ChemicalBook > CAS DataBase List > (-)-MENTHYL CHLOROFORMATE

(-)-MENTHYL CHLOROFORMATE

Product Name
(-)-MENTHYL CHLOROFORMATE
CAS No.
14602-86-9
Chemical Name
(-)-MENTHYL CHLOROFORMATE
Synonyms
MCF;(1R,2S,5R)-2-Isopropyl-5-Methylcyclohexyl carbonochloridate;Chloroformicacid;(1R)-Menthylester;L-MenthylChloroformate;(-)-MENTHYL CHLOROFORMATE;(S)-Menthyl chloroformate;(-)-Menthyl Chloroformate;(-)-MenthylChloroformate>L-p-menth-3-yl chloroformate
CBNumber
CB7248919
Molecular Formula
C11H19ClO2
Formula Weight
218.72
MOL File
14602-86-9.mol
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(-)-MENTHYL CHLOROFORMATE Property

Boiling point:
108-109 °C11 mm Hg(lit.)
Density 
1.031 g/mL at 20 °C(lit.)
vapor pressure 
0.01 psi ( 20 °C)
refractive index 
n20/D 1.459
Flash point:
158 °F
storage temp. 
2-8°C
solubility 
Chloroform (Sparingly), Methanol (Sparingly)
form 
clear liquid
color 
Colorless to Almost colorless
optical activity
[α]20/D 83°, c = 1 in chloroform
Sensitive 
Moisture Sensitive
BRN 
2414686
CAS DataBase Reference
14602-86-9(CAS DataBase Reference)
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Safety

Hazard Codes 
T,N
Risk Statements 
23-34-51/53
Safety Statements 
26-36/37/39-45-61
RIDADR 
UN 3277 6.1/PG 2
WGK Germany 
3
F 
10-19-21
HS Code 
2915.90.5010
HazardClass 
6.1
PackingGroup 
II
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H331Toxic if inhaled

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
245305
Product name
(1R)-(?)-Menthyl chloroformate
Purity
optical purity ee: 99% (GLC)
Packaging
25g
Price
$182
Updated
2023/06/20
Sigma-Aldrich
Product number
245305
Product name
(1R)-(?)-Menthyl chloroformate
Purity
optical purity ee: 99% (GLC)
Packaging
100g
Price
$456
Updated
2023/06/20
TCI Chemical
Product number
M0990
Product name
(-)-Menthyl Chloroformate
Purity
>97.0%(T)
Packaging
5mL
Price
$51
Updated
2024/03/01
TCI Chemical
Product number
M0990
Product name
(-)-Menthyl Chloroformate
Purity
>97.0%(T)
Packaging
25mL
Price
$169
Updated
2024/03/01
Alfa Aesar
Product number
L11739
Product name
(1R)-(-)-Menthyl chloroformate, 90+%
Packaging
5g
Price
$36.1
Updated
2021/12/16
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(-)-MENTHYL CHLOROFORMATE Chemical Properties,Usage,Production

Uses

Readily forms a chloroimidodicarbonate which asymmetrically chlorinates silyl enol ethers under mild conditions and in good yields.

(-)-MENTHYL CHLOROFORMATE Preparation Products And Raw materials

Raw materials

Preparation Products

Ethyl 5-[3-(4,6-dimethoxy pyrimidyl-2-yl)ureido]methylpyrazolyl-4-carboxylic ester cis-3-Hexenyl formate OCTYL FORMATE Alclometasone Dipropionate BENFURACARB Isobutyric acid biodegrddable finishing agent for fabric 1,2-Pentanediol TIADINIL FENOTHIOCARB azafenidin Mercaptoacetic acid Geranyl formate Benzyl formate 2-Naphthalenethiol Butyl formate
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(-)-MENTHYL CHLOROFORMATE Suppliers

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View Lastest Price from (-)-MENTHYL CHLOROFORMATE manufacturers

Hebei Duling International Trade Co. LTD
Product
(-)-MENTHYL CHLOROFORMATE 14602-86-9
Price
US $50.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100 tons
Release date
2023-04-23
Zhuozhou Wenxi import and Export Co., Ltd
Product
(1R)-(-)-Menthyl chloroformate optical purity ee: 99% (GLC) 14602-86-9
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

14602-86-9, (-)-MENTHYL CHLOROFORMATERelated Search:

2-Ethylhexyl chloroformate Diisopropyl chlorophosphate 4-Nitrophenyl chloroformate Chloromethyl ethyl ether L-Menthol 2-Methylcyclohexanol Ethyl chloroformate CHLOROMETHYL OCTYL ETHER Isopropyl chloroformate DL-Menthol CHLOROFORMIC ACID N-OCTYL ESTER CHLOROMETHYL ISO-PROPYL ETHER Heptyl chloroformate 3,7-DIMETHYL-1-OCTANOL Propyl chloroformate (+)-CHLOROMETHYL ISOMENTHYL ETHER Methyl chloroformate CHLOROMETHYL BUTYL ETHER

  • MCF
  • (-)-MENTHYL CHLOROFORMATE
  • (-)-CHLOROFORMYLOXY-P-MENTHANE
  • (-)-(1R)-Menthyl chloroformate (99% EE/GLC)
  • (1R)-(-)-MENTHYL CHLOROFORMATE 95+%
  • L-MenthylChloroformate
  • (1R,2S,5R)-(-)-MENTHYLCHLOROFORMATE
  • (-)-(1R)-MENTHYL CHLOROFORMATE
  • (1R)-(-)-MENTHYL CHLOROFORMATE
  • Chloroformic acid (1R)-menthyl ester~L-Menthyl chloroformate
  • L-p-menth-3-yl chloroformate
  • carbonochloridic acid (5-methyl-2-propan-2-ylcyclohexyl) ester
  • (1R)-Menthylester
  • Chloroformicacid
  • Carbonochloridic acid, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester
  • chloroformic acid (1r)-menthyl ester
  • (5-Methyl-2-propan-2-ylcyclohexyl) carbonochloridate
  • (1R,2S,5R)-2-Isopropyl-5-Methylcyclohexyl carbonochloridate
  • (1R)-(-)-Menthyl chloroforMate optical purity ee: 99% (GLC)
  • (-)-Menthyloxycarbonyl chloride
  • (S)-Menthyl chloroformate
  • Chloroformic acid (1R,3R,4S)-p-menthane-3-yl ester
  • Chloroformic acid [[1R,2S,5R,(-)]-2-isopropyl-5-methylcyclohexyl] ester
  • (-)-Chloroformic acid 2-(1-methylethyl)-5-methylcyclohexyl ester
  • Chloroformic acid (-)-menthyl ester
  • (-)-MenthylChloroformate&gt
  • (-)-Menthyl Chloroformate
  • (-)-(1R)-Menthyl Chloroformate
  • (-) (1R)-Menthyl chloroformate (R-MnCF)
  • 14602-86-9
  • 1492-24-8
  • Asymmetric Synthesis
  • Optical Resolution
  • for Resolution of Alcohols & Thiols
  • for Resolution of Bases
  • Monocyclic Monoterpenes
  • Terpenes
  • Chiral Resolution Reagents
  • Chiral Resolving Reagents
  • UV-VIS
  • CHLOROFORMATES
  • chiral
  • Biochemistry
  • for Resolution of Alcohols & Thiols
  • for Resolution of Bases
  • Monocyclic Monoterpenes
  • Optical Resolution
  • Synthetic Organic Chemistry
  • Terpenes