TETRAHYDROTHIOPYRAN-4-OL 97

Product Name: TETRAHYDROTHIOPYRAN-4-OL 97
CAS No.: 29683-23-6
Chemical Name: TETRAHYDROTHIOPYRAN-4-OL 97
Synonyms: thian-4-ol;4-Hydroxythiane;Thiacyclohexane-4-ol;Tetrahydrothiophene-4-ol;Tetrahydro-2H-thiopyran-4-O;Thiopyran-4-ol, tetrahydro-;4-Hydroxytetrahydrothiopyran;TETRAHYDROTHIOPYRAN-4-OL 97;2H-thiopyran-4-ol, tetrahydro-;4-hydroxy-tetrahydro-2H-thiopyran
CBNumber: CB6499679
Molecular Formula: C5H10OS
Formula Weight: 118.2
MOL File: 29683-23-6.mol

More

Less

TETRAHYDROTHIOPYRAN-4-OL 97 Property

Melting point:: 47-51 °C (lit.)
Boiling point:: 70°C/0.05mmHg(lit.)
Density: 1.148±0.06 g/cm3(Predicted)
Flash point:: >230 °F
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: powder to lump
pka: 14.56±0.20(Predicted)
color: White to Almost white

More

Less

Safety

RIDADR: UN 3335
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 2934999090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 540714
Product name: Tetrahydrothiopyran-4-ol
Purity: 97%
Packaging: 1g
Price: $226
Updated: 2023/06/20

TCI Chemical

Product number: T3373
Product name: Tetrahydro-2H-thiopyran-4-ol
Purity: >98.0%(GC)
Packaging: 1g
Price: $87
Updated: 2025/07/31

TCI Chemical

Product number: T3373
Product name: Tetrahydro-2H-thiopyran-4-ol
Purity: >98.0%(GC)
Packaging: 5g
Price: $432
Updated: 2025/07/31

TRC

Product number: P991973
Product name: Tetrahydro-2H-thiopyran-4-O
Packaging: 50mg
Price: $45
Updated: 2021/12/16

TRC

Product number: P991973
Product name: Tetrahydro-2H-thiopyran-4-O
Packaging: 100mg
Price: $60
Updated: 2021/12/16

More

Less

TETRAHYDROTHIOPYRAN-4-OL 97 Chemical Properties,Usage,Production

General Description

Tetrahydrothiopyran-4-ol is a sulfur containing heterocyclic building block. Tetrahydrothiopyran-4-ol can be synthesized from tetrahydrothiopyran-4-one. It participates in the synthesis of 4-hydroxyl-1-methyltetrahydrothiopyranium iodide.

Synthesis

1072-72-6

29683-23-6

GENERAL METHOD: Tetrahydrothiopyran-4-one (40.10 g, 0.271 mol) was dissolved in methanol (700 mL), and sodium borohydride (15.36 g, 0.406 mol) was added in batches under ice-bath cooling, and the reaction was stirred for 1 hr. (NOTE: the reaction is exothermic and violent). Subsequently, the reaction mixture was continued to be stirred at 20°C for 2 hours. After completion of the reaction, the solvent was removed by concentration under reduced pressure to give a solid residue. To the residue was added a mixture of saturated aqueous sodium bicarbonate (150 mL) and ethyl acetate (250 mL) (Note: the product is soluble in water). After vigorous shaking, the organic layer was separated and the aqueous layer was further extracted with ethyl acetate (4 x 250 mL). All organic layers were combined, dried over anhydrous sodium sulfate and concentrated to dryness under reduced pressure to give the target product tetrahydro-2H-thiopyran-4-ol.

References

[1] Synthetic Communications, 2018, vol. 48, # 17, p. 2198 - 2205
[2] Chemistry - A European Journal, 2018, vol. 24, # 62, p. 16526 - 16531
[3] Bulletin of the Chemical Society of Japan, 1995, vol. 68, # 9, p. 2739 - 2750
[4] Chemical Communications (Cambridge, United Kingdom), 2002, # 10, p. 1070 - 1071
[5] Patent: EP3342765, 2018, A1. Location in patent: Paragraph 0337

TETRAHYDROTHIOPYRAN-4-OL 97 Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

TETRAHYDROTHIOPYRAN-4-OL 97 Suppliers

China 87 India 3 Japan 1 Switzerland 1 United States 8 Global 100

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

Shandong Xiya Chemical Co., Ltd

Tel: 4009903999 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18729
Advantage: 57

Thermo Fisher Scientific

Tel: 800-810-5118
Fax: +86-10-84193589
Email: cnchemical@thermofisher.com
Country: China
ProdList: 17770
Advantage: 75

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22514
Advantage: 55

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-6206333 13167063860
Fax: 021-50323701
Email: anhua.mao@aladdin-e.com
Country: China
ProdList: 25003
Advantage: 65

Shanghai JONLN Reagent Co., Ltd.

Tel: 400-0066400 13621662912
Fax: 021-55660885
Email: 422131432@qq.com
Country: China
ProdList: 9979
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

More

Less

View Lastest Price from TETRAHYDROTHIOPYRAN-4-OL 97 manufacturers

Career Henan Chemical Co

Product: TETRAHYDROTHIOPYRAN-4-OL 97 29683-23-6
Price: US $6.60/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 1kg -1000kg
Release date: 2020-01-02

29683-23-6, TETRAHYDROTHIOPYRAN-4-OL 97Related Search:

Tetrahydrothiopyran-4-one Tetrahydrothiophen-3-one Oxan-4-yl 4-methylbenzenesulfonate Tetrahydro-2H-pyran-4-carbonyl chloride Tetrahydro-4-pyranol Hexahydro-3H-pyrrolo[1,2-c]imidazole-1,3-dione TETRAHYDRO-2H-PYRAN-3-CARBOXYLIC ACID 1,1-Dioxo-hexahydro-1l6-thiopyran-4-carboxylic acid tetrahydro-2H-thiopyran-4-ol 1,1-dioxide(SALTDATA: FREE) (TETRAHYDRO-THIOPYRAN-4-YL)-ACETALDEHYDE THIAZOLIDINE Tetrahydro-2H-thiopyran-4-amine 2H-Thiopyran-4-methanol, tetrahydro- 4-Amidinotetrahydro-2H-pyran hydrochloride TETRAHYDROFURAN-3-BORONIC ACID Methyl tetrahydro-3-furoate 2-Furamide,tetrahydro-(6CI,7CI) Tetrahydro-2-furancarboxaldehyde

TETRAHYDROTHIOPYRAN-4-OL 97

2H-thiopyran-4-ol, tetrahydro-

Thiacyclohexane-4-ol

thian-4-ol

4-hydroxy-tetrahydro-2H-thiopyran

Tetrahydro-2<i>H</i>-thiopyran-4-ol

Thiopyran-4-ol, tetrahydro-

4-Hydroxytetrahydrothiopyran

4-Hydroxythiane

Tetrahydro-2H-thiopyran-4-O

Tetrahydrothiophene-4-ol

29683-23-6

Heterocyclic Compounds