Cinnamoyl chloride
- Product Name
- Cinnamoyl chloride
- CAS No.
- 102-92-1
- Chemical Name
- Cinnamoyl chloride
- Synonyms
- Cinnamoyl;Cinnamic chloride;CINNAMIC ACID CHLORIDE;TRANS-CINNAMOYL CHLORIDE;3-PHENYL-2-PROPENOYL CHLORIDE;(E)-3-phenylprop-2-enoyl chloride;(2E)-3-phenylprop-2-enoyl chloride;Ciamoyl chloride;Cinmoyl chloride;AKOS BBS-00003908
- CBNumber
- CB7181872
- Molecular Formula
- C9H7ClO
- Formula Weight
- 166.6
- MOL File
- 102-92-1.mol
Cinnamoyl chloride Property
- Melting point:
- 35-37 °C (lit.)
- Boiling point:
- 256-258 °C (lit.)
- Density
- d445.3 1.1617
- refractive index
- nD42.5 1.614
- Flash point:
- >230 °F
- storage temp.
- 2-8°C
- solubility
- dioxane: 0.1 g/mL, clear
- form
- Crystalline Solid
- color
- White to yellow
- Water Solubility
- DECOMPOSES
- Merck
- 13,2323
- BRN
- 606265
- CAS DataBase Reference
- 102-92-1(CAS DataBase Reference)
- NIST Chemistry Reference
- 2-Propenoyl chloride, 3-phenyl-(102-92-1)
- EPA Substance Registry System
- 2-Propenoyl chloride, 3-phenyl- (102-92-1)
Safety
- Hazard Codes
- C
- Risk Statements
- 34-29-20-14
- Safety Statements
- 26-36/37/39-45-25-30-23-8
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- F
- 10-21
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29163990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
N-Bromosuccinimide Price
- Product number
- C81101
- Product name
- Cinnamoyl chloride
- Purity
- 98%
- Packaging
- 5g
- Price
- $34.8
- Updated
- 2024/03/01
- Product number
- C81101
- Product name
- Cinnamoyl chloride
- Purity
- 98%
- Packaging
- 100g
- Price
- $63.5
- Updated
- 2024/03/01
- Product number
- C81101
- Product name
- Cinnamoyl chloride
- Purity
- 98%
- Packaging
- 500g
- Price
- $163
- Updated
- 2024/03/01
- Product number
- C596290
- Product name
- trans-Cinnamoyl chloride
- Packaging
- 50g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 236892
- Product name
- Cinnamoyl-
- Packaging
- 250mg
- Price
- $273
- Updated
- 2021/12/16
Cinnamoyl chloride Chemical Properties,Usage,Production
Chemical Properties
white to yellowish crystalline solid
Uses
Titrimetric determination of small amounts of water.
Synthesis Reference(s)
Organic Syntheses, Coll. Vol. 3, p. 714, 1955
Tetrahedron Letters, 14, p. 5121, 1973 DOI: 10.1016/S0040-4039(01)87403-7
Hazard
Skin irritant.
Synthesis
140-10-3
102-92-1
General procedure for the synthesis of 3-phenyl-2-propenyl chloride from trans-cinnamic acid: trans-cinnamic acid (1.0 mmol) was mixed with excess thionyl chloride (5 mL) and reacted at reflux for 2 hours. After completion of the reaction, the excess thionyl chloride was removed by vacuum concentration to obtain 3-phenyl-2-propenyl chloride in quantitative yield.
Purification Methods
Refractionate it in a vacuum until the distillate solidifies on cooling, and recrystallise it from pet ether. The trans-amide has m 145-150o (from H2O) [Beilstein 9 III 2711]. [Adams & Ulich J Am Chem Soc 42 605 1920, Bergmann et al. J Chem Soc 2524 1952, Beilstein 9 H 587, 9 I 233, 9 II 390, 9 III 2710, 9 IV 2020.]
References
[1] Tetrahedron, 2009, vol. 65, # 42, p. 8690 - 8696
[2] Chinese Chemical Letters, 2013, vol. 24, # 8, p. 673 - 676
[3] Molecules, 2016, vol. 21, # 1,
[4] Journal of the American Chemical Society, 2017, vol. 139, # 23, p. 7745 - 7748
[5] Patent: WO2007/141389, 2007, A1. Location in patent: Page/Page column 62
Cinnamoyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Cinnamoyl chloride manufacturers
- Product
- Cinnamoyl chloride 102-92-1
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 ton
- Release date
- 2024-12-23
- Product
- Cinnamoyl chloride 102-92-1
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2025-03-14
- Product
- Cinnamoyl chloride 102-92-1
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99.%
- Supply Ability
- 10 ton
- Release date
- 2024-08-23