ChemicalBook > CAS DataBase List > BOC-SER(ME)-OH

BOC-SER(ME)-OH

Product Name
BOC-SER(ME)-OH
CAS No.
51293-47-1
Chemical Name
BOC-SER(ME)-OH
Synonyms
BOC-O-METHYL-L-SERINE;BOC-SER(ME)-OH;BOC-L-Ser（Me）-OH;Boc-O-Methyl-L-Se;BOC-O-METHYL-L-SER;BOC-SER(ME)-OH DCHA;BOC-SERINE(ME)-OH DCHA;N-Boc-O-methyl-L-serine;BOC-L-SERINE(METHYL ETHER);BOC-O-METHYL-L-SERINE DCHA
CBNumber
CB7218147
Molecular Formula
C9H17NO5
Formula Weight
219.24
MOL File
51293-47-1.mol
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BOC-SER(ME)-OH Property

Boiling point:
355.8±37.0 °C(Predicted)
Density 
1.148±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,2-8°C
form 
solid
pka
3.52±0.10(Predicted)
color 
Yellow-brown
InChI
InChI=1S/C9H17NO5/c1-9(2,3)15-8(13)10-6(5-14-4)7(11)12/h6H,5H2,1-4H3,(H,10,13)(H,11,12)/t6-/m0/s1
InChIKey
RFGMSGRWQUMJIR-LURJTMIESA-N
SMILES
C(O)(=O)[C@H](COC)NC(OC(C)(C)C)=O
CAS DataBase Reference
51293-47-1(CAS DataBase Reference)
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Safety

HazardClass 
IRRITANT
HS Code 
2924297099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
B673128
Product name
Boc-Ser(Me)-OH
Packaging
250mg
Price
$50
Updated
2021/12/16
Activate Scientific
Product number
AS29499
Product name
N-Boc-O-methyl-L-serine
Purity
95+% ee
Packaging
1g
Price
$52
Updated
2021/12/16
Chem-Impex
Product number
05599
Product name
Boc-O-methyl-L-serinedicyclohexylammoniumsalt,≥98.5%(HPLC)
Purity
≥98.5%(HPLC)
Packaging
1G
Price
$58.24
Updated
2021/12/16
SynQuest Laboratories
Product number
4158-1-S7
Product name
(2S)-2-Amino-3-methoxypropanoic acid, N-Boc protected
Packaging
1g
Price
$63
Updated
2021/12/16
Apolloscientific
Product number
OR307095
Product name
(2S)-2-Amino-3-methoxypropanoicacid,N-BOCprotected
Packaging
1g
Price
$29
Updated
2021/12/16
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BOC-SER(ME)-OH Chemical Properties,Usage,Production

Chemical Properties

White to off-white crystals

Uses

BOC-SER(ME)-OH, also known as Boc-Ser-OMe or N-tert-butyloxycarbonyl-L-serine methyl ester, is an amino acid derivative commonly used in peptide synthesis.

Synthesis

4219-94-7

24424-99-5

51293-47-1

General procedure for the synthesis of N-Boc-O-methyl-L-serine from O-methyl DL-serine and di-tert-butyl dicarbonate: 35 mL of aqueous 1 N sodium hydroxide solution and 35 mL of tetrahydrofuran (THF) were added to 2.0 g (17 mmol) of O-methyl DL-serine. With stirring at 0 °C, a solution of di-tert-butyl dicarbonate (4.03 g, 18.5 mmol) in THF (15 mL) was added slowly. The reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, the reaction mixture was concentrated by evaporation under reduced pressure. The aqueous phase was acidified to pH 4-5 with 10% aqueous citric acid and then extracted with ethyl acetate. The organic phase was washed with saturated brine, dried over anhydrous magnesium sulfate, and the solvent was evaporated under reduced pressure to give 3.6 g of N-Boc-O-methyl-L-serine (98% yield). Mass spectrum (ESI) m/z: 220.1 (M + H)+.

References

[1] Chemistry - A European Journal, 2011, vol. 17, # 15, p. 4183 - 4194
[2] Patent: WO2016/11088, 2016, A2. Location in patent: Paragraph 00238; 00239

BOC-SER(ME)-OH Preparation Products And Raw materials

Raw materials

Preparation Products

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BOC-SER(ME)-OH Suppliers

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View Lastest Price from BOC-SER(ME)-OH manufacturers

Sichuan Jiaying Lai Technology Co.,LTD
Product
Boc-ser(me)-OH 51293-47-1
Price
US $1.00/g
Min. Order
1g
Purity
98%
Supply Ability
100KG
Release date
2019-07-22
Career Henan Chemical Co
Product
BOC-SER(ME)-OH 51293-47-1
Price
US $100.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2018-07-30

51293-47-1, BOC-SER(ME)-OHRelated Search:

Boc-Ser(tBu)-OH (dicyclohexylammonium) salt,Boc-Ser(tBu)-OH Dicyclohexylamine Salt,Boc-Ser(Tbu)-Ohcha,Boc-Ser(tBu)-OH&#8226,BOC-SER(TBU)-OH DCHA BOC-SER(ME)-OH Boc-O-tert-butyl-L-threonine Boc-Ser(tBu)-OH 3-FLUORO-5-(TRIFLUOROMETHYL)PHENOL Boc-Thr(Bzl)-OH (S)-(-)-3-TERT-BUTOXYCARBONYL-4-METHOXYCARBONYL-2,2-DIMETHYL-1,3-OXAZOLIDINE BOC-THR(ME)-OH BOC-Ser (Obzl) OH,BOC-SER(BUT)-OH,BOC-SER(BU)-OH,BOC-SER(TBU)-OH BOC-SER(BU)-OH,BOC-SER(BUT)-OH,BOC-SER(TBU)-OH Boc-D-Ser(Bzl)-OH BOC-L-Serine L-Serine BOC-SER(BZL)-OH DCHA BOC-L-THR(ALLOC)-OH DCHA BOC-SER(BZL)-OSU BOC-O-BENZYL-L-THREONINE N-CARBOXY ANHYDRIDE Boc-Ser(Aloc)-OH·DCHA

  • BOC-L-Ser（Me）-OH
  • (2S)-2-(tert-Butoxycarbonylamino)-3-methoxy-propanoic acid
  • (S)-N-BOC-2-AMINO-3-METHOXY-PROPIONIC ACID
  • N-ALPHA-T-BUTOXYCARBONYL-O-METHYL-L-SERINE
  • N-ALPHA-T-BUTOXYCARBONYL-O-METHYL-L-SERINE DICYCLOHEXYLAMMONIUM SALT
  • N-ALPHA-T-BOC-O-METHYL-L-SERINE
  • BOC-(S)-2-AMINO-3-METHOXYLPROPANOIC ACID
  • BOC-(S)-2-AMINO-3-METHOXYPROPIONIC ACID
  • BOC-SER(ME)-OH
  • BOC-SER(ME)-OH DCHA
  • BOC-SERINE(ME)-OH DCHA
  • Boc-O-methyl-L-serine dicyclohexylammonium salt≥ 98.5% (HPLC)
  • BOC-L-SERINE(METHYL ETHER)
  • BOC-O-METHYL-L-SER
  • BOC-O-METHYL-L-SERINE
  • BOC-O-METHYL-L-SERINE DCHA
  • BOC-O-METHYL-L-SERINE DICYCLOHEXYLAMMONIUM SALT
  • Boc-O-methyl-L-Serinedicyclohexylamine salt
  • Boc-O-Methyl-L-Se
  • N-tert-Butoxycarbonyl-O-methyl-L-serine
  • (S)-2-(tert-butoxycarbonylamino)-3-methoxypropanoicacid
  • L-Serine, N-[(1,1-diMethylethoxy)carbonyl]-O-Methyl-
  • Boc-Ser(Me)-OH·DCHA Boc-O-Methyl-L-SerinedicyclohexylaMine salt
  • N-Boc-O-Methyl-L-serine, 97%
  • (2S)-2-Amino-3-methoxypropanoic acid, N-BOC protected
  • N-Boc-O-methyl-L-serine,97%
  • (S)-N-Boc-2-Amino-3-Methoxy-PropionicAci
  • N-α-(t-Butoxycarbonyl)-O-methyl-L-serine
  • N-tert-butoxycarbonyl-(S)-O-methyl-serin
  • N-[(1,1-Dimethylethoxy)carbonyl]-O-methyl-L-serine
  • (2S)-3-methoxy-2-[(2-methylpropan-2-yl)oxycarbonylamino]propanoic acid
  • N-Boc-O-methyl-L-serine
  • 51293-47-1
  • C9H17NO5C12H23N
  • unnatural amino acids
  • Boc-Amino acid series
  • Serine [Ser, S]
  • Boc-Amino Acids and Derivative
  • API