Phenyl chlorothionocarbonate

Product Name: Phenyl chlorothionocarbonate
CAS No.: 1005-56-7
Chemical Name: Phenyl chlorothionocarbonate
Synonyms: O-Phenyl carbonochloridothioate;PHENYL CHLOROTHIONOFORMATE;O-PHENYL CHLOROTHIONOFORMATE;PHENYL THIONOCHLOROFORMATE;phenylcarbonochloridothioate;phenyl thioxochloroformate;Phenoxythiocarbonyl chloride;O-phenyl chloromethanethioate;NSC 99103;Phenoxythiocar
CBNumber: CB7480281
Molecular Formula: C7H5ClOS
Formula Weight: 172.63
MOL File: 1005-56-7.mol

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Phenyl chlorothionocarbonate Property

Melting point:: 51 °C
Boiling point:: 81-83 °C/6 mmHg (lit.)
Density: 1.248 g/mL at 25 °C (lit.)
refractive index: n20/D 1.581(lit.)
Flash point:: 179 °F
storage temp.: Inert atmosphere,2-8°C
solubility: Chloroform, Ethyl Acetate
form: Liquid
Specific Gravity: 1.248
color: Clear yellow
Water Solubility: decomposes
Sensitive: Moisture Sensitive
BRN: 774830
CAS DataBase Reference: 1005-56-7(CAS DataBase Reference)

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: UN 3265 8/PG 2
WGK Germany: 3
F: 10-21
HazardClass: 8
PackingGroup: II
HS Code: 29309070

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 234524
Product name: O-Phenyl chlorothionoformate
Purity: 99%
Packaging: 5g
Price: $96.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 234524
Product name: O-Phenyl chlorothionoformate
Purity: 99%
Packaging: 1g
Price: $28.2
Updated: 2023/06/20

TCI Chemical

Product number: P1236
Product name: Phenyl Chlorothionoformate
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $32
Updated: 2024/03/01

TCI Chemical

Product number: P1236
Product name: Phenyl Chlorothionoformate
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $97
Updated: 2024/03/01

Alfa Aesar

Product number: L00838
Product name: Phenyl chlorothionoformate, 98+%
Packaging: 1g
Price: $28.65
Updated: 2024/03/01

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Phenyl chlorothionocarbonate Chemical Properties,Usage,Production

Chemical Properties

CLEAR YELLOW LIQUID

Uses

O-Phenyl chlorothionoformate has been used in:

stereodirected synthesis of optically active, (?)-mintlactone
synthesis of peptide α-thioesters having a variety of C-terminal amino acids
synthesis of scyllo-inositol derivatives
thionocarbonylation of unprotected thymine nucleosides
preparation of phenoxythiocarbonyl esters of protected ribonucleosides

Uses

Phenyl Chlorothionoformate is used in the preparation of an bicyclic thymidine analogs as selective inhibitors of Thymidine monophosphate kinase Mycobacterium tuberculosis (TMPKmt).

Purification Methods

Purify it by dissolving in CHCl3, washing with H2O, drying (CaCl2), filtering, evaporating and distilling twice under a vacuum to give a clear yellow liquid. It is reactive and POISONOUS—work in a fume cupboard. Store it in sealed ampoules under N2. A possible impurity is O,O'-diphenyl thiocarbonate which has m 106o and remains behind in the distilling flask. [B.gemann et al. in Methoden Der Organischen Chemie (Houben-Weyl) 4th edn (E. Müller Ed.) Vol 9 Schwefel-Selen-Tellur Verbindungen pp. 807-808 1955, Rivier & Schalch Helv Chim Acta 6 612 1923, Kalson Chem Ber 20, 2384 1987, Rivier & Richard Helv Chim Acta 8 490 1925, Sch.nberg & Varga Justus Liebigs Ann Chem 483 176 1930, Sch.nberg & Vargha Chem Ber 64 1390 1931, Beilstein 6 III 609.]

Phenyl chlorothionocarbonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Phenyl chlorothionocarbonate Suppliers

Americas 1 Belgium 2 Canada 2 China 187 Europe 2 France 1 Germany 6 India 27 Japan 3 Poland 1 South Korea 2 Switzerland 3 United Kingdom 9 United States 27 Global 273

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View Lastest Price from Phenyl chlorothionocarbonate manufacturers

JINING XINHE CHEMICAL CO., LTD

Product: Phenyl chlorothionoformate 1005-56-7
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 20
Release date: 2024-11-12

Shaanxi Dideu Medichem Co. Ltd

Product: Phenyl chlorothionocarbonate 1005-56-7
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000KG
Release date: 2024-07-16

Career Henan Chemical Co

Product: Phenyl chlorothionocarbonate 1005-56-7
Price: US $1.00/kg
Min. Order: 1kg
Purity: 95%-99%
Supply Ability: as request
Release date: 2018-12-25

1005-56-7, Phenyl chlorothionocarbonateRelated Search:

Diphenyl ether Benzyl benzoate Benzyl chloroformate PHENYL ACETATE Phenyl chloroformate Dimethyl phthalate Thiobenzoic acid Phenyl butyrate Phenyl salicylate Phenyl dichlorophosphate Diisononyl phthalate PHENYL VALERATE 3-Chloroperoxybenzoic acid Triethyl phosphonoacetate Phenyl benzoate Phenyl bromoacetate PHENYL RESIN Potassium di-tert-butyl phosphate

phenylcarbonochloridothioate

Phenyl thiochloroformate.

Phenoxythiocarbonyl chloride

Phenyl chlorothionoformate, 98+%

Formic acid, chlorothio-, O-phenyl ester

O-Phenyl carbonochloridothioate

(Phenoxy)thioformyl chloride

Chloridothiocarbonic acid O-phenyl ester

Chloridothiocarbonic acid phenyl ester

Phenyl chlorothionocarbonate,99%

2-Phenyl chlorothionoformate

Phenyl chlorothionocarbonate, 99% 5GR

NSC 99103

Phenoxythiocar

Chlorothioformic Acid O-Phenyl Ester Phenyl Thionochloroformate

O-Phenyl chlorothionoforMate 99%

Chlorothioformic Acid O-Phenyl Ester,Phenyl Thionochloroformate,Phenyl Chlorothionoformate Phenyl chlorothionocarbonate

O-Phenyl chlorothioformate for synthesis

Carbonochloridothioicacid,O-phenylester

O-PHENYL CHLOROTHIOCARBONATE

O-PHENYL CHLOROTHIOFORMATE

O-PHENYL CHLOROTHIONOFORMATE

PHENYL CHLOROTHIONOCARBONATE

PHENYL CHLOROTHIONOFORMATE

PHENYL CHLOROTHIOXOFORMATE

PHENYL THIONOCHLOROFORMATE

CHLOROTHIOFORMIC ACID O-PHENYL ESTER

CHLOROTHIOFORMIC ACID PHENYL ESTER

phenyl thioxochloroformate

HENYL CHLOROTHIONOCARBONATE

Phenylchlorothionocarbonate~Phenylthionochloroformate

PhenylChlorothionoformate&gt

orothionoformate

phenyl chloromethanethioate

O-Phenyl chlorotionoformate

O-phenyl chloromethanethioate

p-chlorobenzoic acid thioester

1005-56-7

ClCSOC6H5

C7H5ClOS

Building Blocks

Thiocarbonyl Compounds

Sulfur Compounds

Organic Building Blocks

Sulfur Compounds (for Synthesis)

Building Blocks

Chemical Synthesis

Organic Building Blocks

Sulfur Compounds

Thiocarbonyl Compounds

Sulfur Compounds (for Synthesis)

Synthetic Organic Chemistry