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ChemicalBook > CAS DataBase List > (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

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Product Name
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
CAS No.
169689-05-8
Chemical Name
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
Synonyms
Rostligand;(S,S)-DACH-phenyl ligand;(1S,2S)-(-)-1,2-TROST LIGAND;1S,2S- DHAC-Phenyl Trost Ligand;(S,S)-DACH-phenyl Trost ligand;95% (S,S)-DACH-Phenyl Trost Ligand;(S,S)-DACH-phenyl Trost ligand 95%;(1S,2S)-DHAC-Phenyl Trost Ligand,99%e.e.;1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl);(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosp...
CBNumber
CB9299425
Molecular Formula
C44H40N2O2P2
Formula Weight
690.76
MOL File
169689-05-8.mol
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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Property

Melting point:
134-136°C
Boiling point:
817.0±65.0 °C(Predicted)
alpha 
-134o (C=1 IN METHANOL)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
13.35±0.40(Predicted)
form 
Powder
color 
white to off-white
optical activity
[α]20/D -134°, c = 1 in methanol
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
692794
Product name
(S,S)-DACH-phenyl Trost ligand
Purity
95%
Packaging
250mg
Price
$64.8
Updated
2024/03/01
Sigma-Aldrich
Product number
692794
Product name
(S,S)-DACH-phenyl Trost ligand
Purity
95%
Packaging
1g
Price
$374
Updated
2024/03/01
Strem Chemicals
Product number
15-0961
Product name
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand
Packaging
100mg
Price
$41
Updated
2024/03/01
Strem Chemicals
Product number
15-0961
Product name
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand
Packaging
500mg
Price
$161
Updated
2024/03/01
Strem Chemicals
Product number
15-0961
Product name
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand
Packaging
2g
Price
$495
Updated
2024/03/01
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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Chemical Properties,Usage,Production

Reaction

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles.

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Preparation Products And Raw materials

Raw materials

Preparation Products

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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Suppliers

Accela ChemBio Inc.
Tel
+1-858-6993322
Fax
(+1)-858-876-1948
Email
info@accelachem.com
Country
United States
ProdList
17322
Advantage
58
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Strem Chemicals, Inc.
Tel
--
Fax
--
Email
info@strem.com
Country
United States
ProdList
4910
Advantage
86
Riedel-de Haen AG
Tel
--
Fax
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Country
United States
ProdList
6773
Advantage
87
Alfa Chemistry
Tel
--
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Email
info@Alfa-Chemistry.com
Country
United States
ProdList
6814
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View Lastest Price from (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(S,S)-DACH-phenyl Trost ligand 169689-05-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) 169689-05-8
Price
US $3.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-10

169689-05-8, (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)Related Search:


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