5-BROMO-2-(METHYLTHIO)PYRIMIDINE

Product Name: 5-BROMO-2-(METHYLTHIO)PYRIMIDINE
CAS No.: 14001-67-3
Chemical Name: 5-BROMO-2-(METHYLTHIO)PYRIMIDINE
Synonyms: 5-BROMO-2-(METHYLTHIO)PYRIMIDINE;5-BROMO-2-METHYLSULFANYLPYRIMIDINE;2-Methylsulfanyl-5-broMopyriMidine;5-broMo-2-MethylpyriMidine-1-thiol;Pyrimidine, 5-bromo-2-(methylthio)-;5-Bromo-2-(methylthio)pyrimidine ,98%;5-BROMO-2-(METHYLTHIO)PYRIMIDINE ISO 9001：2015 REACH;5-BroMo-2-(Methylthio)pyriMidine
CBNumber: CB8452506
Molecular Formula: C5H5BrN2S
Formula Weight: 205.08
MOL File: 14001-67-3.mol

More

Less

5-BROMO-2-(METHYLTHIO)PYRIMIDINE Property

Melting point:: 63-68℃
Boiling point:: 281.2±13.0 °C(Predicted)
Density: 1.72±0.1 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
pka: -0.56±0.22(Predicted)
form: Crystalline Powder of Flakes
color: White
InChI: InChI=1S/C5H5BrN2S/c1-9-5-7-2-4(6)3-8-5/h2-3H,1H3
InChIKey: WFLSPLBDSJLPFW-UHFFFAOYSA-N
SMILES: C1(SC)=NC=C(Br)C=N1

More

Less

Safety

Hazard Codes: Xi,Xn,C
Risk Statements: 22-34
Safety Statements: 26-36/37/39-45
RIDADR: UN 1759 8/PG 2
WGK Germany: 3
Hazard Note: Irritant
HazardClass: 8
PackingGroup: Ⅱ
HS Code: 29335995

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 705896
Product name: 5-Bromo-2-(methylthio)pyrimidine
Purity: 97%
Packaging: 1g
Price: $79.7
Updated: 2022/05/15

TRC

Product number: B697830
Product name: 5-Bromo-2-(methylthio)pyrimidine
Packaging: 250mg
Price: $55
Updated: 2021/12/16

TRC

Product number: B697830
Product name: 5-Bromo-2-(methylthio)pyrimidine
Packaging: 500mg
Price: $65
Updated: 2021/12/16

Matrix Scientific

Product number: 069495
Product name: 5-Bromo-2-(methylthio)pyrimidine
Purity: 98%
Packaging: 5g
Price: $78
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB139356
Product name: 5-Bromo-2-(methylthio)pyrimidine
Packaging: 5G
Price: $79
Updated: 2021/12/16

More

Less

5-BROMO-2-(METHYLTHIO)PYRIMIDINE Chemical Properties,Usage,Production

Synthesis

74-93-1

32779-36-5

14001-67-3

Step 1: Synthesis of 5-bromo-2-methylmercaptopyrimidine To a stirred solution of 5-bromo-2-chloropyrimidine (0.3 g, 1.563 mmol) in dimethylformamide (DMF, 10 mL) was slowly added methyl mercaptan (0.1 mL, 1.563 mmol) at room temperature. The reaction mixture was then heated to 50 °C with continuous stirring for 3 hours. The reaction process was monitored by thin layer chromatography (TLC). Upon completion of the reaction, the reaction mixture was quenched by addition of water and extracted with ethyl acetate (EtOAc). The organic phases were combined and dried over anhydrous sodium sulfate (Na2SO4), followed by evaporation of the solvent under reduced pressure to give the crude product. The crude product was purified by silica gel (100-200 mesh) column chromatography using 5% ethyl acetate/hexane as eluent, resulting in purified 5-bromo-2-methylmercaptopyrimidine (0.240 g, 75% yield) as a white solid. Mass spectrometry (MS) analysis showed that [M++1] was 205.1.

References

[1] Patent: US2017/291910, 2017, A1. Location in patent: Paragraph 0496-0498

5-BROMO-2-(METHYLTHIO)PYRIMIDINE Preparation Products And Raw materials

Raw materials

ZINC Phosphorus oxitrichloride Carbon tetrachloride 2-Methylthio-4-pyrimidinol Bromine

Preparation Products

More

Less

5-BROMO-2-(METHYLTHIO)PYRIMIDINE Suppliers

China 114 Germany 2 India 1 United Kingdom 3 United States 16 Global 136

Jinan SanZhi Pharmaceutical Technology Co., Ltd.

Tel: 15053191807
Fax: -
Email: sales_sanzhi@163.com
Country: China
ProdList: 286
Advantage: 55

wuhan Dekray Biomedical Technology Co.,Ltd

Tel: 027-69573188 18221423799
Email: 1503407886@qq.com
Country: China
ProdList: 1439
Advantage: 58

ZHEJIANG ZETIAN FINE CHEMICALS CO.,LTD

Tel: 0571-87322520 18957127338
Fax: QQ:3007632051
Email: sales@zetchem.com
Country: China
ProdList: 467
Advantage: 55

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006356688 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
Advantage: 66

Beijing Ouhe Technology Co., Ltd

Tel: 010-010-82967028 13522913783
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12000
Advantage: 60

Pure Chemistry Scientific Inc.

Tel: 001-857-928-2050 or 1-888-588-9418
Fax: 001-617-206-9595
Email: sales@chemreagents.com
Country: United States
ProdList: 10186
Advantage: 62

Shandong Xiya Chemical Co., Ltd

Tel: 4009903999 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18729
Advantage: 57

More

Less

View Lastest Price from 5-BROMO-2-(METHYLTHIO)PYRIMIDINE manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd

Product: 5-Bromo-2-(methylthio)pyrimidine 14001-67-3
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 ton
Release date: 2024-11-13

Shanghai Rlavie Technology Co ltd

Product: 5-Bromo-2-(methylthio)pyrimidine 14001-67-3
Price: US $0.00-0.00/KG
Min. Order: 1g
Purity: 98%minHPLC
Supply Ability: 100kgs/month
Release date: 2021-11-17

Dideu Industries Group Limited

Product: 5-BROMO-2-(METHYLTHIO)PYRIMIDINE 14001-67-3
Price: US $1.10/g
Min. Order: 1g
Purity: 99.00%
Supply Ability: 100 Tons Min
Release date: 2021-12-01

14001-67-3, 5-BROMO-2-(METHYLTHIO)PYRIMIDINERelated Search:

5-Bromo-2-methylpyridine 5-Bromo-2-hydroxymethylpyridine 5-Bromo-2-methoxypyridine 5-BROMO-4-CHLORO-2-METHYLSULFANYL-PYRIMIDINE 4-Bromo-2-(methylthio)pyrimidine 5-BROMO-2-(METHYLTHIO)PYRIMIDINE-4-CARBOXYLIC ACID,5-BROMO-2-(METHYLTHIO)PYRIMIDINE-4-CARB&,5-Bromo-2-(methylthio)pyrimidine-4-carboxylic acid ,97% Methyl 5-bromo-2-(methylthio)pyrimidine-4-carboxylate ,97% 5-BROMO-2-(METHYLTHIO)PYRIMIDINE 5-BROMO-2-METHANESULFONYL-PYRIMIDINE 6-AMINO-5-BROMO-2-(ETHYLTHIO)PYRIMIDIN-4-OL 5-bromo-2-(methylsulfanyl)pyrimidin-4-ol 4-[(5-BROMOPYRIMIDIN-2-YL)THIO]ANILINE ((5-BROMOPYRIMIDIN-2-YL)THIO)ACETIC ACID 2-[(5-BROMOPYRIMIDIN-2-YL)THIO]ANILINE IFLAB-BB F2124-0044 5-Bromo-4-methoxy-2-(methylthio)pyrimidine METHYL [(5-BROMO-4-HYDROXY-6-METHYLPYRIMIDIN-2-YL)THIO]ACETATE 2-(2-thenyl)sulfonyl-5-bromopyrimidine

5-BROMO-2-METHYLSULFANYLPYRIMIDINE

5-BROMO-2-(METHYLTHIO)PYRIMIDINE

5-Bromo-2-(methylthio)pyrimidine ,98%

5-broMo-2-MethylpyriMidine-1-thiol

2-Methylsulfanyl-5-broMopyriMidine

5-<WBR>BroMo-<WBR>2-<WBR>(Methylthio)<WBR>pyriMidine

Pyrimidine, 5-bromo-2-(methylthio)-

5-BROMO-2-(METHYLTHIO)PYRIMIDINE ISO 9001：2015 REACH

14001-67-3

C5H5BrN2S

Building Blocks

Chemical Synthesis

Halogenated Heterocycles

Heterocyclic Building Blocks

Pyrimidines

Heterocycle-Pyrimidine series

Pyrimidine

Organohalides

Thio