ChemicalBook > CAS DataBase List > 5-Bromo-2-methoxypyrimidine

5-Bromo-2-methoxypyrimidine

Product Name: 5-Bromo-2-methoxypyrimidine
CAS No.: 14001-66-2
Chemical Name: 5-Bromo-2-methoxypyrimidine
Synonyms: Bromomethoxypyrimidine;5-Bromo-2-methoxypyrimidine;2-Methoxy-5-bromopyrimidine;5-Bromo-22-methoxypyrimidine;5-Bromo-2-methoxy-1,3-diazine;Pyrimidine, 5-bromo-2-methoxy-;5-Bromo-2-(methyloxy)pyrimidine;5-Bromo-2-methoxypyrimidine 98%;5-BROMO-2-METHOXYPYRIMIDINE 97;5-Bromo-2-methoxypyrimidine >
CBNumber: CB7505281
Molecular Formula: C5H5BrN2O
Formula Weight: 189.01
MOL File: 14001-66-2.mol

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5-Bromo-2-methoxypyrimidine Property

Melting point:: 55.5-59.5 °C (lit.)
Boiling point:: 259.8±32.0 °C(Predicted)
Density: 1.628±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
pka: -0.22±0.22(Predicted)
form: Solid
color: White to yellow (may have pinkish tinge)
CAS DataBase Reference: 14001-66-2(CAS DataBase Reference)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22-43
Safety Statements: 37/39
WGK Germany: 3
Hazard Note: Irritant
HS Code: 29333990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 634883
Product name: 5-Bromo-2-methoxypyrimidine
Purity: 97%
Packaging: 1g
Price: $32.3
Updated: 2023/06/20

TCI Chemical

Product number: B3521
Product name: 5-Bromo-2-methoxypyrimidine
Purity: >98.0%(GC)
Packaging: 1g
Price: $33
Updated: 2025/07/31

TCI Chemical

Product number: B3521
Product name: 5-Bromo-2-methoxypyrimidine
Purity: >98.0%(GC)
Packaging: 5g
Price: $165
Updated: 2025/07/31

TRC

Product number: B696908
Product name: 5-Bromo-2-methoxypyrimidine
Packaging: 250mg
Price: $55
Updated: 2021/12/16

Matrix Scientific

Product number: 069463
Product name: 5-Bromo-2-methoxypyrimidine
Purity: 98%
Packaging: 1g
Price: $38
Updated: 2021/12/16

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5-Bromo-2-methoxypyrimidine Chemical Properties,Usage,Production

Chemical Properties

White solid

Synthesis

124-41-4

32779-36-5

14001-66-2

Synthesis of compound 11-3 (5-bromo-2-methoxypyrimidine): to a solution of 5-bromo-2-chloropyrimidine (11-2, 2.0 g, 10 mmol) in methanol (15 mL) was added sodium methanolate (CH3ONa, 2.16 g, 40 mmol). The reaction mixture was stirred at 70 °C overnight. Upon completion of the reaction, methanol was removed by rotary evaporator under reduced pressure. Water (10 mL) was slowly added to the residue, followed by extraction with ethyl acetate (300 mL x 3). The organic phases were combined, dried over anhydrous sodium sulfate (Na2SO4), filtered and concentrated to give 11-3 as a yellow solid (1.17 g, 60% yield).

References

[1] Patent: US9138427, 2015, B2. Location in patent: Page/Page column 289-290
[2] Bioorganic and Medicinal Chemistry Letters, 2011, vol. 21, # 19, p. 5849 - 5853

5-Bromo-2-methoxypyrimidine Preparation Products And Raw materials

Raw materials

Ethyl 2-(Chlorosulfonyl)acetate Phosphorus oxitrichloride Carbon tetrachloride 2-Methylthio-4-pyrimidinol Chloramine-T Zinkamalgam Bromine Methanol

Preparation Products

2-Methoxypyrimidine-5-boronic acid

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View Lastest Price from 5-Bromo-2-methoxypyrimidine manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 5-Bromo-2-methoxypyrimidine 14001-66-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-06-04

Hebei Chuanghai Biotechnology Co., Ltd

Product: 5-Bromo-2-methoxypyrimidine 14001-66-2
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5tons
Release date: 2024-12-03

Hebei Zhuanglai Chemical Trading Co Ltd

Product: 5-Bromo-2-methoxypyrimidine 14001-66-2
Price: US $150.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 500kg
Release date: 2024-11-12

14001-66-2, 5-Bromo-2-methoxypyrimidineRelated Search:

5-BROMO-2,4-DIMETHOXYPYRIMIDINE 2 , 4-BIS(BENZYLOXY)-5-BROMOPYRIMIDINE 2,4-DI-(TERT-BUTOXY)-5-BROMOPYRIMIDINE 2-BROMO-6-METHOXYPYRIMIDINE 5-BROMO-2-METHOXYPYRIMIDIN-4-YLAMINE 2-Bromo-4-methoxypyridine 2-Bromo-6-methoxypyrimidine 5-Bromopyrimidine 5-BROMO-2-(P-TOLYLOXY)PYRIMIDINE N-(4-(5-bromo-2-pyrimidinyloxy)-3-chlorophenyl)-N'-(2-nitrobenzoyl)urea 5-BROMO-2-(4-METHOXYPHENOXY)PYRIMIDINE 5-BROMO-2-(4-FLUOROPHENOXY)PYRIMIDINE 5-BROMO-2-(4-CHLOROPHENOXY)PYRIMIDINE 4-[(5-BROMOPYRIMIDIN-2-YL)OXY]BENZONITRILE 2-AMINO-5-BROMO-4-METHOXYPYRIMIDINE 4-AMINO-5-BROMO-6-METHOXYPYRIMIDINE 5-BROMO-2,4,6-TRIETHOXYPYRIMIDINE N-(((4-((5-Bromo-2-pyrimidinyl)oxy)-3-nitrophenyl)amino)carbonyl)-2-ni trobenzamide

Bromomethoxypyrimidine

5-BROMO-2-METHOXYPYRIMIDINE 97

2-Methoxy-5-bromopyrimidine

5-Bromo-2-methoxypyrimidine

5-Bromo-2-methoxy-1,3-diazine

5-Bromo-2-methoxypyrimidine 98%

2-Methoxy-5-broMopyriMidine(5-BroMo-2-MethoxypyriMidine)

5-Bromo-22-methoxypyrimidine

5-Bromo-2-methoxypyrimidine &gt

Pyrimidine, 5-bromo-2-methoxy-

5-Bromo-2-(methyloxy)pyrimidine

5-Bromo-2-methoxypyrimidine ISO 9001：2015 REACH

14001-66-2

C5H5BrN2O

Heterocycle-Pyrimidine series

Building Blocks

Halogenated Heterocycles

Heterocyclic Building Blocks

Pyrimidines

PyrimidinesHeterocyclic Building Blocks

Pyrimidine

Alkoxy

Organohalides