ChemicalBook > CAS DataBase List > TRIPHENYLPHOSPHINE RESIN

TRIPHENYLPHOSPHINE RESIN

Product Name
TRIPHENYLPHOSPHINE RESIN
CAS No.
39319-11-4
Chemical Name
TRIPHENYLPHOSPHINE RESIN
Synonyms
POLYMER-BOUND TRIPHENYLPHOSPHINE;POLYMER SUPPORTED TRIPHENYLPHOSPHINE;TRIPHENYLPHOSPHINE POLYMER BOUND;PL-TPP RESIN;-C6H4P(C6H5)2;PL-TPP MP-RESIN;POLYSTYRENE-PPH2;diphenylphosphinated;TRIPHENYLPHOSPHINE PS;TRIPHENYLPHOSPHINE RESIN
CBNumber
CB9181407
Molecular Formula
C18H15P
Formula Weight
262.285461
MOL File
39319-11-4.mol
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TRIPHENYLPHOSPHINE RESIN Property

storage temp. 
2-8°C
form 
Beads
color 
White to yellow
Sensitive 
Air Sensitive
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-43-20/21/22-36/37/38
Safety Statements 
36/37-36-26
WGK Germany 
3
10-23
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
14664
Product name
Triphenylphosphine, polymer-bound
Purity
100-200?mesh, extent of labeling: ~3.2?mmol/g loading
Packaging
25g
Price
$304
Updated
2024/03/01
Alfa Aesar
Product number
L19478
Product name
Triphenylphosphine, polymer-supported
Purity
1.4-2.0 mmol/g on polystyrene
Packaging
1g
Price
$31.1
Updated
2023/06/20
Alfa Aesar
Product number
L19478
Product name
Triphenylphosphine, polymer-supported
Purity
1.4-2.0 mmol/g on polystyrene
Packaging
5g
Price
$96.3
Updated
2021/12/16
Strem Chemicals
Product number
15-6730
Product name
Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked)
Packaging
1g
Price
$48
Updated
2021/12/16
Strem Chemicals
Product number
15-6730
Product name
Triphenylphosphine, polymer-bound, on styrene-divinylbenzene copolymer (20% cross-linked)
Packaging
5g
Price
$143
Updated
2021/12/16
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TRIPHENYLPHOSPHINE RESIN Chemical Properties,Usage,Production

Chemical Properties

white to yellow beads

Uses

Polymer-bound triphenylphosphine is a solid-supported reagent that can be used as a better alternative to triphenylphosphine in the Mitsunobu reaction.
It can also be used:

  • For the esterification of alkylphosphonic acids using primary alcohols in the presence of iodine and imidazole.
  • To catalyze the conversion of 3-[3-(1,3-dioxolan-2-yl)-1-hydroxypropyl]pyridine to 3-[1-bromo-3-(1,3-dioxolan-2-yl)propyl]pyridine using carbon tetrabromide.
  • To isomerize (Z)-nitro olefins to the (E)-isomers.
  • To prepare polymer-bound ylides which are useful in Wittig reactions.
  • To convert alcohols or carboxylic acids to the corresponding chlorides.
  • In combination with carbon tetrachloride for the coupling N-alkoxycarbonyl α-amino acids and primary amines to form the corresponding amides.

Uses

Triphenylphosphine resin is used for the preparation of polymer bound ylids which are useful for Wittig reactions.

TRIPHENYLPHOSPHINE RESIN Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIPHENYLPHOSPHINE RESIN Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40240
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18217
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12458
Advantage
60
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9725
Advantage
55
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17779
Advantage
75
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
22519
Advantage
55
Huainan Kedi Chemical Factory
Tel
0554-2106669
Fax
0554-2666215
Email
sales1@kedichem.com
Country
China
ProdList
4928
Advantage
55
Chengdu HuaXia Chemical Reagent Co. Ltd
Tel
400-1166-196 13458535857
Fax
QQ:800101999
Email
cdhxsj@163.com
Country
China
ProdList
13358
Advantage
58

39319-11-4, TRIPHENYLPHOSPHINE RESINRelated Search:


  • TRIPHENYLPHOSPHINE POL. BOUND, 100-200 M ESH, ~1.6 MMOL/G
  • TRIPHENYLPHOSPHINE POL. BOUND, 200-400 M ESH, ~3 MMOL/G
  • TriphenylphosphineResin1%DvbMesh,1-1.5Mmol/G
  • Triphenylphosphine resin, Crosslinked with 1% DVB, 1.2-1.5 mmol/g, 100-200 mesh
  • Triphenylphosphine resin, 1% crosslinked with DVB
  • 4-DIPHENYLPHOSPHINO POLYSTYRENE RESIN
  • COPOLYMER OF STYRENE AND DIVINYLBENZENE, DIPHENYLPHOSPHINATED
  • DIPHENYLPHOSPHINOBENZOYL NOVAGEL(TM) AM RESIN
  • DIPHENYLPHOSPHINO-POLYSTYRENE
  • MACROPOROUS POLYMER SUPPORTED TRIPHENYLPHOSPHINE
  • PL-TPP RESIN
  • PL-TPP MP-RESIN
  • POLYMER SUPPORTED TRIPHENYLPHOSPHINE
  • POLYMER-BOUND TRIPHENYLPHOSPHINE
  • POLYSTYRENE CROSSLINKED WITH DIVINYL-BENZENE, DIPHENYLPHOSPHINATED
  • POLYSTYRENE-PPH2
  • TRIPHENYLPHOSPHINE POLYMER BOUND
  • TRIPHENYLPHOSPHINE, POLYMER-SUPPORTED
  • TRIPHENYLPHOSPHINE POLYSTYRENE
  • TRIPHENYLPHOSPHINE PS
  • TRIPHENYLPHOSPHINE PS RESIN
  • TRIPHENYLPHOSPHINE RESIN
  • TRIPHENYLPHOSPHINE NOVAGEL
  • TRIPHENYLPHOSPHINE NOVAGEL(TM)
  • 4-DIPHENYLPHOSPHINO POLYSTYRENE RESIN, CROSS-LINKED WITH 2% DVB: (1.0-2.0MMOLP/G), 200-400MESH
  • Triphenylphosphine polystyrene (100-200 mesh, 0.8-1.6 mmol
  • Triphenylphosphine polystyrene (200-400 mesh, 1.0-1.5 mmol
  • 4-Diphenylphosphino Polystyrene Resin cross-linked with 2% DVB (200-400mesh) (1.0-2.0mmol/g)
  • diphenylphosphinated
  • Copolymer of styrene and divinylbenzene, diphenylphosphinated, Diphenylphosphino-polystyrene, Polystyrene crosslinked with divinylbenzene, diphenylphosphinated
  • TRIPHENYLPHOSPHINE RESIN, 1% CROSSL.WITH DVB, 1.2-1.5 MMOL/G, 200-400 MESH
  • Triphenylphosphine resin, 1% crossl. with DVB, 1.2-1.5 mmol/g, 100-200 mesh
  • 4-Diphenylphosphino polystyrene resin, cross-linked with 2% DVB
  • Diphenyl(4-vinylphenyl)phosphine-divinylbenzene-styrene copolymer
  • Triphenylphosphine, polyMer-bound 100-200 Mesh, extent of labeling: ~3.0 MMol/g loading, 2 % cross-linked with divinylbenzene
  • Triphenylphosphine resin(1.0-1.5 meq/g, 100-200 mesh)
  • Triphenylphosphine, polymer-supported, 1.4 to 2.0mmol/g on polystyrene
  • Triphenylphosphine resin, 1% crosslinked with DVB, 1.0-1.5mmol/g
  • -C6H4P(C6H5)2
  • Triphenylphosphine, polymer supported1.4-2.0mmol/g on polystyrene 200-400 mesh2% DVB loading
  • Triphenylphosphine, polymer-bound 100-200 mesh, extent of labeling: ~1.6 mmol/g loading
  • Triphenylphosphine, polymer-bound 100-200 mesh, extent of labeling: ~3 mmol/g triphenylphosphine loading
  • 39319-11-4
  • C20H17PmC10H10nC8H8x
  • -C6H4PC6H52
  • Supported Reagents
  • Supported Synthesis
  • Specialty Synthesis
  • Ligands
  • Combinatrial Chemistry
  • Resins
  • Mitsunobu Reaction
  • Polymer-Supported Reagents
  • Phosphines (Mitsunobu Reaction)
  • Combinatorial Chemistry
  • Mitsunobu Reaction
  • Phosphines (Mitsunobu Reaction)
  • Polymer-Supported Reagents