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2-Bromo-3-methylpyridine

Product Name
2-Bromo-3-methylpyridine
CAS No.
3430-17-9
Chemical Name
2-Bromo-3-methylpyridine
Synonyms
2-BROMO-3-PICOLINE;2-Bromo-β-picoline;2-bormo-3-methylpyridine;2-BROMO-3-METHYLPYRIDINE;Pyridine, 2-bromo-3-methyl-;2-Bromo-3-methylpyridine,95%;2-BROMO-3-METHYLPYRIDINE 98%;2-Bromo-3-methylpyridine >2-Bromo-3-methylpyridine, 98+%;2-BroMo-3-Methylpyridine, 95% 5ML
CBNumber
CB9122668
Molecular Formula
C6H6BrN
Formula Weight
172.02
MOL File
3430-17-9.mol
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2-Bromo-3-methylpyridine Property

Boiling point:
218-219 °C (lit.)
Density 
1.544 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.568(lit.)
Flash point:
>230 °F
storage temp. 
Inert atmosphere,Room Temperature
pka
1.08±0.10(Predicted)
form 
Liquid
Specific Gravity
1.55
color 
Clear slightly yellow to light brown
BRN 
107896
InChI
InChI=1S/C6H6BrN/c1-5-3-2-4-8-6(5)7/h2-4H,1H3
InChIKey
PZSISEFPCYMBDL-UHFFFAOYSA-N
SMILES
C1(Br)=NC=CC=C1C
CAS DataBase Reference
3430-17-9(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-37/39-36/37/39-36
WGK Germany 
3
Hazard Note 
Harmful
HazardClass 
IRRITANT
PackingGroup 
III
HS Code 
29333990
Storage Class
10 - Combustible liquids
Hazard Classifications
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
448109
Product name
2-Bromo-3-methylpyridine
Purity
95%
Packaging
5ml
Price
$115
Updated
2026/03/19
Sigma-Aldrich
Product number
448109
Product name
2-Bromo-3-methylpyridine
Purity
95%
Packaging
25ml
Price
$218
Updated
2026/03/19
TCI Chemical
Product number
B1894
Product name
2-Bromo-3-methylpyridine
Purity
>97.0%(GC)
Packaging
5g
Price
$26
Updated
2026/03/19
TCI Chemical
Product number
B1894
Product name
2-Bromo-3-methylpyridine
Purity
>97.0%(GC)
Packaging
25g
Price
$87
Updated
2026/03/19
TRC
Product number
B697575
Product name
2-Bromo-3-methylpyridine
Packaging
5g
Price
$75
Updated
2021/12/16
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2-Bromo-3-methylpyridine Chemical Properties,Usage,Production

Description

2-Bromo-3-methylpyridine is a diazido compound with a hydrogen bond. It reacts rapidly with copper chloride to form the coordination complex Cu(diazido)(Cl)2 and an organic product.

Chemical Properties

clear slightly yellow to light brown liquid

Uses

2-Bromo-3-methylpyridine is a halogenated pyridine analogue containing a bromine functional group. The substance is used as a reaction reagent and as a basic structural unit in organic synthesis for the preparation of other heterocyclic compounds.

Production Methods

2-Bromo-3-methylpyridine can be synthesized from 2,4-dibromopyridine by a cross coupling reaction with copper chloride and calcium carbonate in the presence of sodium potassium bicarbonate.

Synthesis

A solution of 2,3-dibromopyridine (0.10 M, 3.0 mL) in THF was stirred at T ℃. A solution of n-BuLi (0.40 M, 0.75 mL) in hexane was added dropwise to this solution at a regular pace for 1.0 min. After stirring for 10 min, iodomethane (0.60 M, 1.5 mL) was added dropwise to this mixture at a regular pace for 1.0 min. After stirring at T ℃ for 10 min, a cooling bath was removed. When the reaction mixture reached room temperature and was quenched with H2O, the yields of 2-bromo-3-methylpyridine (2) and 2-bromopyridine (3) and the conversion of 2,3-dibromopyridine (1) was analyzed by GC.

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2-Bromo-3-methylpyridine Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
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China
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96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
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40228
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Liaoning Tianhua Chemical Co., Ltd.
Tel
0418-6530555 2855550
Fax
+86-418-6502885
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China
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338
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future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
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China
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1995
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Alfa Aesar
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400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
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China
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TCI (Shanghai) Development Co., Ltd.
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021-67121386
Fax
021-67121385
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Sales-CN@TCIchemicals.com
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China
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24529
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Chang Zhou Chemistar Chemistry Technology Co.,Ltd
Tel
+86 (519) 8689-6136
Fax
+86 (519) 8205-9235
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kr@krchemistar.com
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China
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Beijing HwrkChemical Technology Co., Ltd
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89508211 18501085097
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010-89508210
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sales.bj@hwrkchemical.com
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China
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Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44802
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Shijiazhuang Sdyano Fine Chemical Co., Ltd.
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0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2826
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View Lastest Price from 2-Bromo-3-methylpyridine manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
2-Bromo-3-methylpyridine 3430-17-9
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-12
Shanghai Yongzeng Technology Co.,Ltd
Product
2-Bromo-3-methylpyridine 3430-17-9
Price
US $0.00/gm
Min. Order
100gm
Purity
99%min
Supply Ability
100kgs
Release date
2024-09-04
Henan Fengda Chemical Co., Ltd
Product
2-Bromo-3-methylpyridine 3430-17-9
Price
US $5.00-0.10/KG
Min. Order
1KG
Purity
98%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-09

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