ChemicalBook > CAS DataBase List > 4'-CHLORO-2,2':6',2''-TERPYRIDINE

4'-CHLORO-2,2':6',2''-TERPYRIDINE

Product Name
4'-CHLORO-2,2':6',2''-TERPYRIDINE
CAS No.
128143-89-5
Chemical Name
4'-CHLORO-2,2':6',2''-TERPYRIDINE
Synonyms
DK7365;4'-Chloro-α,α',α''-tripyridyl;4'-CHLORO-2,2'6'2''-TERPYRIDINE;4'-CHLORO-2,2':6',2''-TERPYRIDINE;4'-CHLORO-2,2':6',2''-TERPYRIDINE;2,2':6',2''-Terpyridine,4'-chloro-;4'-Chloro-2,2,2':6',2''-terpyridine;4'-Chloro-2,2':6',2"-terpyridine-98%;4'-Chloro-2,2':6',2"-terpyridine-98%;4-Chloro-2,6-di(pyridin-2-yl)pyridine
CBNumber
CB6491835
Molecular Formula
C15H10ClN3
Formula Weight
267.71
MOL File
128143-89-5.mol
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4'-CHLORO-2,2':6',2''-TERPYRIDINE Property

Melting point:
148-150 °C(lit.)
Boiling point:
416.73°C (rough estimate)
Density 
1.2245 (rough estimate)
refractive index 
1.6010 (estimate)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Crystalline Powder
pka
4.22±0.22(Predicted)
color 
Brown
Water Solubility 
Slightly soluble in water.
λmax
278nm(CH3CN)(lit.)
BRN 
3613386
InChIKey
AHEMFMCEBIJRMU-UHFFFAOYSA-N
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Safety

Hazard Codes 
Xn
Risk Statements 
22-37/38-41
Safety Statements 
26-39
RIDADR 
UN 2811 6.1 / PGIII
WGK Germany 
3
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
405868
Product name
4′-Chloro-2,2′:6′,2′′-terpyridine
Purity
99%
Packaging
1g
Price
$215
Updated
2024/03/01
TCI Chemical
Product number
C3187
Product name
4'-Chloro-2,2':6',2''-terpyridine
Purity
>98.0%(GC)(T)
Packaging
200mg
Price
$69
Updated
2024/03/01
TCI Chemical
Product number
C3187
Product name
4'-Chloro-2,2':6',2''-terpyridine
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$206
Updated
2024/03/01
Alfa Aesar
Product number
L14728
Product name
4'-Chloro-2,2':6',2''-terpyridine, 98%
Packaging
250mg
Price
$51.65
Updated
2024/03/01
Alfa Aesar
Product number
L14728
Product name
4'-Chloro-2,2':6',2''-terpyridine, 98%
Packaging
1g
Price
$145
Updated
2024/03/01
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4'-CHLORO-2,2':6',2''-TERPYRIDINE Chemical Properties,Usage,Production

Chemical Properties

brown crystalline powder

Uses

4'-Chloro-2,2':6',2''-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture double helicates, dendrimers, micelles and metallo-supramolecular polymers. It is used to synthesize the mono- and bis-terpyridines. It is actively involved in Williamson type ether reactions alpha,μ-bishydroxy-functionalized poly(propylene oxide).

General Description

4′-Chloro-2,2′:6′,2′′-terpyridine (4′-Cltpy, Cltpy, Cl-terpy) is a tridentate ligand that contains a terpyridine (tpy) site with a Cl site at the 4 -position. It coordinates with various metal ions through these two sites to form different coordination polymers. Crystal structure study shows terpyridine unit of Cltpy adopts a trans, trans conformation. Mol-ecules assemble themselves into stacked columns along the b axis, with an inter-planar distance of 3.51?. It undergoes Williamson type ether reactions with α,ω-bishydroxy-functionalized poly(propylene oxide). It undergoes Williamson type reaction with α-hydroxy-ω-carboxy-functionalized poly(ethylen-oxide) to afford monoterpyridine terminated telechelics.

4'-CHLORO-2,2':6',2''-TERPYRIDINE Preparation Products And Raw materials

Raw materials

Sodium hydride Acetone Phosphorus oxychloride Ethyl picolinate Phosphorus pentachloride Tetrahydrofuran Ammonium acetate

Preparation Products

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4'-CHLORO-2,2':6',2''-TERPYRIDINE Suppliers

Americas 1 Belgium 1 Canada 1 China 115 Europe 1 Germany 2 India 8 Japan 2 Switzerland 2 United Kingdom 4 United States 15 Global 152
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View Lastest Price from 4'-CHLORO-2,2':6',2''-TERPYRIDINE manufacturers

Shanghai UCHEM Inc.
Product
4'-CHLORO-2,2':6',2''-TERPYRIDINE 128143-89-5
Price
US $80.00-376.00/g
Min. Order
1g
Purity
0.98
Supply Ability
10kg
Release date
2024-04-12
Career Henan Chemical Co
Product
4'-CHLORO-2,2':6',2''-TERPYRIDINE 128143-89-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1ton
Release date
2019-07-11

128143-89-5, 4'-CHLORO-2,2':6',2''-TERPYRIDINERelated Search:

2,2'-BIPYRIDINE-5-CARBOXYLIC ACID 2,2'-DIPYRIDYL N,N'-DIOXIDE 2,2':6',2''-TERPYRIDINE-4,4',4''-TRICARBOXYLIC ACID 4,4'-Dimethyl-2,2'-bipyridyl 4‘-(4-hydroxyphenyl)-2, 2':6‘, 2“-terpyridine 1,3,5-Tris(m-iodophenyl)benzene 4'-BROMO-2,2':6',2''-TERPYRIDINE 4-Methyl-4'-(3-carboxypropyl)-2,2'-bipyridine 6-BROMO-2,2'-BIPYRIDINE 6''-CHLORO-[3,2':5',3'']-TERPYRIDINE 2,2':6',2''-TERPYRIDINE 4-Chloro-2,6-dimethylpyridine 4'-CHLORO-2,2':6',2''-TERPYRIDINE 2,2'-BIPYRIDINE HYDROCHLORIDE 4-Chloro-2,2'-bipyridine 6-METHYL-2,2'-BIPYRIDINE 2,6-Lutidinehydrochloride CHLORO(2,2':6',2''-TERPYRIDINE)PLATINUM(II) CHLORIDE DIHYDRATE

  • 4'-CHLORO-2,2':6',2''-TERPYRIDINE
  • 4'-CHLORO-2,2'6'2''-TERPYRIDINE
  • 4-Chloro-2,6-di(pyridin-2-yl)pyridine ,99%
  • 4''-CHLORO-2,2'':6'',2''-TERPYRIDINE 99%
  • 4'-Chloro-2,2':6',2''-terpyridine,99%
  • 4-Chloro-2,6-di(pyridin-2-yl)pyridine
  • 2,2':6',2''-Terpyridine,4'-chloro-
  • 4'-Chloro-2,2,2':6',2''-terpyridine
  • 4'-Chloro-alpha,alpha',alpha''-tripyridyl
  • 4'-Chloro-2,2':6',2"-terpyridine-98%
  • 4-chloro-6-(pyridin-2-yl)-2,2''-bipyridine
  • DK7365
  • 4'-CHLORO-2,2':6',2''-TERPYRIDINE
  • 4'-Chloro-α,α',α''-tripyridyl
  • 4'-Chloro-2,2':6',2"-terpyridine-98%
  • 128143-89-5
  • C15H10ClN3
  • Building Blocks
  • Pyridines
  • Heterocyclic Building Blocks
  • Halogenated Heterocycles
  • C9 to C46Heterocyclic Building Blocks
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Pyridines
  • Building Blocks
  • C13 to C40
  • C7 to C18
  • Chemical Synthesis
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks