ChemicalBook > CAS DataBase List > 2,4,6-Trimethybromombenzene

2,4,6-Trimethybromombenzene

Product Name
2,4,6-Trimethybromombenzene
CAS No.
576-83-0
Chemical Name
2,4,6-Trimethybromombenzene
Synonyms
2-BROMO-1,3,5-TRIMETHYLBENZENE;2-BROMOMESITYLENE;MESITYL BROMIDE;BROMOMESITYLENE;1-bromo-2,4,6-trimethylbenzene;1-Bromomesitylene;2,4,6-Trimethylphenyl bromide;2-BROMOM;2-Bromomesifylene;TIMTEC-BB SBB007975
CBNumber
CB6711661
Molecular Formula
C9H11Br
Formula Weight
199.09
MOL File
576-83-0.mol
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2,4,6-Trimethybromombenzene Property

Melting point:
2 °C(lit.)
Boiling point:
225 °C(lit.)
Density 
1.301 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.552(lit.)
Flash point:
205 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
color 
Clear colorless to very slightly yellow
Water Solubility 
Insoluble in water(20°C) .
Sensitive 
Light Sensitive
BRN 
1907245
InChI
InChI=1S/C9H11Br/c1-6-4-7(2)9(10)8(3)5-6/h4-5H,1-3H3
InChIKey
RRTLQRYOJOSPEA-UHFFFAOYSA-N
SMILES
C1(C)=CC(C)=CC(C)=C1Br
CAS DataBase Reference
576-83-0(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 2-bromo-1,3,5-trimethyl-(576-83-0)
EPA Substance Registry System
2-Bromomesitylene (576-83-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-36/37/39-23
WGK Germany 
3
TSCA 
TSCA listed
HS Code 
29036990
Storage Class
10 - Combustible liquids
Hazard Classifications
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B71608
Product name
2-Bromomesitylene
Purity
98%
Packaging
25g
Price
$48
Updated
2026/03/19
Sigma-Aldrich
Product number
B71608
Product name
2-Bromomesitylene
Purity
98%
Packaging
100g
Price
$84.4
Updated
2026/03/19
TCI Chemical
Product number
B1261
Product name
Mesityl Bromide
Packaging
25G
Price
$41
Updated
2026/03/19
TCI Chemical
Product number
B1261
Product name
Mesityl Bromide
Packaging
100G
Price
$108
Updated
2026/03/19
TCI Chemical
Product number
B1261
Product name
Mesityl Bromide
Packaging
500G
Price
$359
Updated
2026/03/19
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2,4,6-Trimethybromombenzene Chemical Properties,Usage,Production

Chemical Properties

colorless liquid

Uses

2-Bromomesitylene is a useful synthetic intermediate, Aromatics, Boron Derivatives, Catalyst. It is an intermediate used to prepare Hydrogen[4-[bis(2,4,6-trimethylphenyl)phosphino]-2,3,5,6-tetrafluorophenyl]hydrobis(2,3,4,5,6-pentafluorophenyl)borate (H714510) which is a frustrated phosphonium borate for metal-free catalytic hydrogenation of imines.

Synthesis

108-67-8

576-83-0

The general procedure for the synthesis of 2-bromo-1,3,5-trimethylbenzene from 1,3,5-trimethylbenzene was as follows: N-bromosuccinimide (NBS, 1.0 mmol) and Catalyst 1 (0.1 or 1 mol% Au based on the substrate) were accurately weighed and added to 10 mL of a sealed reaction vessel, followed by 1,2-dichloroethane (DCE, 2 mL) and 1,3,5- trimethylbenzene (1.0 mmol). The reaction mixture was stirred at a set temperature for a specified time. Upon completion of the reaction, the catalyst was removed by separation using a magnet, followed by concentration of the reaction solution under reduced pressure and final purification by column chromatography to afford the target product 2-bromo-1,3,5-trimethylbenzene.

References

[1] Journal of Organic Chemistry, 1993, vol. 58, # 11, p. 3072 - 3075
[2] Tetrahedron, 2009, vol. 65, # 22, p. 4429 - 4439
[3] Angewandte Chemie - International Edition, 2010, vol. 49, # 11, p. 2028 - 2032
[4] Tetrahedron Letters, 2013, vol. 54, # 9, p. 1063 - 1066
[5] Synthesis, 2002, # 2, p. 169 - 171

2,4,6-Trimethybromombenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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2,4,6-Trimethybromombenzene Suppliers

Changzhou Jiuwu Chemical co., Ltd.
Tel
13775162768
Email
16356194@qq.com
Country
China
ProdList
28
Advantage
58
CHANGZHOU MALONG CHEMICALS CO., LTD.
Tel
18651958646
Email
info@malongchem.com
Country
China
ProdList
184
Advantage
58
Hangzhou Copiore Chemical Co., Ltd.
Tel
17300981287 13757145729
Fax
0571-56501939
Email
sales@copiore.com
Country
China
ProdList
300
Advantage
58
Creasyn Finechem(Tianjin) Co., Ltd.
Tel
022-83946278 13820503911
Fax
022-83945176
Email
sales@creasyn.com
Country
China
ProdList
994
Advantage
68
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44802
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
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View Lastest Price from 2,4,6-Trimethybromombenzene manufacturers

Henan Fengda Chemical Co., Ltd
Product
2,4,6-Trimethybromombenzene 576-83-0
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
HONG KONG IPURE BIOLOGY CO.,LIMITED
Product
2- bromo-1,3,5- trimethylbenzene 576-83-0
Price
US $1.00/BOU/Drum
Min. Order
1KG
Purity
98%
Supply Ability
1kg
Release date
2020-11-23
Career Henan Chemical Co
Product
2,4,6-Trimethybromombenzene 576-80-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-10

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