1,1'-Bis(diisopropylphosphino)ferrocene

ChemicalBook > CAS DataBase List > 1,1'-Bis(diisopropylphosphino)ferrocene

1,1'-Bis(diisopropylphosphino)ferrocene

Reaction

Product Name: 1,1'-Bis(diisopropylphosphino)ferrocene
CAS No.: 97239-80-0
Chemical Name: 1,1'-Bis(diisopropylphosphino)ferrocene
Synonyms: 1,1'-Bis(diisopropyL;1,1'-Bis(di-i-propylphosphino)f;cyclopentyl(diisopropyl)phosphane;-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-Bis(di-i-propylphosphino)ferrocene;1,1'-bis-(di-Isopropylphosphino)ferrocene;1,1'-Bis(diisopropylphosphino)ferrocene>1,1'-Bis(diisopropylphosphino)ferrocene,98%;1,1'-Bis(di-i-propylphosphino)ferrocene,98%
CBNumber: CB8105732
Molecular Formula: C22H36FeP210*
Formula Weight: 418.31
MOL File: 97239-80-0.mol

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1,1'-Bis(diisopropylphosphino)ferrocene Property

Melting point:: 50-52 °C(lit.)
Flash point:: >230 °F
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
color: orange-yellow
Water Solubility: Insoluble in water.
InChI: InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3;
InChIKey: LPBBEMRSRONKMN-UHFFFAOYSA-N
SMILES: P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23|
CAS DataBase Reference: 97239-80-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 37/39-26
WGK Germany: 3
TSCA: No
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 578266
Product name: 1,1′-Bis(diisopropylphosphino)ferrocene
Purity: 97%
Packaging: 500mg
Price: $114
Updated: 2024/03/01

TCI Chemical

Product number: B2710
Product name: 1,1'-Bis(diisopropylphosphino)ferrocene
Purity: >98.0%(T)
Packaging: 1g
Price: $144
Updated: 2024/03/01

TCI Chemical

Product number: B2710
Product name: 1,1'-Bis(diisopropylphosphino)ferrocene
Purity: >98.0%(T)
Packaging: 100mg
Price: $38
Updated: 2024/03/01

Alfa Aesar

Product number: H27057
Product name: 1,1'-Bis(diisopropylphosphino)ferrocene, 98%
Packaging: 1g
Price: $169
Updated: 2023/06/20

Alfa Aesar

Product number: H27057
Product name: 1,1'-Bis(diisopropylphosphino)ferrocene, 98%
Packaging: 5g
Price: $571
Updated: 2023/06/20

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1,1'-Bis(diisopropylphosphino)ferrocene Chemical Properties,Usage,Production

Reaction

Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes
Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO.
Pd-catalyzed carbonylative ɑ-arylation of ketones with aryl iodides
Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters
Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation
Ligand for ruthenium-catalyzed C—C coupling reactions of fluorinated alcohols with allenes.
Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents.

Chemical Properties

orange crystalline powder

Uses

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

1,1'-Bis(diisopropylphosphino)ferrocene Preparation Products And Raw materials

Raw materials

Ferrocene Hexane N,N,N',N'-Tetramethylethylenediamine Chlorodiisopropylphosphine n-Butyllithium

Preparation Products

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1,1'-Bis(diisopropylphosphino)ferrocene Suppliers

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View Lastest Price from 1,1'-Bis(diisopropylphosphino)ferrocene manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 1,1'-Bis(diisopropylphosphino)ferrocene 97239-80-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-30

Henan Research New Materials Co., Ltd.

Product: 1,1'-Bis(diisopropylphosphino)ferrocene 97239-80-0
Price: US $0.00-0.00/Kg
Min. Order: 1Kg
Purity: 98％
Supply Ability: 100kg
Release date: 2024-07-26

XINXIANG RUNYU MATERIAL CO., LTD.

Product: 1,1'-Bis(diisopropylphosphino)ferrocene 97239-80-0
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 50KG
Release date: 2024-10-14

97239-80-0, 1,1'-Bis(diisopropylphosphino)ferroceneRelated Search:

1,1'-Bis(di-tert-butylphosphino)ferrocene 1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE 1,2,3,4,5-PENTAPHENYL-1'-(DI-TERT-BUTYLPHOSPHINO)FERROCENE 1,1'-Bis(diphenylphosphino)ferrocene Ferrocene 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, 1,1'-BIS(DI-I-PROPYLPHOSPHINO)FERROCENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE 1,1-Bis[(2S,3S,4S,5S)-2,5-dimethyl-3,4-O-isopropylidene-3,4-dihydroxyphospholanyl]ferrocene 1,1μ-Bis[(2S,5S)-2,5-diisopropylphospholano]ferrocene S,S-Me-FerrocelaneTM 1,1μ-Bis(diisopropylphosphino)ferrocene(cod)Rh-phosphotungstic acid on alumox (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE 1,1-BIS(DIISOPROPYLPHOSPHINO)FERROCENE(COD)RH-PHOSPHOTUNGSTIC ACID 1,1μ-Bis[(2R,5R)-2,5-diisopropylphospholano]ferrocene 1,1'-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]FERROCENE

BIS[(DIISOPROPYLPHOSPHINO)CYCLOPENTADIENYL]IRON

1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE

-BIS(DIISOPROPYLPHOSPHINO)FERROCENE

1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98%

1,1'-Bis(diisopropylphosphino)ferrocene,98%

1,1'-Bis(di-i-propylphosphino)ferrocene,min.98%

1,1'-Bis[bis(1-methylethyl)phosphino]ferrocene

Ferrocene,1,1'-bis[bis(1-Methylethyl)phosphino]-

1,1'-Bis(di-i-propylphosphino)ferrocene,98%

cyclopentyl(diisopropyl)phosphane

1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF

1,1'-Bis(di-i-propylphosphino)f

1,1'-Bis(diisopropylphosphino)ferrocene&gt

1,1'-Bis(diisopropyL

1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE ISO 9001：2015 REACH

bis(2-diisopropylphosphanylcyclopenta-1,3-dien-1-yl)iron

1,1'-bis-(di-Isopropylphosphino)ferrocene

1,1'-Bis(di-i-propylphosphino)ferrocene

97239-80-0

97239-80-8

C22H36FeP210

C22H36FeP2

2C11H18PFe

Phosphine Ligands

Ferrocenes

Metallocenes

Polydentate Phosphine Ligands

Phosphorus Compounds

Catalysis and Inorganic Chemistry

Achiral Phosphine

Aryl Phosphine

Ligand

Ferrocenes

Metallocenes

Phosphine Ligands

Synthetic Organic Chemistry

Catalysis and Inorganic Chemistry

Phosphorus Compounds

Polydentate Phosphine Ligands