TERT-BUTYL METHYL MALONATE

Product Name: TERT-BUTYL METHYL MALONATE
CAS No.: 42726-73-8
Chemical Name: TERT-BUTYL METHYL MALONATE
Synonyms: TERT-BUTYL METHYL MA;T-BUTYL METHYL MALONATE;ert-ButylMethylMalonate;TERT-BUTYL METHYL MALOTE;Methyl tert-butyl malonate;TERT-BUTYL METHYL MALONATE;TERT-BUTYL-(METHYLMALONAT);tert.-Butyl methylemalonate;tert.-Butyl methyl malonate,95%;tert-Butyl methyl malonate
CBNumber: CB7772557
Molecular Formula: C8H14O4
Formula Weight: 174.19
MOL File: 42726-73-8.mol

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TERT-BUTYL METHYL MALONATE Property

Melting point:: -10 °C
Boiling point:: 80 °C11 mm Hg(lit.)
Density: 1.03 g/mL at 25 °C(lit.)
refractive index: n20/D 1.415(lit.)
Flash point:: 175 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
pka: 11.83±0.46(Predicted)
form: Liquid
color: Clear colorless to slightly yellow
BRN: 1772136
InChI: InChI=1S/C8H14O4/c1-8(2,3)12-7(10)5-6(9)11-4/h5H2,1-4H3
InChIKey: XPSYZCWYRWHVCC-UHFFFAOYSA-N
SMILES: C(OC(C)(C)C)(=O)CC(OC)=O

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Safety

Safety Statements: 23-24/25
WGK Germany: 3
HS Code: 29171900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H227Combustible liquid
Precautionary statements: P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 360015
Product name: tert-Butyl methyl malonate
Purity: 95%
Packaging: 10ml
Price: $174
Updated: 2023/06/20

TCI Chemical

Product number: B2747
Product name: tert-Butyl Methyl Malonate
Purity: min. 95.0 %
Packaging: 5G
Price: $82
Updated: 2025/07/31

TCI Chemical

Product number: B2747
Product name: tert-Butyl Methyl Malonate
Purity: min. 95.0 %
Packaging: 25G
Price: $246
Updated: 2025/07/31

TRC

Product number: B809128
Product name: tert-Butyl methyl malonate
Packaging: 500mg
Price: $60
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB72074
Product name: tert-Butyl methyl malonate
Packaging: 25g
Price: $70
Updated: 2021/12/16

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TERT-BUTYL METHYL MALONATE Chemical Properties,Usage,Production

Chemical Properties

clear colorless to slightly yellow liquid

General Description

tert-Butyl methyl malonate is an ester. Stereospecific Pd(O)-catalyzed addition of tert-butyl methyl malonate to allylic carbonates is reported.

Synthesis

67-56-1

40052-13-9

42726-73-8

To a 200 mL round bottom flask equipped with a magnetic stirrer was added mono-tert-butyl malonate (3.0 g, 18.7 mmol) and methanol (70 mL). To this solution was added hafnium(IV) chloride tetrahydrofuran complex (1:2) (88 mg, 0.19 mmol). The reaction mixture was stirred at room temperature for 48 hours. After completion of the reaction, saturated saline was added to the mixture and extracted with dichloromethane (3 x 70 mL). The organic layers were combined, dried with anhydrous magnesium sulfate and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: n-hexane/ethyl acetate = 50:50) to afford the target compound tert-butyl methyl malonate (3.0 g, 91% yield) as a colorless oily liquid.1H NMR (400 MHz, CDCl3) δ 3.74 (s, 3H), 3.30 (s, 2H), 1.47 (s, 9H); 13C NMR ( 100 MHz, CDCl3) δ 167.5, 165.8, 82.1, 52.3, 42.7, 27.9; HR-FAB MS m/z calculated value C8H15O4 [M+H]+ 175.0883, measured value 175.0875.

References

[1] Tetrahedron Asymmetry, 2015, vol. 26, # 4, p. 214 - 218

TERT-BUTYL METHYL MALONATE Preparation Products And Raw materials

Raw materials

tert-Butyl methyl ether Potassium hydroxide Dimethyl malonate Sodium sulfate tert-Butanol Diethyl ether Hydrochloric acid Sodium bicarbonate Dichloromethane Methanol Dicyclohexylcarbodiimide 4-Dimethylaminopyridine

Preparation Products

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TERT-BUTYL METHYL MALONATE Suppliers

Belgium 1 China 150 Germany 1 India 5 Slovakia 1 Switzerland 2 United Kingdom 7 United States 17 Global 184

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Beijing Isomersyn Technology CO;LTD

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View Lastest Price from TERT-BUTYL METHYL MALONATE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: TERT-BUTYL METHYL MALONATE 42726-73-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2025-03-14

Henan Aochuang Chemical Co.,Ltd.

Product: tert-Butyl methyl malonate 42726-73-8
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-29

Career Henan Chemical Co

Product: TERT-BUTYL METHYL MALONATE 42726-73-8
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: Customized
Release date: 2018-12-22

42726-73-8, TERT-BUTYL METHYL MALONATERelated Search:

BENZYL TERT-BUTYL MALONATE Di-tert-Butyl malonate TERT-BUTYL ETHYL MALONATE Diisopropyl malonate Ethyl potassium malonate 3-tert-Butoxy-3-oxopropanoic acid Dimethyl malonate Potassium 3-methoxy-3-oxopropanoate Ethyl hydrogen malonate Diethyl malonate MONOMETHYL MALONATE Malonic acid tert-Butylhydrazine hydrochloride tert-Butyldimethylsilyl chloride tert-butyl((4-bromo-5-cyano-1-methyl-1H-pyrazol-3-yl)methyl)(methyl)carbamate tert-Butyl nitrite tert-Butylchlorodiphenylsilane Coumarin 338

T-BUTYL METHYL MALONATE

TERT-BUTYL-(METHYLMALONAT)

TERT-BUTYL METHYL MALONATE

Methyl tert-butyl malonate

Propanedioic acid 1,1-dimethylethyl methyl ester

Malonic acid 1-methyl 3-tert-butyl ester

Malonic acid 1-tert-butyl 3-methyl ester

Propanedioic acid 1-(1,1-dimethylethyl)3-methyl ester

tert.-Butyl methyl malonate,95%

Malonic acid tert-butyl methyl ester

TERT-BUTYL METHYL MALOTE

tert.-Butyl methylemalonate

TERT-BUTYL METHYL MA

tert.-Butyl Methyl Malonate, 95% 5ML

3-tert-Butoxy-2-methyl-3-oxopropanoicacid

propanedioic acid O3-tert-butyl ester O1-methyl ester

1-tert-butyl 3-methyl propanedioate

ert-ButylMethylMalonate

TERT-BUTYL METHYL MALONATE 42726-73-8

3-O-tert-butyl 1-O-methyl propanedioate

<i>tert</i>-Butyl methyl malonate

42726-73-8

CH3OCOCH2COOCCH33

Esters

Organic Building Blocks

C8 to C9

Building Blocks

Carbonyl Compounds

Aromatic Esters

C8 to C9

Carbonyl Compounds

Esters