4-Morpholinecarbonyl chloride

Product Name: 4-Morpholinecarbonyl chloride
CAS No.: 15159-40-7
Chemical Name: 4-Morpholinecarbonyl chloride
Synonyms: 4-Morpholinecarbonyl;N-CHLOROFORMYLMORPHOLINE;Morpholincarbonylchlorid;4-CHLOROCARBONYLMORPHOLINE;4-(Chloroformyl)morpholine;MORPHOLINOCARBONYL CHLORIDE;4-MORPHOLINECARBONYL CHLORIDE;MORPHOLINE-4-CARBONYL CHLORIDE;4-MORPHOLINYLCARBONYL CHLORIDE;MORPHOLIN-4-YLCARBONYL CHLORIDE
CBNumber: CB8744478
Molecular Formula: C5H8ClNO2
Formula Weight: 149.58
MOL File: 15159-40-7.mol

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4-Morpholinecarbonyl chloride Property

Boiling point:: 137-138 °C/33 mmHg (lit.)
Density: 1.282 g/mL at 25 °C (lit.)
refractive index: n20/D 1.498(lit.)
Flash point:: >230 °F
storage temp.: Inert atmosphere,2-8°C
pka: -2.16±0.20(Predicted)
form: clear liquid
color: Colorless to Light yellow
BRN: 116257
InChI: InChI=1S/C5H8ClNO2/c6-5(8)7-1-3-9-4-2-7/h1-4H2
InChIKey: XMWFMEYDRNJSOO-UHFFFAOYSA-N
SMILES: C(Cl)(N1CCOCC1)=O
CAS DataBase Reference: 15159-40-7(CAS DataBase Reference)
EPA Substance Registry System: 4-Morpholinecarbonyl chloride (15159-40-7)

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Safety

Hazard Codes: Xn
Risk Statements: 14-36/38-40
Safety Statements: 26-30-36-38
RIDADR: UN 3265 8/PG 2
WGK Germany: 3
F: 10-21
HazardClass: 8
PackingGroup: II
HS Code: 29349990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 348295
Product name: 4-Morpholinecarbonyl chloride
Purity: 98%
Packaging: 25g
Price: $86.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 348295
Product name: 4-Morpholinecarbonyl chloride
Purity: 98%
Packaging: 100g
Price: $307
Updated: 2023/06/20

TCI Chemical

Product number: M0935
Product name: 4-Morpholinylcarbonyl Chloride
Purity: >97.0%(GC)(T)
Packaging: 25g
Price: $101
Updated: 2024/03/01

TCI Chemical

Product number: M0935
Product name: 4-Morpholinylcarbonyl Chloride
Purity: >97.0%(GC)(T)
Packaging: 100g
Price: $228
Updated: 2024/03/01

TRC

Product number: M723600
Product name: 4-Morpholinecarbonyl chloride
Packaging: 10g
Price: $50
Updated: 2021/12/16

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4-Morpholinecarbonyl chloride Chemical Properties,Usage,Production

Uses

Photographic intermediate

Uses

4-Morpholinecarbonyl chloride may be used in the preparation of a versatile fluorogenic label for biomolecular imaging. It may be used in the synthesis of:

morpholine-4-carboxylic acid [4-(2,4-dimethylphenyl)thiazol-2-yl]amide
morpholine-4-carboxylic acid [4-(2,4,6-trimethylphenyl)thiazol-2-yl]amide
2-isopropyl-6-methylpyrimidin-4-yl morpholine-4-carboxylate

General Description

4-Morpholinecarbonyl chloride is a photographic intermediate. Rates of solvolysis of 4-morpholinecarbonyl chloride with N-alkyl group in aqueous binary solvents of acetone, ethanol, methanol, methanol-d, 2,2,2-trifluoroethanol, pure water and D₂O has been determined. Preparation of 4-morpholinecarbonyl chloride has been reported.

Synthesis

4-Morpholinecarbonyl chloride is prepared by reacting morpholine hydrochloride with phosgene in an inert liquid medium such as toluene and xylene, at 50W150°C, pref. 60W120°C. The morpholine hydrochloride is prepared by dissolving 1 part by weight of morpholine in ≥4 parts of an inert liquid medium and introducing a slightly excessive HCl into the solution under agitation.

4-Morpholinecarbonyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Morpholinecarbonyl chloride Suppliers

Americas 1 China 114 Europe 3 France 1 Germany 4 India 4 Japan 2 Slovakia 1 South Korea 1 Switzerland 1 Ukraine 1 United Kingdom 5 United States 15 Global 153

Aladdin Scientific

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View Lastest Price from 4-Morpholinecarbonyl chloride manufacturers

Honest Joy Holdings Limited

Product: 4-Morpholinecarbonyl chloride 15159-40-7
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.9%
Supply Ability: 100 tons
Release date: 2022-02-08

Unipharm pharmaceutical industry Co., Ltd

Product: 4-Morpholinecarbonyl chloride 15159-40-7
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 97% GC
Supply Ability: EX: 100kgs
Release date: 2021-03-23

Shaanxi Dideu Medichem Co. Ltd

Product: 4-Morpholinylcarbonyl chloride 15159-40-7
Price: US $0.00-0.00/Kg
Min. Order: 1KG
Purity: 99.0%+
Supply Ability: 600 tons
Release date: 2020-01-02

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15159-40-7

C5H8ClNO2

Building Blocks

Morpholines

Heterocyclic Building Blocks

Phosgene Derivatives

Building Blocks

Heterocyclic Building Blocks

Morpholines

Building Blocks

Chemical Synthesis

Heterocyclic Building Blocks

Morpholines/Thiomorpholines

ACIDHALIDE