5-Bromo-2-methylpyridine

ChemicalBook > CAS DataBase List > 5-Bromo-2-methylpyridine

5-Bromo-2-methylpyridine

Description Referrence

Product Name: 5-Bromo-2-methylpyridine
CAS No.: 3430-13-5
Chemical Name: 5-Bromo-2-methylpyridine
Synonyms: 5-BROMO-2-PICOLINE;5-BROMOPICOLINE;3-BROMO-6-PICOLINE;2-Methyl-5-bromopyrid;5-Bromo-2-picoline,99%;5-BROMO-2-METHYLPYRIDINE;3-BROMO-6-METHYLPYRIDINE;2-METHYL-5-BROMOPYRIDINE;5-broMo-1-Methylpyridine;5-bormo-2-methylpyridine
CBNumber: CB7327298
Molecular Formula: C6H6BrN
Formula Weight: 172.02
MOL File: 3430-13-5.mol

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5-Bromo-2-methylpyridine Property

Melting point:: 32-36 °C
Boiling point:: 74 °C / 17mmHg
Density: 1.494±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
form: Solid
pka: 3.59±0.10(Predicted)
color: Off-White to Light Yellow
BRN: 107324
InChI: InChI=1S/C6H6BrN/c1-5-2-3-6(7)4-8-5/h2-4H,1H3
InChIKey: OFKWIQJLYCKDNY-UHFFFAOYSA-N
SMILES: C1(C)=NC=C(Br)C=C1
CAS DataBase Reference: 3430-13-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-20/21/22
Safety Statements: 26-36-36/37/39
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29333990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H301Toxic if swalloed

H311Toxic in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: B2572
Product name: 5-Bromo-2-methylpyridine
Purity: >98.0%(GC)
Packaging: 1g
Price: $19
Updated: 2024/03/01

TCI Chemical

Product number: B2572
Product name: 5-Bromo-2-methylpyridine
Purity: >98.0%(GC)
Packaging: 5g
Price: $58
Updated: 2024/03/01

Alfa Aesar

Product number: H27085
Product name: 5-Bromo-2-methylpyridine, 98%
Packaging: 250mg
Price: $44.3
Updated: 2023/06/20

Alfa Aesar

Product number: H27085
Product name: 5-Bromo-2-methylpyridine, 98%
Packaging: 1g
Price: $84.4
Updated: 2023/06/20

TRC

Product number: B685590
Product name: 5-Bromo-2-picoline
Packaging: 50g
Price: $1390
Updated: 2021/12/16

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5-Bromo-2-methylpyridine Chemical Properties,Usage,Production

Description

It is an important intermediate in the organic synthesis, which has many applications, such as pharmaceutical intermediate, organic synthesis, organic solvent, production of dyes, pesticide, and spice. Specifically, this chemical can act as the raw material to prepare 2:2’-dipyridyl and its derivatives.¹ Moreover, this compound may be involved in the synthesis of biaryls through a one-pot tandem borylation/Suzuki-Miyaura cross-coupling reaction catalyzed by a palladacycle.² In addition, 5-bromo-2-methylpyridine has been demonstrated to function as the substrate in a general palladium-catalyzed coupling of aryl bromides/triflates and thiols.³ Besides, this substance can facilitate the synthesis of 5-arylamino-2-picolines via displacement of bromide by anthranilic acid and decarboxylation.⁴

Referrence

Willink, H. D. T.; Wibaut, J. P., The preparation of 2 : 2'-dipyridyl and some of its derivatives. Recueil Des Travaux Chimiques Des Pays-Bas 1935, 54, 275-283.
Wang, L. H.; Cui, X. L.; Li, J. Y.; Wu, Y. S.; Zhu, Z. W.; Wu, Y. J., Synthesis of Biaryls through a One-Pot Tandem Borylation/Suzuki-Miyaura Cross-Coupling Reaction Catalyzed by a Palladacycle. Eur. J. Org. Chem. 2012, 595-603.
Itoh, T.; Mase, T., A general palladium-catalyzed coupling of aryl bromides/triflates and thiols. Org. Lett. 2004, 6, 4587-4590.
Louis H. Peterson; Tolman, R. L., Reinvestigation of the synthesis of 5-arylamino-2-picolines J. Heterocycl. Chem. 1977.

Chemical Properties

Light yellow Cryst

Uses

5-Bromo-2-picoline is a halogenated pyridine derivative used is a building block in the preparation of nitrogen containing heterocyclic compounds.

5-Bromo-2-methylpyridine Preparation Products And Raw materials

Raw materials

Preparation Products

5-Bromo-2-hydroxymethylpyridine 5-BROMO-2-METHYLPYRIDINE N-OXIDE 4-AMINO-5-BROMO-2-METHYLPYRIDINE 5-Bromopyridine-2-carbaldehyde 6-Methylpyridine-3-boronic Acid

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5-Bromo-2-methylpyridine Suppliers

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View Lastest Price from 5-Bromo-2-methylpyridine manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 5-Bromo-2-methylpyridine 3430-13-5
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-03

Hebei Weibang Biotechnology Co., Ltd

Product: 5-Bromo-2-methylpyridine 3430-13-5
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-12

Hebei Chuanghai Biotechnology Co,.LTD

Product: 5-Bromo-2-methylpyridine 3430-13-5
Price: US $9.00/KG
Min. Order: 1KG
Purity: 99.9
Supply Ability: 1 ton
Release date: 2024-08-21

3430-13-5, 5-Bromo-2-methylpyridineRelated Search:

5-Bromo-2-hydroxymethylpyridine 5-Bromo-2-methoxypyridine 5-BROMO-2-(METHYLTHIO)PYRIMIDINE 2-AMINO-3,5-DIBROMO-6-METHYLPYRIDINE 2,6-Dimethyl-3,5-dibromopyridine 5-Bromo-2-methylpyridine 3-Bromo-2,6-dimethylpyridine Methyl 6-bromonicotinate 5-bromo-2-pyridinecarboxylic acid ethyl ester 5-Bromo-2-pyridinecarbonitrile 6-AMINO-5-BROMO-2-PICOLINE 5-BROMO-2-METHYLPYRIDINE N-OXIDE 3,5-DIBROMO-2,4,6-TRIMETHYLPYRIDINE 2-CHLORO-3-BROMO-6-PICOLINE 2,5,6-Tribromo-3-methylpyridine 2-FLUORO-3-BROMO-6-PICOLINE 2,3-DIBROMO-6-PICOLINE 3-AMINO-2-BROMO-5-PICOLINE

5-broMo-1-Methylpyridine

5--2- MethylpyridinebroMide

2 - Methyl - 5 - broMide pyridine

2-METHYL-5-BROMOPYRIDINE

5-BROMOPICOLINE

3-BROMO-6-METHYLPYRIDINE

5-BROMO-2-METHYLPYRIDINE

5-BROMO-2-PICOLINE

3-BROMO-6-PICOLINE

5-Bromo-2-methylpyridine 98%

Pyridine, 5-bromo-2-methyl-

2-METHYL-5-BROMOPYRIDINE 98.5%(MIN)

2-Methyl-5-bromopyrid

5-bormo-2-methylpyridine

5-Bromo-2-picoline,99%

2-Picoline, 5-bromo- (6CI,7CI,8CI)

5-Bromo-2-methylpyridine ,99%

5-BROMO-2-METHYLPYRIDINE (5-BROMO-2-PICOLINE)

5-BROMO-2-PICOLINE5-BROMO-2-METHYLPYRIDINE

5-BroMo-2-picoline, 99% 1GR

5-Bromo-2-methylpyridine &gt

5-Bromo-2-methylpyridine ISO 9001：2015 REACH

3430-13-5

3430-18-5

340-13-5

1074-98-7

Building Blocks

Heterocyclic Building Blocks

Bromopyridines

Halopyridines

Pyridines

Halogenated Heterocycles

Building Blocks

Chemical Synthesis

Halogenated Heterocycles

Heterocyclic Building Blocks

Pyridines derivates

Bromopyridines

Halopyridines

Pyridine series

blocks

Bromides

Pyridines

Pyridine

Pyridines, Pyrimidines, Purines and Pteredines

alkyl bromide

3430-13-5