ChemicalBook > CAS DataBase List > Thiophosgene

Thiophosgene

Product Name
Thiophosgene
CAS No.
463-71-8
Chemical Name
Thiophosgene
Synonyms
CSCl2;Thiocarbonyl dichloride;Carbonothioyl dichloride;Thiophosg;Thiofosgen;THIOPHOSGENE;thio-phosgen;Phosgene, thio-;Thiophosgene,97%;thiofosgen(czech)
CBNumber
CB7117651
Molecular Formula
CCl2S
Formula Weight
114.98
MOL File
463-71-8.mol
More
Less

Thiophosgene Property

Melting point:
<25 °C
Boiling point:
73 °C
Density 
1.508
vapor density 
4 (vs air)
refractive index 
n20/D 1.548(lit.)
Flash point:
62 °C
storage temp. 
2-8°C
solubility 
Chloroform
form 
Liquid
color 
A reddish liquid
Water Solubility 
slow decomposition in cold, fast in hot water
BRN 
1633495
Stability:
Stable. but reacts violently with water to produce toxic fumes. Incompatible with water, alcohols. Refrigerate at 2-8 C.
CAS DataBase Reference
463-71-8(CAS DataBase Reference)
NIST Chemistry Reference
Carbonothioic dichloride(463-71-8)
EPA Substance Registry System
Thiophosgene (463-71-8)
More
Less

Safety

Hazard Codes 
T
Risk Statements 
22-23-36/37/38
Safety Statements 
7-9-36/37-45-7/9
RIDADR 
UN 2474 6.1/PG 2
WGK Germany 
1
RTECS 
XN2450000
19-21
HazardClass 
6.1(a)
PackingGroup 
II
HS Code 
28530090
Hazardous Substances Data
463-71-8(Hazardous Substances Data)
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H331Toxic if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
115150
Product name
Thiophosgene
Packaging
5g
Price
$36.9
Updated
2024/03/01
Sigma-Aldrich
Product number
115150
Product name
Thiophosgene
Packaging
25g
Price
$103
Updated
2024/03/01
Sigma-Aldrich
Product number
115150
Product name
Thiophosgene
Packaging
100g
Price
$119.2
Updated
2024/03/01
TRC
Product number
T368200
Product name
Thiophosgene
Packaging
50g
Price
$195
Updated
2021/12/16
Oakwood
Product number
005987
Product name
Thiophosgene
Packaging
10g
Price
$32
Updated
2021/12/16
More
Less

Thiophosgene Chemical Properties,Usage,Production

Chemical Properties

Reddish liquid. Decomposes in water and alcohol; soluble in ether.

Chemical Properties

A clear dark red to reddish-yellow liquid. Sharp, choking odor.

Uses

Thiophosgene is a photo degradation product of the agricultural fungicide Folpet (F402000).

Definition

ChEBI: Thiophosgene is a thiocarbonyl compound and a one-carbon compound.

General Description

A reddish liquid. Boiling point 73.5°C. A severe eye irritant. May severely burn skin on contact. Very toxic by inhalation and by skin absorption.

Air & Water Reactions

Reacts with water to evolve hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot.

Reactivity Profile

Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids.

Hazard

Toxic by ingestion and inhalation.

Health Hazard

Inhalation causes irritation of respiratory system and delayed pulmonary edema. Vapor irritates eyes. Liquid burns skin and eyes. Ingestion causes irritation of mouth and stomach.

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. A skin, mucous membrane, and severe eye irritant. When heated to decomposition it emits very toxic fumes of Cland SOx. See also PHOSGENE.

Potential Exposure

Primary irritant (w/o allergic reaction). There is not large-scale production of the chemical in the United States It is used to make other chemicals and in laboratory synthesis.

Shipping

UN2474 Thiophosgene, Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard; Inhalation Hazard Zone B. PG 2. STN: 49 232 98.

Incompatibilities

Vapors may form explosive mixture with air. Incompatible with water and alcohols. Reacts with water releasing toxic hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot. Decomposes above 200℃ to highly flammable carbon bisulfide and carbon tetrachloride. Corrodes metals, rubber and some plastics in the presence of moisture. Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

More
Less

Thiophosgene Suppliers

Shanghai Yudiao Chemistry Technology Co.,Ltd
Tel
21-37285211 18964703211
Fax
021-37285211
Email
info@yudiaochem.com
Country
China
ProdList
264
Advantage
58
Yangzhou juhechang Technology Co., Ltd
Tel
0514-0514-83662002 13073488988
Fax
0514-83662002
Email
13073488988@163.com
Country
China
ProdList
37
Advantage
58
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9555
Advantage
66
NingBo Sialon Chem Co., Ltd.
Tel
0574-28809768 18658497215
Fax
+86-574-56708448 / 28809708
Email
sales@newsialon.com
Country
China
ProdList
40
Advantage
58
Shanghai Song Yuan Chemical Technology Co., Ltd.
Tel
010-1234567 18521000990
Fax
86-021-33275113
Email
sonyuanchemical@163.com
Country
China
ProdList
6490
Advantage
50
Zhengzhou KeYulong chemical products Co., Ltd
Tel
17319789407
Fax
0371-53335504
Email
Keyulongchem@163.com
Country
China
ProdList
1993
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Beijing Donghualituo Techonlogy Development Co.,Ltd.
Tel
010-88425576
Fax
(+86)-10-88425546
Email
sales@dhltchem.com
Country
China
ProdList
793
Advantage
59
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
More
Less

View Lastest Price from Thiophosgene manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Thiophosgene 463-71-8
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2020-05-19
Honest Joy Holdings Limited
Product
Thiophosgene 463-71-8
Price
US $0.00/KG
Min. Order
1KG
Purity
98.2%
Supply Ability
100 tons
Release date
2022-02-18
Career Henan Chemical Co
Product
Thiophosgene 463-71-8
Price
US $1.00-2.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200kg
Release date
2019-08-30

463-71-8, ThiophosgeneRelated Search:


  • Carbon chlorosulfide
  • carbonchlorosulfide
  • Carbonic dichloride, thio-
  • carbonothioicdichloride
  • Carbonyl chloride, thio-
  • CSCl2
  • Dichlorothiocarbonyl
  • Phosgene, thio-
  • Thiocarbonic dichloride
  • THIOPHOSGENE
  • THIOCARBONYL CHLORIDE
  • Thiophosgene, AcroSeal, 97%
  • Carbon Dichloride Sulfide
  • Carbonyl Sulfide Dichloride
  • DichlorothioforMaldehyde
  • Thiophosgene, 95%, AcroSeal
  • Carbonothioyl dichloride
  • Chlorothioformic acid chloride
  • Dichloromethanethione
  • Thiophosgene,97%
  • Thiophosgene, 95%, J&KSeal
  • Thiophosg
  • thio-carbonicdichlorid
  • thiocarbonicdichloride
  • Thiocarbonyl dichloride
  • thio-carbonylchlorid
  • thiocarbonyldichloride
  • Thiofosgen
  • thiofosgen(czech)
  • Thiokarbonylchlorid
  • thiokarbonylchlorid(czech)
  • thio-phosgen
  • Thiophosgene (Thiocarbonyl chloride)
  • 463-71-8 Thiophosgene
  • Thiophosgene, 85%, AcroSeal&trade
  • 463-71-8
  • CCl2S
  • Coupling
  • Phosgene Derivatives
  • Synthetic Reagents
  • Organics