ChemicalBook > CAS DataBase List > 4-Aminoindole

4-Aminoindole

Product Name
4-Aminoindole
CAS No.
5192-23-4
Chemical Name
4-Aminoindole
Synonyms
4-INDOLAMINE;4-Aminoindole;4-Aiminoindole;INDOLE-4-AMINE;1H-INDOL-4-AMINE;4-AMINO-1H-INDOLE;4-AMinoindole 97%;(Indol-4-yl)amine;4-Aminoindole >4-Aminoindole ,97%
CBNumber
CB9300055
Molecular Formula
C8H8N2
Formula Weight
132.16
MOL File
5192-23-4.mol
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4-Aminoindole Property

Melting point:
106-109 °C (lit.)
Boiling point:
354.0±15.0 °C(Predicted)
Density 
1.268±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
18.23±0.30(Predicted)
form 
powder to crystal
color 
White to Gray to Brown
Water Solubility 
Insoluble
Sensitive 
Air Sensitive
BRN 
114919
InChI
InChI=1S/C8H8N2/c9-7-2-1-3-8-6(7)4-5-10-8/h1-5,10H,9H2
InChIKey
LUNUNJFSHKSXGQ-UHFFFAOYSA-N
SMILES
N1C2=C(C(N)=CC=C2)C=C1
CAS DataBase Reference
5192-23-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-24/25
WGK Germany 
3
8-10-34
HazardClass 
AIR SENSITIVE, IRRITANT-HARMFUL, KEEP COLD
HS Code 
29339990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
525022
Product name
4-Aminoindole
Purity
97%
Packaging
500mg
Price
$93.4
Updated
2023/06/20
TCI Chemical
Product number
A2070
Product name
4-Aminoindole
Purity
>98.0%(GC)
Packaging
1g
Price
$69
Updated
2025/07/31
TCI Chemical
Product number
A2070
Product name
4-Aminoindole
Purity
>98.0%(GC)
Packaging
5g
Price
$207
Updated
2025/07/31
TRC
Product number
A576743
Product name
4-Aminoindole
Packaging
100mg
Price
$75
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK130926
Product name
4-Aminoindole
Purity
97%
Packaging
500mg
Price
$109
Updated
2021/12/16
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4-Aminoindole Chemical Properties,Usage,Production

Chemical Properties

Greenish-grey to tan powder

Uses

Reactant for preparation of:• ;Inhibitors of bacterial thymidylate synthase1• ;Mimetics of non-alkaloid toxin lignan anticancer and antiviral agent Podophyllotoxin (PPT)2• ;Inhibitors of Gli1-mediated transcription in the Hedgehog pathway3• ;Protein kinase C θ (PKCθ) inhibitors4• ;Indolic non-peptidic HIV protease inhibitors5• ;Transient receptor potential cation channel subfamily V member 1 (TRPV1) antagonists6• ;Cyclooxygenase-2 (COX-2) and lipoxygenase (LOX) inhibitors7• ;11β-hydroxysteroid dehydrogenase 1 (11β-HSD1) inhibi

Uses

4-Aminoindole may be used to synthesize:

  • macrolactam tumour promoter indolactam V
  • tricyclic structure of 2-substituted-pyrrolo[2,3-h]quinolin-4-one
  • 4-azidoindole

Definition

ChEBI: 4-Aminoindole is a member of indoles.

Synthesis Reference(s)

The Journal of Organic Chemistry, 48, p. 5130, 1983 DOI: 10.1021/jo00173a071

General Description

4-Aminoindole is an indole derivative. Its cytokinin activity has been assessed by tobacco pith callus bioassay. 4-Aminoindole can be prepared by reacting 2,6-dinitrotoluene and N,N-dimethylformamide dimethylacetal in anhydrous DMF.

Synthesis

4769-97-5

7439-89-6

5192-23-4

A. Synthesis of 4-aminoindole. Iron powder (1.20 g, 21.58 mmol) and acetic acid (2.47 mL, 43.19 mmol) were sequentially added to a solution of ethanol (20 mL) containing 4-nitroindole (1.0 g, 6.17 mmol). The reaction mixture was heated to reflux for 14 hours. After completion of the reaction, the ethanol solvent was removed by rotary evaporator. The residue was dispersed in a solvent mixture of water and ethyl acetate for extraction and separation. The ethyl acetate layer was collected and dried with anhydrous magnesium sulfate followed by filtration to remove the desiccant. The filtrate was concentrated by rotary evaporation to give the crude product. The crude product was further purified by silica gel column chromatography using 1% methanol/dichloromethane mixture as eluent. The elution fractions containing the target product were collected, combined and the solvent was removed by rotary evaporation to give 0.815 g of 4-aminoindole as an orange solid in 82% yield.

References

[1] Patent: US6162818, 2000, A

4-Aminoindole Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Aminoindole Suppliers

Changzhou Wanyao Biotechnology Co., Ltd.
Tel
0519-89185693 15312551983
Fax
0519-89185693
Email
2410037592@qq.com
Country
China
ProdList
261
Advantage
55
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Bridge Organics
Tel
+1269-649-4200
Fax
+1269-649-0611
Email
ab@bridgeorganics.com
Country
United States
ProdList
162
Advantage
55
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-010-82967028 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12000
Advantage
60
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View Lastest Price from 4-Aminoindole manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
4-Aminoindole 5192-23-4
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-25
Chemwill Asia Co.,Ltd.
Product
4-Aminoindole in stock Factory 5192-23-4
Price
US $1.00/KG
Min. Order
1KG
Purity
TOP 3 Factory in China
Supply Ability
Top 3 largest production capacity Factory
Release date
2019-04-03
Career Henan Chemical Co
Product
4-Aminoindole 5192-23-4
Price
US $8.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10tons
Release date
2018-12-24

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