(Bromomethyl)cyclopropane

Uses Description

Product Name: (Bromomethyl)cyclopropane
CAS No.: 7051-34-5
Chemical Name: (Bromomethyl)cyclopropane
Synonyms: CYCLOPROPYLMETHYL BROMIDE;Cyclopropane, (bromomethyl)-;CPMBr;(Bromomethyl)cyclopr;(Xiu Jiaji)cyclopropane;BroMoMethyl)cyclopropan;Cyclopropylmethylbromid;Roflumilast impurity 18;CYCLOPROPYLMETYL BROMIDE;Bromo(cyclopropyl)methane
CBNumber: CB8119915
Molecular Formula: C4H7Br
Formula Weight: 135
MOL File: 7051-34-5.mol

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(Bromomethyl)cyclopropane Property

Melting point:: 87-90 °C
Boiling point:: 105-107 °C(lit.)
Density: 1.392 g/mL at 25 °C(lit.)
refractive index: n20/D 1.457(lit.)
Flash point:: 107 °F
storage temp.: Inert atmosphere,2-8°C
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Liquid
Specific Gravity: 1.392
color: Clear colorless to slightly colored
Water Solubility: Not miscible in water.
BRN: 605296
Stability:: Stable. Flammable. Incompatible with strong bases, strong oxidizing agents.
InChIKey: AEILLAXRDHDKDY-UHFFFAOYSA-N
CAS DataBase Reference: 7051-34-5(CAS DataBase Reference)
NIST Chemistry Reference: Cyclopropane, (bromomethyl)-(7051-34-5)

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Safety

Hazard Codes: Xi,F,Xn
Risk Statements: 10-36/37/38-22
Safety Statements: 23-24/25-37/39-26-16-36/37/39
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
Hazard Note: Irritant
HazardClass: 3
PackingGroup: III
HS Code: 29035990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H302Harmful if swallowed

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 242403
Product name: (Bromomethyl)cyclopropane
Purity: 97%
Packaging: 1g
Price: $54
Updated: 2024/03/01

Sigma-Aldrich

Product number: 242403
Product name: (Bromomethyl)cyclopropane
Purity: 97%
Packaging: 5g
Price: $162
Updated: 2024/03/01

Alfa Aesar

Product number: L01122
Product name: (Bromomethyl)cyclopropane, 97%
Packaging: 1g
Price: $46.4
Updated: 2024/03/01

Alfa Aesar

Product number: L01122
Product name: (Bromomethyl)cyclopropane, 97%
Packaging: 5g
Price: $132
Updated: 2024/03/01

Alfa Aesar

Product number: L01122
Product name: (Bromomethyl)cyclopropane, 97%
Packaging: 25g
Price: $522
Updated: 2024/03/01

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(Bromomethyl)cyclopropane Chemical Properties,Usage,Production

Uses

(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Description

(Bromomethyl) cyclopropane is a cyclopropane derivative. It can be used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1, 4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Chemical Properties

Colorless to yellow liquid

Uses

(Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.

Synthesis Reference(s)

Tetrahedron Letters, 13, p. 2135, 1972 DOI: 10.1016/S0040-4039(01)84787-0

General Description

The coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied.

(Bromomethyl)cyclopropane Preparation Products And Raw materials

Raw materials

Tetrahydrofuran Diethyl ether Lithium Aluminum Hydride Cyclopropanecarboxylic acid Phosphorus tribromide

Preparation Products

Cimetropium bromide 2-cyclopropylethanamine Cyclopropylacetic acid

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(Bromomethyl)cyclopropane Suppliers

Belgium 2 Canada 2 China 399 Europe 4 France 2 Germany 8 India 17 Japan 3 Slovakia 1 Switzerland 2 The Netherlands 1 United Kingdom 13 United States 47 Global 501

VladaChem GmbH

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Boehringer Ingelheim GmbH

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ACTIVATE SCIENTIFIC GmbH

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ABCR GmbH & CO. KG

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Merck Schuchardt OHG

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View Lastest Price from (Bromomethyl)cyclopropane manufacturers

Speranza Chemical Co., Ltd.

Product: (Bromomethyl)cyclopropane 7051-34-5
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200 tons/ year
Release date: 2020-03-11

HebeiShuoshengImportandExportco.,Ltd

Product: (Bromomethyl)cyclopropane 7051-34-5
Price: US $6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 2000KG/Month
Release date: 2024-08-06

Hebei Yanxi Chemical Co., Ltd.

Product: (Bromomethyl)cyclopropane 7051-34-5
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 100tons
Release date: 2023-09-27

7051-34-5, (Bromomethyl)cyclopropaneRelated Search:

Cyclopropanecarbonitrile Bromotrimethylsilane Cyclopropylboronic acid BROMOPENTAMETHYLBENZENE 1,1-Bis(hydroxymethyl)cyclopropane Ciprofloxacin Ciprofloxacin lactate CHLORODIBROMOMETHANE Cyclohexylmethyl bromide Cyclopropyl methyl ketone Ciprofloxacin hydrochloride Cyromazine Dibromomethane Sodium bromate Propiconazole Cyclopropane Ethidium bromide Benzyl bromide Cyclopropylmethyl Bromide

CPMBr

Cyclopropylcarbinyl bromide

Bromo(cyclopropyl)methane

1-(Bromomethyl)cyclopropane, 95+%

(Bromomethyl)cyclopropane,Cyclopropylmethyl bromide

(Bromomethyl)cyclopr

(Bromomethyl)cyclopropane,96%

Cyclopropane Methyl Chloride

BroMoMethyl)cyclopropan

(Xiu Jiaji)cyclopropane

Cyclopropanemethyl bromide

1-(BROMOMETHYL)CYCLOPROPANE

CYCLOPROPYLMETHYL BROMIDE

(BROMOMETHYL)CYCLOPROPANE

CYCLOPROPYLMETYL BROMIDE

CyclopropylmethylBromide96%

Cyclopropyl bromo methane

Cyclopropane, (bromomethyl)-

Cyclopropylmethylbromid

Roflumilast impurity 18

(Bromomethyl)cyclopropane, 96%, for synthesis

(BROMOMETHYL)CYCLOPROPANE 7051-34-5

(Bromomethyl)cyclopropane ISO 9001：2015 REACH

7051-34-5

051-34-5

C3H5CH2Br

C4H7Br

HALOGEN

Alkyl

Building Blocks

Organic Building Blocks

Halogenated Hydrocarbons

Methyl Halides

Halides

Methyl Halides

Ring Systems

Cycloalkanes

Miscellaneous Reagents

bc0001