2,4,6-Trimethybromombenzene
- Product Name
- 2,4,6-Trimethybromombenzene
- CAS No.
- 576-83-0
- Chemical Name
- 2,4,6-Trimethybromombenzene
- Synonyms
- 2-BROMOMESITYLENE;2-BROMO-1,3,5-TRIMETHYLBENZENE;MESITYL BROMIDE;BROMOMESITYLENE;1-bromo-2,4,6-trimethylbenzene;1-Bromomesitylene;2,4,6-Trimethylphenyl bromide;2-BROMOM;2-Bromomesifylene;TIMTEC-BB SBB007975
- CBNumber
- CB6711661
- Molecular Formula
- C9H11Br
- Formula Weight
- 199.09
- MOL File
- 576-83-0.mol
2,4,6-Trimethybromombenzene Property
- Melting point:
- 2 °C(lit.)
- Boiling point:
- 225 °C(lit.)
- Density
- 1.301 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.552(lit.)
- Flash point:
- 205 °F
- storage temp.
- Sealed in dry,Room Temperature
- form
- Liquid
- color
- Clear colorless to very slightly yellow
- Water Solubility
- Insoluble in water(20°C) .
- Sensitive
- Light Sensitive
- BRN
- 1907245
- InChI
- InChI=1S/C9H11Br/c1-6-4-7(2)9(10)8(3)5-6/h4-5H,1-3H3
- InChIKey
- RRTLQRYOJOSPEA-UHFFFAOYSA-N
- SMILES
- C1(C)=CC(C)=CC(C)=C1Br
- CAS DataBase Reference
- 576-83-0(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzene, 2-bromo-1,3,5-trimethyl-(576-83-0)
- EPA Substance Registry System
- 2-Bromomesitylene (576-83-0)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-36/37/39-23
- WGK Germany
- 3
- TSCA
- Yes
- HS Code
- 29036990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- B71608
- Product name
- 2-Bromomesitylene
- Purity
- 98%
- Packaging
- 25g
- Price
- $45
- Updated
- 2025/07/31
- Product number
- B71608
- Product name
- 2-Bromomesitylene
- Purity
- 98%
- Packaging
- 100g
- Price
- $79.2
- Updated
- 2025/07/31
- Product number
- B1261
- Product name
- Mesityl Bromide
- Packaging
- 25G
- Price
- $37
- Updated
- 2025/07/31
- Product number
- B1261
- Product name
- Mesityl Bromide
- Packaging
- 100G
- Price
- $97
- Updated
- 2025/07/31
- Product number
- B1261
- Product name
- Mesityl Bromide
- Packaging
- 500G
- Price
- $323
- Updated
- 2025/07/31
2,4,6-Trimethybromombenzene Chemical Properties,Usage,Production
Chemical Properties
colorless liquid
Uses
2-Bromomesitylene is a useful synthetic intermediate, Aromatics, Boron Derivatives, Catalyst. It is an intermediate used to prepare Hydrogen[4-[bis(2,4,6-trimethylphenyl)phosphino]-2,3,5,6-tetrafluorophenyl]hydrobis(2,3,4,5,6-pentafluorophenyl)borate (H714510) which is a frustrated phosphonium borate for metal-free catalytic hydrogenation of imines.
Synthesis
108-67-8
576-83-0
The general procedure for the synthesis of 2-bromo-1,3,5-trimethylbenzene from 1,3,5-trimethylbenzene was as follows: N-bromosuccinimide (NBS, 1.0 mmol) and Catalyst 1 (0.1 or 1 mol% Au based on the substrate) were accurately weighed and added to 10 mL of a sealed reaction vessel, followed by 1,2-dichloroethane (DCE, 2 mL) and 1,3,5- trimethylbenzene (1.0 mmol). The reaction mixture was stirred at a set temperature for a specified time. Upon completion of the reaction, the catalyst was removed by separation using a magnet, followed by concentration of the reaction solution under reduced pressure and final purification by column chromatography to afford the target product 2-bromo-1,3,5-trimethylbenzene.
References
[1] Journal of Organic Chemistry, 1993, vol. 58, # 11, p. 3072 - 3075
[2] Tetrahedron, 2009, vol. 65, # 22, p. 4429 - 4439
[3] Angewandte Chemie - International Edition, 2010, vol. 49, # 11, p. 2028 - 2032
[4] Tetrahedron Letters, 2013, vol. 54, # 9, p. 1063 - 1066
[5] Synthesis, 2002, # 2, p. 169 - 171
2,4,6-Trimethybromombenzene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2,4,6-Trimethybromombenzene manufacturers
- Product
- 2,4,6-Trimethybromombenzene 576-83-0
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-25
- Product
- 2- bromo-1,3,5- trimethylbenzene 576-83-0
- Price
- US $1.00/BOU/Drum
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1kg
- Release date
- 2020-11-23
- Product
- 2,4,6-Trimethybromombenzene 576-80-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2020-01-10