1,1'-Bis(diisopropylphosphino)ferrocene
Reaction- Product Name
- 1,1'-Bis(diisopropylphosphino)ferrocene
- CAS No.
- 97239-80-0
- Chemical Name
- 1,1'-Bis(diisopropylphosphino)ferrocene
- Synonyms
- 1,1'-Bis(diisopropyL;1,1'-Bis(di-i-propylphosphino)f;cyclopentyl(diisopropyl)phosphane;-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE;1,1'-BIS(DI-I-PROPYLPHOSPHINO)FERROCENE;1,1'-Bis(di-i-propylphosphino)ferrocene;1,1'-bis-(di-Isopropylphosphino)ferrocene;1,1'-Bis(diisopropylphosphino)ferrocene>1,1'-Bis(di-i-propylphosphino)ferrocene,98%
- CBNumber
- CB8105732
- Molecular Formula
- C22H36FeP210*
- Formula Weight
- 418.31
- MOL File
- 97239-80-0.mol
1,1'-Bis(diisopropylphosphino)ferrocene Property
- Melting point:
- 50-52 °C(lit.)
- Flash point:
- >230 °F
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- color
- orange-yellow
- Water Solubility
- Insoluble in water.
- InChI
- InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3;
- InChIKey
- LPBBEMRSRONKMN-UHFFFAOYSA-N
- SMILES
- P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23|
- CAS DataBase Reference
- 97239-80-0(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 578266
- Product name
- 1,1′-Bis(diisopropylphosphino)ferrocene
- Purity
- 97%
- Packaging
- 500mg
- Price
- $114
- Updated
- 2024/03/01
- Product number
- B2710
- Product name
- 1,1'-Bis(diisopropylphosphino)ferrocene
- Purity
- >98.0%(T)
- Packaging
- 1g
- Price
- $144
- Updated
- 2024/03/01
- Product number
- B2710
- Product name
- 1,1'-Bis(diisopropylphosphino)ferrocene
- Purity
- >98.0%(T)
- Packaging
- 100mg
- Price
- $38
- Updated
- 2024/03/01
- Product number
- H27057
- Product name
- 1,1'-Bis(diisopropylphosphino)ferrocene, 98%
- Packaging
- 1g
- Price
- $169
- Updated
- 2023/06/20
- Product number
- H27057
- Product name
- 1,1'-Bis(diisopropylphosphino)ferrocene, 98%
- Packaging
- 5g
- Price
- $571
- Updated
- 2023/06/20
1,1'-Bis(diisopropylphosphino)ferrocene Chemical Properties,Usage,Production
Reaction
- Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes
- Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO.
- Pd-catalyzed carbonylative ɑ-arylation of ketones with aryl iodides
- Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters
- Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation
- Ligand for ruthenium-catalyzed C—C coupling reactions of fluorinated alcohols with allenes.
- Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents.
Chemical Properties
orange crystalline powder
Uses
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.
1,1'-Bis(diisopropylphosphino)ferrocene Preparation Products And Raw materials
Raw materials
Preparation Products
1,1'-Bis(diisopropylphosphino)ferrocene Suppliers
- Tel
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- Country
- Switzerland
- ProdList
- 6896
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View Lastest Price from 1,1'-Bis(diisopropylphosphino)ferrocene manufacturers
- Product
- 1,1'-Bis(diisopropylphosphino)ferrocene 97239-80-0
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-01-30
- Product
- 1,1'-Bis(diisopropylphosphino)ferrocene 97239-80-0
- Price
- US $0.00-0.00/Kg
- Min. Order
- 1Kg
- Purity
- 98%
- Supply Ability
- 100kg
- Release date
- 2024-07-26
- Product
- 1,1'-Bis(diisopropylphosphino)ferrocene 97239-80-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 50KG
- Release date
- 2024-10-14