Description Referrence
ChemicalBook > CAS DataBase List > 5-Bromo-2-methylpyridine

5-Bromo-2-methylpyridine

Description Referrence
Product Name
5-Bromo-2-methylpyridine
CAS No.
3430-13-5
Chemical Name
5-Bromo-2-methylpyridine
Synonyms
5-BROMO-2-PICOLINE;5-BROMOPICOLINE;3-BROMO-6-PICOLINE;2-Methyl-5-bromopyrid;5-Bromo-2-picoline,99%;5-BROMO-2-METHYLPYRIDINE;3-BROMO-6-METHYLPYRIDINE;2-METHYL-5-BROMOPYRIDINE;5-broMo-1-Methylpyridine;5-bormo-2-methylpyridine
CBNumber
CB7327298
Molecular Formula
C6H6BrN
Formula Weight
172.02
MOL File
3430-13-5.mol
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5-Bromo-2-methylpyridine Property

Melting point:
32-36 °C
Boiling point:
74 °C / 17mmHg
Density 
1.494±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
Solid
pka
3.59±0.10(Predicted)
color 
Off-White to Light Yellow
BRN 
107324
InChI
InChI=1S/C6H6BrN/c1-5-2-3-6(7)4-8-5/h2-4H,1H3
InChIKey
OFKWIQJLYCKDNY-UHFFFAOYSA-N
SMILES
C1(C)=NC=C(Br)C=C1
CAS DataBase Reference
3430-13-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-36-36/37/39
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H301Toxic if swalloed

H311Toxic in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B2572
Product name
5-Bromo-2-methylpyridine
Purity
>98.0%(GC)
Packaging
1g
Price
$19
Updated
2024/03/01
TCI Chemical
Product number
B2572
Product name
5-Bromo-2-methylpyridine
Purity
>98.0%(GC)
Packaging
5g
Price
$58
Updated
2024/03/01
Alfa Aesar
Product number
H27085
Product name
5-Bromo-2-methylpyridine, 98%
Packaging
250mg
Price
$44.3
Updated
2023/06/20
Alfa Aesar
Product number
H27085
Product name
5-Bromo-2-methylpyridine, 98%
Packaging
1g
Price
$84.4
Updated
2023/06/20
TRC
Product number
B685590
Product name
5-Bromo-2-picoline
Packaging
50g
Price
$1390
Updated
2021/12/16
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5-Bromo-2-methylpyridine Chemical Properties,Usage,Production

Description

It is an important intermediate in the organic synthesis, which has many applications, such as pharmaceutical intermediate, organic synthesis, organic solvent, production of dyes, pesticide, and spice. Specifically, this chemical can act as the raw material to prepare 2:2’-dipyridyl and its derivatives.1 Moreover, this compound may be involved in the synthesis of biaryls through a one-pot tandem borylation/Suzuki-Miyaura cross-coupling reaction catalyzed by a palladacycle.2 In addition, 5-bromo-2-methylpyridine has been demonstrated to function as the substrate in a general palladium-catalyzed coupling of aryl bromides/triflates and thiols.3 Besides, this substance can facilitate the synthesis of 5-arylamino-2-picolines via displacement of bromide by anthranilic acid and decarboxylation.4

Referrence

  1. Willink, H. D. T.; Wibaut, J. P., The preparation of 2 : 2'-dipyridyl and some of its derivatives. Recueil Des Travaux Chimiques Des Pays-Bas 1935, 54, 275-283.
  2. Wang, L. H.; Cui, X. L.; Li, J. Y.; Wu, Y. S.; Zhu, Z. W.; Wu, Y. J., Synthesis of Biaryls through a One-Pot Tandem Borylation/Suzuki-Miyaura Cross-Coupling Reaction Catalyzed by a Palladacycle. Eur. J. Org. Chem. 2012, 595-603.
  3. Itoh, T.; Mase, T., A general palladium-catalyzed coupling of aryl bromides/triflates and thiols. Org. Lett. 2004, 6, 4587-4590.
  4. Louis H. Peterson; Tolman, R. L., Reinvestigation of the synthesis of 5-arylamino-2-picolines J. Heterocycl. Chem. 1977.

Chemical Properties

Light yellow Cryst

Uses

5-Bromo-2-picoline is a halogenated pyridine derivative used is a building block in the preparation of nitrogen containing heterocyclic compounds.

5-Bromo-2-methylpyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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5-Bromo-2-methylpyridine Suppliers

Shanghai Taijilin Industrial Co., Ltd.
Tel
021-021-50630626 18964684208
Fax
021-50563898
Email
kate@tajilin.com
Country
China
ProdList
1230
Advantage
58
Aikon International Limited
Tel
025-66113011 18112977050
Fax
(5)02557626880
Email
cb6@aikonchem.com
Country
China
ProdList
15494
Advantage
58
Nanjing Starting Point High tech Materials Technology Co., Ltd
Tel
18724007942
Email
2556868169@qq.com
Country
China
ProdList
25
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1995
Advantage
65
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
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View Lastest Price from 5-Bromo-2-methylpyridine manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
5-Bromo-2-methylpyridine 3430-13-5
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-03
Hebei Weibang Biotechnology Co., Ltd
Product
5-Bromo-2-methylpyridine 3430-13-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-12
Hebei Chuanghai Biotechnology Co,.LTD
Product
5-Bromo-2-methylpyridine 3430-13-5
Price
US $9.00/KG
Min. Order
1KG
Purity
99.9
Supply Ability
1 ton
Release date
2024-08-21

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