METHYLPYRIDINE),3-AMINO-2-BROMO-6-METHYLPYRIDINE,98+% 2-AMINO-3-BROMO-6-METHYLPYRIDINE,2-AMINO-3-BROMO-6-PICOLINE (2-AMINO-3-BROMO-6-METHYLPYRIDINE) 4-AMINO-5-BROMO-3-METHYLPYRIDINE 4-AMINO-5-BROMO NICOTINIC ACID 2-Amino-5-bromo-6-methylpyridine 5-AMINO-2-BROMO-6-PICOLINE (5-AMINO-2-BROMO-6-METHYLPYRIDINE),5-AMINO-2-BROMO-6-METHYLPYRIDINE,3-AMINO-6-BROMO-2-METHYLPYRIDINE 4-Bromo-2-methyl-3-pyridinamine 2-Amino-3-bromo-5-methylpyridine 5-AMINO-2-BROMO-3-METHYLPYRIDINE,5-AMINO-2-BROMO-3-PICOLINE (5-AMINO-2-BROMO-3-METHYLPYRIDINE)

4-Amino-5-bromo-3-methylpyridine 95+%

4-AMINO-5-BROMO-3-METHYLPYRIDINE

4-AMINO-5-BROMO-3-PICOLINE

3-Bromo-5-methylpyridin-4-amine

3-Bromo-5-methyl-4-pyridinamine

3-Bromo-5-methyl-pyridin-4-ylamine

4-Pyridinamine, 3-bromo-5-methyl-

4-AMINO-5-BROMO-3-METHYLPYRIDINE ISO 9001：2015 REACH

97944-43-9

Pyridines

Pyridine