ChemicalBook > CAS DataBase List > 3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER

3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER

Product Name: 3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER
CAS No.: 82702-31-6
Chemical Name: 3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER
Synonyms: RARECHEM AL BF 0277;Methyl 3-bromo-4-fluorobenzene;METHYL 3-BROMO-4-FLUOROBENZOATE;3-bromo-4-fluoro-2-methylbenzoate;Methyl3-bromo-4-fluorobenzoate98%;Methyl 3-bromo-4-fluorobenzoate 98%;3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER;Benzoic acid, 3-bromo-4-fluoro-, methyl ester
CBNumber: CB8164036
Molecular Formula: C8H6BrFO2
Formula Weight: 233.03
MOL File: 82702-31-6.mol

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3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER Property

Melting point:: 26-28
Boiling point:: 245.3±20.0 °C(Predicted)
Density: 1.577±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: powder to lump
color: White to Orange to Green
InChI: InChI=1S/C8H6BrFO2/c1-12-8(11)5-2-3-7(10)6(9)4-5/h2-4H,1H3
InChIKey: JVORYGNKYAXATM-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=C(F)C(Br)=C1

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 22
Hazard Note: Irritant/Keep cold
HS Code: 2916310090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical

Product number: M3018
Product name: Methyl 3-Bromo-4-fluorobenzoate
Purity: >98.0%(GC)
Packaging: 1g
Price: $29
Updated: 2025/07/31

TCI Chemical

Product number: M3018
Product name: Methyl 3-Bromo-4-fluorobenzoate
Purity: >98.0%(GC)
Packaging: 5g
Price: $96
Updated: 2025/07/31

TRC

Product number: M295918
Product name: Methyl 3-Bromo-4-fluorobenzoate
Packaging: 100mg
Price: $45
Updated: 2021/12/16

TRC

Product number: M295918
Product name: Methyl 3-Bromo-4-fluorobenzoate
Packaging: 500mg
Price: $65
Updated: 2021/12/16

AK Scientific

Product number: V7890
Product name: Methyl 3-Bromo-4-fluorobenzoate
Packaging: 10g
Price: $144
Updated: 2021/12/16

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3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER Chemical Properties,Usage,Production

Chemical Properties

off-white powder

Synthesis

67-56-1

1007-16-5

82702-31-6

a) Synthesis of methyl 3-bromo-4-fluorobenzoate 3-Bromo-4-fluorobenzoic acid (3.33 g, 15.2 mmol) was dissolved in methanol (30 mL) and acetyl chloride (4.3 mL, 60.8 mmol) was added slowly and dropwise under cooling in an ice bath. The reaction mixture was stirred at room temperature for 20 hours. After completion of the reaction, the reaction solution was concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: hexane/ethyl acetate) to afford methyl 3-bromo-4-fluorobenzoate (3.2 g, 90% yield) as a colorless oil.1H-NMR (CDCl3) δ: 3.92 (3H, s), 7.18 (1H, dd, J = 8.0, 8.2 Hz), 7.99 (1H, ddd, J = 1.9, 4.9, 8.0 Hz), 7.99 (1H, ddd, J = 1.9, 4.9, 8.0 Hz). 4.9, 8.0 Hz), 8.27 (1H, dd, J = 1.9, 6.5 Hz).

References

[1] European Journal of Medicinal Chemistry, 2007, vol. 42, # 11-12, p. 1334 - 1357
[2] Patent: US2010/280013, 2010, A1. Location in patent: Page/Page column 16
[3] Journal of Enzyme Inhibition and Medicinal Chemistry, 2012, vol. 27, # 5, p. 658 - 665,8
[4] Patent: WO2007/99171, 2007, A2. Location in patent: Page/Page column 55
[5] ACS Medicinal Chemistry Letters, 2013, vol. 4, # 3, p. 358 - 362

3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER Suppliers

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View Lastest Price from 3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: Methyl 3-bromo-4-fluorobenzoate 82702-31-6
Price: US $0.00-0.00/KG
Min. Order: 5mg
Purity: 99%HPLC
Supply Ability: 2000tons
Release date: 2020-01-07

82702-31-6, 3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTERRelated Search:

METHYL 2-BROMO-5-FLUOROBENZOATE Methyl 3-BroMo-5-forMylbenzoate 3-Bromo-2-fluorobenzoic acid methyl ester Methyl 3-bromo-5-iodobenzoate Methyl 4-fluoro-3-nitrobenzoate methyl 3-bromo-4-chlorobenzoate 5-BROMO-2-NITRO-BENZOIC ACID METHYL ESTER Methyl 2-broMo-4-chlorobenzoate Methyl 5-bromo-2-chlorobenzoate 3-AMINO-5-BROMOBENZOATE methyl 3-bromo-5-fluoro-2-methylbenzoate Methyl 3-bromo-4-(trifluoromethyl)benzoate METHYL 3-BROMO-5-CHLOROBENZOATE METHYL 3-BROMO-6-FLUORO-2-METHYLBENZOATE 3-BroMo-5-cyanobenzoic acid Methyl ester Methyl 3-bromo-4-hydroxybenzoate methyl 3-bromo-5-chloro-2-methylbenzoate 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER

3-BROMO-4-FLUORO-BENZOIC ACID METHYL ESTER

METHYL 3-BROMO-4-FLUOROBENZOATE

RARECHEM AL BF 0277

Methyl 3-bromo-4-fluorobenzoate 98%

Methyl3-bromo-4-fluorobenzoate98%

Methyl 3-bromo-4-fluorobenzene

3-bromo-4-fluoro-2-methylbenzoate

Benzoic acid, 3-bromo-4-fluoro-, methyl ester

82702-31-6

Acids & Esters

Bromine Compounds

Fluorine Compounds

blocks

Bromides

Carboxes

FluoroCompounds

Aromatic Esters