1-Chloro-3-nitrobenzene

Product Name: 1-Chloro-3-nitrobenzene
CAS No.: 121-73-3
Chemical Name: 1-Chloro-3-nitrobenzene
Synonyms: 1-CHLORO-3-NITROBENZENE;mncb;3-CHLORONITROBENZENE;M-NITROCHLOROBENZENE;1-chloronitrobenzene;M-CHLORONITROBENZENE;1-nitro-3-chlorobenzene;1-Chloro-3;3-Chlornitrobenzol;3-NITROCHLOROBENZENE
CBNumber: CB8747505
Molecular Formula: C6H4ClNO2
Formula Weight: 157.55
MOL File: 121-73-3.mol

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1-Chloro-3-nitrobenzene Property

Melting point:: 43-47 °C(lit.)
Boiling point:: 236 °C(lit.)
Density: 1.534 g/mL at 25 °C(lit.)
vapor pressure: 1.9Pa at 25℃
refractive index: 1.5545 (estimate)
Flash point:: 218 °F
storage temp.: Store below +30°C.
solubility: alcohol: freely soluble (hot)(lit.)
form: powder to lump to clear liquid
color: White or Colorless to Yellow
PH: 7 (0.26g/l, H2O, 20℃)
Water Solubility: INSOLUBLE
Merck: 14,2151
BRN: 1907947
Stability:: Stable. Incompatible with strong oxidizing agents, strong acids, strong reducing agents.
LogP: 2.49
CAS DataBase Reference: 121-73-3(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 1-chloro-3-nitro-(121-73-3)
EPA Substance Registry System: m-Chloronitrobenzene (121-73-3)

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Safety

Hazard Codes: Xn,N,T
Risk Statements: 22-50/53-23/24/25
Safety Statements: 22-24/25-60-61-45-38-36/37/39-28A
RIDADR: UN 1578 6.1/PG 2
WGK Germany: 2
RTECS: CZ0940000
Autoignition Temperature: 500 °F
TSCA: Yes
HazardClass: 6.1
PackingGroup: II
HS Code: 29049085
Hazardous Substances Data: 121-73-3(Hazardous Substances Data)
Toxicity: mouse,LD50,oral,380mg/kg (380mg/kg),Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 25(8), Pg. 50, 1981.

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 218758
Product name: 1-Chloro-3-nitrobenzene
Purity: 98%
Packaging: 250g
Price: $62.6
Updated: 2023/01/07

TCI Chemical

Product number: C0221
Product name: 1-Chloro-3-nitrobenzene
Purity: >99.0%(GC)
Packaging: 25g
Price: $16
Updated: 2023/06/20

TCI Chemical

Product number: C0221
Product name: 1-Chloro-3-nitrobenzene
Purity: >99.0%(GC)
Packaging: 500g
Price: $87
Updated: 2023/06/20

Alfa Aesar

Product number: B23423
Product name: 1-Chloro-3-nitrobenzene, 98%
Packaging: 250g
Price: $43.8
Updated: 2023/06/20

Alfa Aesar

Product number: B23423
Product name: 1-Chloro-3-nitrobenzene, 98%
Packaging: 1000g
Price: $140
Updated: 2021/12/16

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1-Chloro-3-nitrobenzene Chemical Properties,Usage,Production

Chemical Properties

Moist tan or pale yellow crystalline solid

Uses

Intermediate for dyes. 1-Chloro-3-nitrobenzene was used in the preparation of aromatic azo compounds using gold (Au) nanoparticles supported on TiO2 as a catalyst. It was also used as surrogate standard to evaluate the removal of 2,4-dinitrotoluene from contaminated soils using enhanced electrokinetic remediation.

Production Methods

m-Chloronitrobenzene is of lesser economic importance than its ortho- and para-isomers, with no U.S. production reported. The annual production in Germany was reported to be on the order of 1000–3000 metric tons. It has limited use in the manufacturing of dyes and agricultural chemicals.
There is no information on potential exposure. Chloronitrobenzene has been detected in the surface water of the Rhine River with concentrations between 20 and 500 ng/L and in fish at levels of up to 1 mg/kg.

Definition

ChEBI: 1-chloro-3-nitrobenzene is a C-nitro compound that is nitrobenzene in which one of the meta- hydrogens has been replaced by chlorine. It is a C-nitro compound and a member of monochlorobenzenes.

General Description

Pale yellow crystals. Insoluble in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

3-Nitrochlorobenzene can react with oxidizing materials. .

Hazard

Toxic by inhalation and ingestion. Combustible. Questionable carcinogen.

Fire Hazard

Flash point data for 3-Nitrochlorobenzene are not available. 3-Nitrochlorobenzene is probably combustible.

Flammability and Explosibility

Not classified

Safety Profile

Poison by ingestion and inhalation. It forms methemoglobin in the body and gves rise to cyanosis and blood changes. Its effects are cumulative and analogous to those of nitrobenzene. The para compound is thought to be somewhat less toxic than the ortho compound. Chemically, it is probably converted in the body to chloroaniline, whch is also poisonous. In industry, it is the dust of hs material that is most often the source of intoxication. Flammable liquid and dangerous fire hazard when exposed to heat or flame. It can react with oxidizing materials. When heated to decomposition it emits toxic fumes of Cl-, NOx, and phosgene. See also other chloronitrobenzene entries and NITRO COMPOUNDS of AROMATIC HYDROCARBONS.

Synthesis

1-Chloro-3-nitrobenzene was synthesised from 4-chloro-2-nitro-benzoic acid by adding copper iodide, triethylamine and dimethyl sulfoxide in the presence of inert gas using the Schlenk technique.

Purification Methods

Crystallise the nitrobenzene from MeOH or 95% EtOH (charcoal), then pentane. [Beilstein 5 IV 722.]

1-Chloro-3-nitrobenzene Preparation Products And Raw materials

Raw materials

4-Chloronitrobenzene Iron filings Chlorination tower Chlorobenzene Nitric acid Sulfuric acid

Preparation Products

FAST ORANGE GC SALT 2-Nitrochlorobenzene 3-CHLOROANILINE HYDROCHLORIDE 3-Chloroaniline

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121-73-3, 1-Chloro-3-nitrobenzeneRelated Search:

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1-Chloro-3-nitrobenzene,98%

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1-Chloro-3-nitrobenzene, 98% 5GR

1-Chloro-3

121-73-3 3-Nitrochlorobenzene

1-CHLORO-3-NITROBENZENE For Synthesis

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meta-nitrochlorobenzene

Ceftobiprole Impurity 3

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3-Chloronitrobenzene 100 μg/ml Cyclohexane

C11453600 1-Chloro-3-nitrobenzene

121-73-3

127-73-3

88-73-8

C6H4NO2Cl

121733

NO2C6H4Cl

ClC6H4NO2

Building Blocks

Organic Building Blocks

Nitrogen Compounds

Nitro Compounds

Benzene derivates

Agrochemical Intermediates

Intermediates of Dyes and Pigments

Alpha Sort

Analytical Standards

AromaticsVolatiles/ Semivolatiles

C

CAlphabetic

CHChemical Class

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ChloroAnalytical Standards

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Nitro Compounds