ChemicalBook > CAS DataBase List > (Bromomethyl)cyclopropane
(Bromomethyl)cyclopropane
Uses Description- Product Name
- (Bromomethyl)cyclopropane
- CAS No.
- 7051-34-5
- Chemical Name
- (Bromomethyl)cyclopropane
- Synonyms
- CYCLOPROPYLMETHYL BROMIDE;Cyclopropane, (bromomethyl)-;CPMBr;(Bromomethyl)cyclopr;(Xiu Jiaji)cyclopropane;BroMoMethyl)cyclopropan;Cyclopropylmethylbromid;Roflumilast impurity 18;CYCLOPROPYLMETYL BROMIDE;Bromo(cyclopropyl)methane
- CBNumber
- CB8119915
- Molecular Formula
- C4H7Br
- Formula Weight
- 135
- MOL File
- 7051-34-5.mol
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(Bromomethyl)cyclopropane Property
- Melting point:
- 87-90 °C
- Boiling point:
- 105-107 °C(lit.)
- Density
- 1.392 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.457(lit.)
- Flash point:
- 107 °F
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Liquid
- Specific Gravity
- 1.392
- color
- Clear colorless to slightly colored
- Water Solubility
- Not miscible in water.
- BRN
- 605296
- Stability:
- Stable. Flammable. Incompatible with strong bases, strong oxidizing agents.
- InChIKey
- AEILLAXRDHDKDY-UHFFFAOYSA-N
- CAS DataBase Reference
- 7051-34-5(CAS DataBase Reference)
- NIST Chemistry Reference
- Cyclopropane, (bromomethyl)-(7051-34-5)
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Safety
- Hazard Codes
- Xi,F,Xn
- Risk Statements
- 10-36/37/38-22
- Safety Statements
- 23-24/25-37/39-26-16-36/37/39
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 3
- Hazard Note
- Irritant
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29035990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H302Harmful if swallowed
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242Use only non-sparking tools.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 242403
- Product name
- (Bromomethyl)cyclopropane
- Purity
- 97%
- Packaging
- 1g
- Price
- $54
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 242403
- Product name
- (Bromomethyl)cyclopropane
- Purity
- 97%
- Packaging
- 5g
- Price
- $162
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- L01122
- Product name
- (Bromomethyl)cyclopropane, 97%
- Packaging
- 1g
- Price
- $46.4
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- L01122
- Product name
- (Bromomethyl)cyclopropane, 97%
- Packaging
- 5g
- Price
- $132
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- L01122
- Product name
- (Bromomethyl)cyclopropane, 97%
- Packaging
- 25g
- Price
- $522
- Updated
- 2024/03/01
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(Bromomethyl)cyclopropane Chemical Properties,Usage,Production
Uses
(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents.
Description
(Bromomethyl) cyclopropane is a cyclopropane derivative. It can be used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1, 4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.
Chemical Properties
Colorless to yellow liquid
Uses
(Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.
Synthesis Reference(s)
Tetrahedron Letters, 13, p. 2135, 1972 DOI: 10.1016/S0040-4039(01)84787-0
General Description
The coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied.
(Bromomethyl)cyclopropane Preparation Products And Raw materials
Raw materials
Tetrahydrofuran
Diethyl ether
Lithium Aluminum Hydride
Cyclopropanecarboxylic acid
Phosphorus tribromide
Preparation Products
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View Lastest Price from (Bromomethyl)cyclopropane manufacturers
Speranza Chemical Co., Ltd.
- Product
- (Bromomethyl)cyclopropane 7051-34-5
- Price
- US $20.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200 tons/ year
- Release date
- 2020-03-11
Henan Fengda Chemical Co., Ltd
- Product
- (Bromomethyl)cyclopropane 7051-34-5
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-26
Hebei Yanxi Chemical Co., Ltd.
- Product
- (Bromomethyl)cyclopropane 7051-34-5
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 100tons
- Release date
- 2023-09-27
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